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Title: A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores (in German)

Journal Article · · Angewandte Chemie
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Abstract Through topological rationalization, a zeotype mesoporous Zr‐containing metal–organic framework (MOF), namely PCN‐777, has been designed and synthesized. PCN‐777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm 3  g −1 among reported Zr‐MOFs. Moreover, PCN‐777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN‐777 and different guests can be varied to realize efficient immobilization.

Sponsoring Organization:
USDOE
Grant/Contract Number:
DE‐AC02‐06CH11357
OSTI ID:
1367689
Journal Information:
Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 127 Journal Issue: 1; ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
German

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