High Performance Pseudocapacitor Based on 2D Layered Metal Chalcogenide Nanocrystals

Muller, Guillaume A.; Cook, John B.; Kim, Hyung-Seok; Tolbert, Sarah H.; Dunn, Bruce

doi:10.1021/nl504764m

High Performance Pseudocapacitor Based on 2D Layered Metal Chalcogenide Nanocrystals

Journal Article · Thu Feb 05 00:00:00 EST 2015 · Nano Letters

DOI:https://doi.org/10.1021/nl504764m· OSTI ID:1370225

Muller, Guillaume A. ^[1]; Cook, John B. ^[1]; Kim, Hyung-Seok ^[1]; Tolbert, Sarah H. ^[1]; Dunn, Bruce ^[1]

Univ. of California, Los Angeles, CA (United States)

Single-layer and few-layer transition metal dichalcogenides have been extensively studied for their electronic properties, but their energy-storage potential has not been well explored. This paper describes the structural and electrochemical properties of few-layer TiS₂ nanocrystals. Here, the two-dimensional morphology leads to very different behavior, compared to corresponding bulk materials. Only small structural changes occur during lithiation/delithiation and charge storage characteristics are consistent with intercalation pseudocapacitance, leading to materials that exhibit both high energy and power density.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Molecularly Engineered Energy Materials (MEEM)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-76SF00515; SC0001342

