First analysis of the rotationally-resolved ν2 and 2ν2-ν2 bands of sulfur dioxide, 33S16O2

Blake, T. A.; Flaud, J. -M.; Lafferty, W. J.

doi:10.1016/j.jms.2016.12.011

First analysis of the rotationally-resolved ν₂ and 2ν₂-ν₂ bands of sulfur dioxide, ³³S¹⁶O₂

Journal Article · Tue Jan 03 00:00:00 EST 2017 · Journal of Molecular Spectroscopy

DOI:https://doi.org/10.1016/j.jms.2016.12.011· OSTI ID:1341741

Blake, T. A. ^[1]; Flaud, J. -M. ^[2]; Lafferty, W. J. ^[3]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Univ. Paris-Est Creteil (UPEC), Paris (France); Univ. of Paris Diderot (France); Inst. Pierre Simon Laplace (France)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)

A Fourier transform spectrum of sulfur dioxide ³³S¹⁶O₂ has been recorded in the 18.3 μm spectral region at a resolution of 0.002 cm^$$-$$1 using a Bruker IFS 125HR spectrometer leading to the observation of the ν₂ and 2ν₂-ν₂ vibrational bands of the ³³S¹⁶O₂ molecule. The corresponding upper state ro-vibrational levels were fit using Watson-type Hamiltonians. In this way it was possible to reproduce the upper state ro-vibrational levels to within the experimental uncertainty; i.e., ~ 0.20 × 10^$$-$$3 cm^$$-$$1. Finally, very accurate rotational and centrifugal distortion constants were derived from the fit together with the following band centers: ν₀ (ν₂) = 515.659089(50) cm^$$-$$1, ν₀ (2ν₂) = 1030.697723(20) cm^$$-$$1.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1341741

Alternate ID(s):: OSTI ID: 1411836
OSTI ID: 1361952

Report Number(s):: PNNL-SA--120751; PII: S0022285216302211

Journal Information:: Journal of Molecular Spectroscopy, Journal Name: Journal of Molecular Spectroscopy Journal Issue: C Vol. 333; ISSN 0022-2852

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Isotope shifts and band progressions in SO ₂ rovibrational energy levels: using quantum theory to extract rotational constants Kumar, Praveen; Poirier, Bill Molecular Physics, Vol. 117, Issue 18 https://doi.org/10.1080/00268976.2019.1567850	journal	January 2019

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Related Subjects

36 MATERIALS SCIENCE
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY
High resolution Fourier transform infrared spectroscopy
Ro-vibrational constants
Sulfur dioxide
Sulfur-33 isotope