First analysis of the rotationally-resolved ν 2 and 2 ν 2 - ν 2 bands of sulfur dioxide, 33 S 16 O 2

Blake, T. A.; Flaud, J. -M.; Lafferty, W. J.

doi:10.1016/j.jms.2016.12.011

First analysis of the rotationally-resolved ν 2 and 2 ν 2 - ν 2 bands of sulfur dioxide, 33 S 16 O 2

Journal Article · Wed Mar 01 04:00:00 EST 2017 · Journal of Molecular Spectroscopy

DOI:https://doi.org/10.1016/j.jms.2016.12.011· OSTI ID:1361952

Blake, T. A.; Flaud, J. -M.; Lafferty, W. J.

A Fourier transform spectrum of sulfur dioxide 33S16O2 has been recorded in the 18.3 µm spectral region at a resolution of 0.002 cm-1 using a Bruker IFS 125HR spectrometer leading to the observation of the ν2 and 2ν2- ν2 vibrational bands of the 33S16O2 molecule. The corresponding upper state ro-vibrational levels were fit using Watson-type Hamiltonians. In this way it was possible to reproduce the upper state ro-vibrational levels to within the experimental uncertainty; i.e., ~0.20 x 10-3 cm-1. Very accurate rotational and centrifugal distortion constants were derived from the fit together with the following band centers: ν0 (ν2) =515.659089(50) cm-1, ν0 (2ν2) = 1030.697723(20) cm-1.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (US)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1361952

Report Number(s):: PNNL-SA-120751

Journal Information:: Journal of Molecular Spectroscopy, Journal Name: Journal of Molecular Spectroscopy Vol. 333; ISSN 0022-2852

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

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