OSTI ID:: 1370225

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 3 Vol. 15; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Layer Structured Materials for Advanced Energy Storage and Conversion Guo, Yanpeng; Wei, Yaqing; Li, Huiqiao Small, Vol. 13, Issue 45 https://doi.org/10.1002/smll.201701649	journal	September 2017
Enabling Flexible Heterostructures for Li-Ion Battery Anodes Based on Nanotube and Liquid-Phase Exfoliated 2D Gallium Chalcogenide Nanosheet Colloidal Solutions Zhang, Chuanfang John; Park, Sang-Hoon; Ronan, Oskar Small, Vol. 13, Issue 34 https://doi.org/10.1002/smll.201701677	journal	July 2017
High-Performance Aqueous Zinc-Ion Battery Based on Layered H ₂ V ₃ O ₈ Nanowire Cathode He, Pan; Quan, Yueli; Xu, Xu Small, Vol. 13, Issue 47 https://doi.org/10.1002/smll.201702551	journal	November 2017
Toward High Power‐High Energy Sodium Cathodes: A Case Study of Bicontinuous Ordered Network of 3D Porous Na ₃ (VO) ₂ (PO ₄ ) ₂ F/rGO with Pseudocapacitance Effect Zhang, Zhibo; Chen, Zhihao; Mai, Zhaoxu Small, Vol. 15, Issue 14 https://doi.org/10.1002/smll.201900356	journal	February 2019
General and Scalable Solid-State Synthesis of 2D MPS ₃ (M = Fe, Co, Ni) Nanosheets and Tuning Their Li/Na Storage Properties Liang, Qinghua; Zheng, Yun; Du, Chengfeng Small Methods, Vol. 1, Issue 12 https://doi.org/10.1002/smtd.201700304	journal	November 2017
One-step hydrothermal synthesis of GQDs-MoS2 nanocomposite with enhanced supercapacitive performance Moghimian, Sara; Sangpour, Parvaneh Journal of Applied Electrochemistry, Vol. 50, Issue 1 https://doi.org/10.1007/s10800-019-01366-3	journal	November 2019
Interface-modulated fabrication of hierarchical yolk–shell Co3O4/C dodecahedrons as stable anodes for lithium and sodium storage Wu, Yuzhu; Meng, Jiashen; Li, Qi Nano Research, Vol. 10, Issue 7 https://doi.org/10.1007/s12274-017-1433-6	journal	April 2017
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x Kim, Hyung-Seok; Cook, John B.; Lin, Hao Nature Materials, Vol. 16, Issue 4 https://doi.org/10.1038/nmat4810	journal	December 2016
Achieving high energy density and high power density with pseudocapacitive materials Choi, Christopher; Ashby, David S.; Butts, Danielle M. Nature Reviews Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41578-019-0142-z	journal	October 2019
Self-assembled flower-like ZnCo ₂ O ₄ hierarchical superstructures for high capacity supercapacitors Ratha, Satyajit; Rout, Chandra Sekhar RSC Advances, Vol. 5, Issue 105 https://doi.org/10.1039/c5ra15272k	journal	January 2015
Sodium-ion storage performance of hierarchically structured (Co _1/3 Fe _2/3 )Se ₂ nanofibers with fiber-in-tube nanostructures Hong, Young Jun; Kim, Jung Hyun; Chan Kang, Yun Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/c6ta07354a	journal	January 2016
Methyl-functionalized MoS ₂ nanosheets with reduced lattice breathing for enhanced pseudocapacitive sodium storage Huang, Lei; Wei, Qiulong; Xu, Xiaoming Physical Chemistry Chemical Physics, Vol. 19, Issue 21 https://doi.org/10.1039/c7cp00990a	journal	January 2017
Correlation of montmorillonite exfoliation with interlayer cations in the preparation of two-dimensional nanosheets Zhang, Xian; Yi, Hao; Bai, Haoyu RSC Advances, Vol. 7, Issue 66 https://doi.org/10.1039/c7ra07816a	journal	January 2017
Oriented SnS nanoflakes bound on S-doped N-rich carbon nanosheets with a rapid pseudocapacitive response as high-rate anodes for sodium-ion batteries Sheng, Jian; Yang, Leping; Zhu, Yuan-En Journal of Materials Chemistry A, Vol. 5, Issue 37 https://doi.org/10.1039/c7ta06577a	journal	January 2017
Pseudocapacitance contribution in boron-doped graphite sheets for anion storage enables high-performance sodium-ion capacitors Yu, Feng; Liu, Zaichun; Zhou, Renwu Materials Horizons, Vol. 5, Issue 3 https://doi.org/10.1039/c8mh00156a	journal	January 2018
Template-assisted in situ confinement synthesis of nitrogen and oxygen co-doped 3D porous carbon network for high-performance sodium-ion battery anode Wang, Dan; Wang, Zhiyuan; Li, Yuan New Journal of Chemistry, Vol. 42, Issue 17 https://doi.org/10.1039/c8nj02394h	journal	January 2018
Fresh MoO ₂ as a better electrode for pseudocapacitive sodium-ion storage Zhao, Xu; Zhao, Yundong; Yang, Ying New Journal of Chemistry, Vol. 42, Issue 18 https://doi.org/10.1039/c8nj03570a	journal	January 2018
