A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores

Feng, Dawei; Wang, Kecheng; Su, Jie; Liu, Tian‐Fu; Park, Jihye; Wei, Zhangwen; Bosch, Mathieu; Yakovenko, Andrey; Zou, Xiaodong; Zhou, Hong‐Cai

doi:10.1002/anie.201409334

A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores

Journal Article · Mon Nov 10 00:00:00 EST 2014 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201409334· OSTI ID:1400672

Feng, Dawei; Wang, Kecheng; Su, Jie; Liu, Tian‐Fu; Park, Jihye; Wei, Zhangwen; Bosch, Mathieu; Yakovenko, Andrey; Zou, Xiaodong; Zhou, Hong‐Cai

Abstract

Through topological rationalization, a zeotype mesoporous Zr‐containing metal–organic framework (MOF), namely PCN‐777, has been designed and synthesized. PCN‐777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm ³ g ⁻¹ among reported Zr‐MOFs. Moreover, PCN‐777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN‐777 and different guests can be varied to realize efficient immobilization.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1400672

Alternate ID(s):: OSTI ID: 1239628

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 1 Vol. 54; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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