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Title: Metal–Air Batteries: Will They Be the Future Electrochemical Energy Storage Device of Choice? [Metal-Air Batteries: Future Electrochemical Energy Storage of Choice?]

Journal Article · · ACS Energy Letters

Metal-air batteries have much higher theoretical energy density than lithium-ion batteries, and are frequently advocated as the solution toward next-generation electrochemical energy storage for applications including electric vehicles or grid energy storage. Yet they have not fulfilled their full potentials as limited by challenges associated with the metal anode, air cathode and electrolyte. These challenges would have to be properly resolved before metal-air batteries can become a practical reality and be deployed on a large scale. Here we survey the current status and latest advances in metal-air battery research for both aqueous (e.g. Zn-air) and non-aqueous (e.g. Li-air) systems. The general technical issues confronting their developments are overviewed, and our perspective on possible solutions is offered.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1373737
Journal Information:
ACS Energy Letters, Vol. 2, Issue 6; ISSN 2380-8195
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 516 works
Citation information provided by
Web of Science

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  • Ottakam Thotiyl, Muhammed M.; Freunberger, Stefan A.; Peng, Zhangquan
  • Journal of the American Chemical Society, Vol. 135, Issue 1, p. 494-500 https://doi.org/10.1021/ja310258x
journal December 2012
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Antimony‐ and Bismuth‐Based Chalcogenides for Sodium‐Ion Batteries journal August 2019
Achieving nitrogen-doped carbon/MnO 2 nanocomposites for catalyzing the oxygen reduction reaction journal January 2019
Conjugated Cobalt Polyphthalocyanine as the Elastic and Reprocessable Catalyst for Flexible Li-CO 2 Batteries journal November 2018
Hierarchical Micro‐Nano Sheet Arrays of Nickel–Cobalt Double Hydroxides for High‐Rate Ni–Zn Batteries journal February 2019
Designing Aqueous Organic Electrolytes for Zinc–Air Batteries: Method, Simulation, and Validation journal March 2020
A Game Changer: Functional Nano/Micromaterials for Smart Rechargeable Batteries journal August 2019
Molecular Engineering of a 3D Self‐Supported Electrode for Oxygen Electrocatalysis in Neutral Media journal December 2019
Influence of Al Alloying on the Electrochemical Behavior of Zn Electrodes for Zn–Air Batteries With Neutral Sodium Chloride Electrolyte journal November 2019
Flexible Zn– and Li–air batteries: recent advances, challenges, and future perspectives journal January 2017
Recent Advances in Isolated Single-Atom Catalysts for Zinc Air Batteries: A Focus Review journal October 2019
Fundamental Understanding of Water‐Induced Mechanisms in Li–O 2 Batteries: Recent Developments and Perspectives journal November 2018
Boosting the Cycle Life of Aprotic Li-O 2 Batteries via a Photo-Assisted Hybrid Li 2 O 2 -Scavenging Strategy journal December 2017
Trimetallic Sulfide Mesoporous Nanospheres as Superior Electrocatalysts for Rechargeable Zn-Air Batteries journal October 2018
Analysis on discharge behavior and performance of As- and B-doped silicon anodes in non-aqueous Si–air batteries under pulsed discharge operation journal December 2019
Interfacing Manganese Oxide and Cobalt in Porous Graphitic Carbon Polyhedrons Boosts Oxygen Electrocatalysis for Zn–Air Batteries journal July 2019
Atomic‐ and Molecular‐Level Design of Functional Metal–Organic Frameworks (MOFs) and Derivatives for Energy and Environmental Applications journal August 2019
Interfacial electron transfer of heterostructured MIL-88A/Ni(OH) 2 enhances the oxygen evolution reaction in alkaline solutions journal January 2020
Recent Advances in Materials and Design of Electrochemically Rechargeable Zinc-Air Batteries journal August 2018
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Recent Progress in Electrically Rechargeable Zinc–Air Batteries journal December 2018
Recent Advances in Metal‐Organic Framework Derivatives as Oxygen Catalysts for Zinc‐Air Batteries journal November 2018
Recent Progress in Rechargeable Potassium Batteries journal September 2018
The surface passivation of Ge(100) and Ge(111) anodes in Ge–air batteries with different doping types and concentrations journal January 2019
Metal-Organic-Framework-Derived Co Nanoparticles Deposited on N-Doped Bimodal Mesoporous Carbon Nanorods as Efficient Bifunctional Catalysts for Rechargeable Zinc−Air Batteries journal February 2018
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Hierarchical Co 3 O 4 nanorods anchored on nitrogen doped reduced graphene oxide: a highly efficient bifunctional electrocatalyst for rechargeable Zn–air batteries journal January 2020
Recent Advances in Rational Electrode Designs for High-Performance Alkaline Rechargeable Batteries journal January 2019
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Paper‐Based Microfluidics for Electrochemical Applications journal November 2019
Combined DFT and Differential Electrochemical Mass Spectrometry Investigation of the Effect of Dopants in Secondary Zinc–Air Batteries journal March 2018
Review of energy storage and transportation of energy journal May 2019
Advanced Architectures and Relatives of Air Electrodes in Zn-Air Batteries journal January 2018
Molecular Engineering of a 3D Self‐Supported Electrode for Oxygen Electrocatalysis in Neutral Media journal November 2019
Suppressing corrosion in primary aluminum–air batteries via oil displacement journal November 2018
3D Carbon Materials for Efficient Oxygen and Hydrogen Electrocatalysis journal November 2019
Enhanced Electrocatalytic Stability of Platinum Nanoparticles Supported on Sulfur-Doped Carbon using in-situ Solution Plasma journal September 2019
Transition Metal (Fe, Co, Ni) Nanoparticles on Selective Amino-N-Doped Carbon as High-Performance Oxygen Reduction Reaction Electrocatalyst journal May 2019
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