Morphological evolution of hollow NiCo ₂ O ₄ microspheres and their high pseudocapacitance contribution for Li/Na-ion battery anodes Dong, Kangze; Wang, Zhiyuan; Wang, Dan New Journal of Chemistry, Vol. 42, Issue 21 https://doi.org/10.1039/c8nj03965h	journal	January 2018
Hierarchical self-assembled Bi ₂ S ₃ hollow nanotubes coated with sulfur-doped amorphous carbon as advanced anode materials for lithium ion batteries Dong, Yucheng; Hu, Mingjun; Zhang, Zhenyu Nanoscale, Vol. 10, Issue 28 https://doi.org/10.1039/c8nr04685a	journal	January 2018
Fast Li ⁺ diffusion in interlayer-expanded vanadium disulfide nanosheets for Li ⁺ /Mg ²⁺ hybrid-ion batteries Meng, Yuan; Zhao, Yingying; Wang, Dashuai Journal of Materials Chemistry A, Vol. 6, Issue 14 https://doi.org/10.1039/c8ta00418h	journal	January 2018
Rational design of forest-like nickel sulfide hierarchical architectures with ultrahigh areal capacity as a binder-free cathode material for hybrid supercapacitors Rama Raju, G. Seeta; Pavitra, E.; Nagaraju, Goli Journal of Materials Chemistry A, Vol. 6, Issue 27 https://doi.org/10.1039/c8ta02597e	journal	January 2018
Ultrafast lithium energy storage enabled by interfacial construction of interlayer-expanded MoS ₂ /N-doped carbon nanowires Sun, Huanhuan; Wang, Jian-Gan; Zhang, Yu Journal of Materials Chemistry A, Vol. 6, Issue 27 https://doi.org/10.1039/c8ta04852e	journal	January 2018
Template-free solvothermal preparation of ternary FeNi ₂ S ₄ hollow balloons as RuO ₂ -like efficient electrocatalysts for the oxygen evolution reaction with superior stability Wang, He; Tang, Jianhua; Li, Yinle Journal of Materials Chemistry A, Vol. 6, Issue 40 https://doi.org/10.1039/c8ta06051g	journal	January 2018
Facile synthesis of N,O-codoped hard carbon on the kilogram scale for fast capacitive sodium storage Huang, Man; Xi, Baojuan; Feng, Zhenyu Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/c8ta06160b	journal	January 2018
Insights into the intrinsic capacity of interlayer-expanded MoS ₂ as a Li-ion intercalation host Gong, Shan; Zhao, Guangyu; Lyu, Pengbo Journal of Materials Chemistry A, Vol. 7, Issue 3 https://doi.org/10.1039/c8ta08120d	journal	January 2019
Embedding heterostructured MnS/Co _1−x S nanoparticles in porous carbon/graphene for superior lithium storage Li, Baosheng; Wang, Ruirui; Chen, Ziliang Journal of Materials Chemistry A, Vol. 7, Issue 3 https://doi.org/10.1039/c8ta09740b	journal	January 2019
Embedding CoO nanoparticles in a yolk–shell N-doped porous carbon support for ultrahigh and stable lithium storage Wang, Shuhai; Teng, Jun; Xie, Yanyu Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta11007g	journal	January 2019
A Mn ₃ O ₄ nanospheres@rGO architecture with capacitive effects on high potassium storage capability Nithya, Chandrasekaran; Vishnuprakash, Palanivelu; Gopukumar, Sukumaran Nanoscale Advances, Vol. 1, Issue 11 https://doi.org/10.1039/c9na00425d	journal	January 2019
Recent trends in transition metal dichalcogenide based supercapacitor electrodes Cherusseri, Jayesh; Choudhary, Nitin; Sambath Kumar, Kowsik Nanoscale Horizons, Vol. 4, Issue 4 https://doi.org/10.1039/c9nh00152b	journal	January 2019
(Co, Mn)-Doped NiSe ₂ -diethylenetriamine (dien) nanosheets and (Co, Mn, Sn)-doped NiSe ₂ nanowires for high performance supercapacitors: compositional/morphological evolution and (Co, Mn)-induced electron transfer Dan, Huamei; Tao, Keyu; Hai, Yang Nanoscale, Vol. 11, Issue 36 https://doi.org/10.1039/c9nr04478g	journal	January 2019
Towards fast-charging technologies in Li ⁺ /Na ⁺ storage: from the perspectives of pseudocapacitive materials and non-aqueous hybrid capacitors Huang, Haijian; Niederberger, Markus Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr05732c	journal	January 2019
Ultrastable Li-ion battery anodes by encapsulating SnS nanoparticles in sulfur-doped graphene bubble films Zhao, Bing; Song, Daiyun; Ding, Yanwei Nanoscale, Vol. 12, Issue 6 https://doi.org/10.1039/c9nr10608a	journal	January 2020
Nitrogen-enriched carbon-coated flower-like bismuth sulfide architectures towards high-performance lithium-ion battery anodes Wang, Shuwen; Li, Wenda; Song, Haochen Inorganic Chemistry Frontiers, Vol. 6, Issue 5 https://doi.org/10.1039/c9qi00062c	journal	January 2019
In Operando analysis of the charge storage mechanism in a conversion ZnCo ₂ O ₄ anode and the application in flexible Li-ion batteries Zhao, Zijian; Tian, Guiying; Trouillet, Vanessa Inorganic Chemistry Frontiers, Vol. 6, Issue 7 https://doi.org/10.1039/c9qi00356h	journal	January 2019
Understanding the Li-ion storage mechanism in a carbon composited zinc sulfide electrode Tian, Guiying; Zhao, Zijian; Sarapulova, Angelina Journal of Materials Chemistry A, Vol. 7, Issue 26 https://doi.org/10.1039/c9ta01382b	journal	January 2019
Co ₉ S ₈ embedded into N/S doped carbon composites: in situ derivation from a sulfonate-based metal–organic framework and its electrochemical properties Chen, Lin; Yang, Wenjuan; Li, Xiaoyu Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta01433k	journal	January 2019
Rechargeable Zn-ion batteries with high power and energy densities: a two-electron reaction pathway in birnessite MnO ₂ cathode materials Li, Guanzhou; Huang, Zongxiong; Chen, Jinbiao Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta11985j	journal	January 2020
A stable and high-energy hybrid supercapacitor using porous Cu ₂ O–Cu _1.8 S nanowire arrays Esfandiar, Ali; Qorbani, Mohammad; Shown, Indrajit Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta12675a	journal	January 2020
Mechanistic understanding of monovalent cation transport in eumelanin pigments Tian, Zhen; Hwang, Wonseok; Kim, Young Jo Journal of Materials Chemistry B, Vol. 7, Issue 41 https://doi.org/10.1039/c9tb01211g	journal	January 2019
First principles investigation of copper and silver intercalated molybdenum disulfide Guzman, D. M.; Onofrio, N.; Strachan, A. Journal of Applied Physics, Vol. 121, Issue 5 https://doi.org/10.1063/1.4975035	journal	February 2017
In-situ synthesis of Ni–Co–S nanoparticles embedded in novel carbon bowknots and flowers with pseudocapacitance-boosted lithium ion storage Yang, Tao; Yang, Dexin; Mao, Qinan Nanotechnology, Vol. 30, Issue 15 https://doi.org/10.1088/1361-6528/aafe42	journal	February 2019
Graphene oxide wrapped Cu ₃ V ₂ O ₇ (OH) ₂ · 2H ₂ O nanocomposite with enhanced electrochemical performance for lithium-ion storage Li, Malin; Wei, Zhixuan; Wang, Dongxue Nanotechnology, Vol. 30, Issue 18 https://doi.org/10.1088/1361-6528/aafec3	journal	February 2019
Solution phase synthesis of large-area ultra-thin two dimensional layered Bi ₂ Se ₃ : role of Cu-intercalation and substitution Pradhan, Bapi; Dalui, Amit; Paul, Susmita Materials Research Express, Vol. 6, Issue 12 https://doi.org/10.1088/2053-1591/ab63fd	journal	December 2019
Method Comparison for Deconvoluting Capacitive and Pseudo-Capacitive Contributions to Electrochemical Capacitor Electrode Behavior Forghani, Marveh; Donne, Scott W. Journal of The Electrochemical Society, Vol. 165, Issue 3 https://doi.org/10.1149/2.0931803jes	journal	January 2018
Gyroidal Niobium Sulfide/Carbon Hybrid Monoliths for Electrochemical Energy Storage Fleischmann, Simon; Dörr, Tobias S.; Frank, Anna Universität des Saarlandes https://doi.org/10.22028/d291-28795	collection	January 2019
Understanding the Li-ion storage mechanism in a carbon composited zinc sulfide electrode Tian, Guiying; Zhao, Zijian; Sarapulova, Angelina Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2020-00236	text	January 2019
Towards fast-charging technologies in Li+/Na+ storage: from the perspectives of pseudocapacitive materials and non-aqueous hybrid capacitors Huang, Haijian; Niederberger, Markus ETH Zurich https://doi.org/10.3929/ethz-b-000373418	text	January 2019
Understanding the Li-ion storage mechanism in a carbon composited zinc sulfide electrode Tian, Guiying; Zhao, Zijian; Sarapulova, Angelina Karlsruhe https://doi.org/10.5445/ir/1000093972	text	January 2019
Electrochemical and Structural Investigation of Calcium Substituted Monoclinic Li3V2(PO4)3 Anode Materials for Li‐Ion Batteries Fu, Qiang; Liu, Shuoqi; Sarapulova, Angelina Karlsruhe https://doi.org/10.5445/ir/1000097048	text	January 2019
Superior Lithium Storage Capacity of α‐MnS Nanoparticles Embedded in S‐Doped Carbonaceous Mesoporous Frameworks Ma, Yuan; Ma, Yanjiao; Kim, Guk‐Tae Karlsruhe https://doi.org/10.5445/ir/1000098869	text	January 2019

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36 MATERIALS SCIENCE
TiS2
chalcogenides
diffusion
electrochemical energy storage
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intercalation kinetics
lattices
lithium
materials
nanocrystals
pseudocapacitors

High Performance Pseudocapacitor Based on 2D Layered Metal Chalcogenide Nanocrystals

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