Magnetically Recoverable Pd/Fe3O4 Core-Shell Nanowire Clusters with Increased Hydrogenation Activity

Watt, John; Kotula, Paul G.; Huber, Dale L.

doi:10.1002/cplu.201700009

Title: Magnetically Recoverable Pd/Fe₃O₄ Core-Shell Nanowire Clusters with Increased Hydrogenation Activity

Journal Article · Mon Feb 06 00:00:00 EST 2017 · ChemPlusChem

DOI:https://doi.org/10.1002/cplu.201700009· OSTI ID:1356218

Watt, John ^[1]; Kotula, Paul G. ^[1]; Huber, Dale L. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Abstract Core–shell nanostructures are promising candidates for the next generation of catalysts due to synergistic effects which can arise from having two active species in close contact, leading to increased activity. Likewise, catalysts displaying added functionality, such as a magnetic response, can have increased scientific and industrial potential. Here, Pd/Fe ₃ O ₄ core–shell nanowire clusters are synthesized and applied as hydrogenation catalysts for an industrially important hydrogenation reaction: the conversion of acetophenone to 1‐phenylethanol. During synthesis, the palladium nanowires self‐assemble into clusters which act as a high‐surface‐area framework for the growth of a magnetic iron oxide shell. This material demonstrates excellent catalytic activity due to the presence of palladium while the strong magnetic properties provided by the iron oxide shell enable facile catalyst recovery.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1356218

Alternate ID(s):: OSTI ID: 1401749

Report Number(s):: SAND-2017-2638J; 651634

Journal Information:: ChemPlusChem, Vol. 82, Issue 3; ISSN 2192-6506

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

References (38)

Synthesis and catalytic properties of highly branched palladium nanostructures using seeded growth Graham, L.; Collins, G.; Holmes, J. D. Nanoscale, Vol. 8, Issue 5 https://doi.org/10.1039/C5NR07413D	journal	January 2016
Magnetically Separable Nanocatalysts: Bridges between Homogeneous and Heterogeneous Catalysis Shylesh, Sankaranarayanapillai; Schünemann, Volker; Thiel, Werner R. Angewandte Chemie International Edition, Vol. 49, Issue 20 https://doi.org/10.1002/anie.200905684	journal	April 2010
Magnetically Recoverable Palladium(0) Nanocomposite Catalyst for Hydrogenation Reactions in Water Pélisson, Carl-Hugo; Denicourt-Nowicki, Audrey; Meriadec, Cristelle ChemCatChem, Vol. 7, Issue 2 https://doi.org/10.1002/cctc.201402761	journal	November 2014
Palladium Nanoparticles Encapsulated in Core–Shell Silica: A Structured Hydrogenation Catalyst with Enhanced Activity for Reduction of Oxyanion Water Pollutants Wang, Yin; Liu, Jinyong; Wang, Peng ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs500971r	journal	September 2014
A stepwise loading method to magnetically responsive Pt-Fe3O4/MCNT catalysts for selective hydrogenation of 3-methylcrotonaldehyde Song, Shaofei; Yu, Jianyan; Xiao, Qiang Nanoscale Research Letters, Vol. 9, Issue 1 https://doi.org/10.1186/1556-276X-9-677	journal	January 2014
Gold-Palladium Core-Shell Nanocrystals with Size and Shape Control Optimized for Catalytic Performance Henning, Anna M.; Watt, John; Miedziak, Peter J. Angewandte Chemie International Edition, Vol. 52, Issue 5 https://doi.org/10.1002/anie.201207824	journal	December 2012
Benzene Formation at 70 °C by Coupling of Propylene on Supported Pd Nanoclusters Chou, Ju; Zhang, Siyan; Sun, Shouli Angewandte Chemie International Edition, Vol. 44, Issue 30 https://doi.org/10.1002/anie.200500022	journal	July 2005
Highly Active and Sinter-Resistant Pd-Nanoparticle Catalysts Encapsulated in Silica Park, Jung-Nam; Forman, Arnold J.; Tang, Wei Small, Vol. 4, Issue 10 https://doi.org/10.1002/smll.200800895	journal	October 2008
Heterogenized Bimetallic Pd–Pt–Fe ₃ O ₄ Nanoflakes as Extremely Robust, Magnetically Recyclable Catalysts for Chemoselective Nitroarene Reduction Byun, Sangmoon; Song, Yeami; Kim, B. Moon ACS Applied Materials & Interfaces, Vol. 8, Issue 23 https://doi.org/10.1021/acsami.6b05229	journal	June 2016
The Reaction of Metal Carbonyls and Amines. I. Iron Carbonyl with Piperidine and n-Butylamine. The Initial Stages of the Reaction ^1,2 Edgell, Walter F.; Yang, Meiling T.; Bulkin, Bernard J. Journal of the American Chemical Society, Vol. 87, Issue 14 https://doi.org/10.1021/ja01092a012	journal	July 1965
Immobilised lipase-catalysed resolution of (R,S)-1-phenylethanol in recirculated packed bed reactor Chua, Lee Suan; Sarmidi, Mohamad Roji Journal of Molecular Catalysis B: Enzymatic, Vol. 28, Issue 2-3 https://doi.org/10.1016/j.molcatb.2004.02.004	journal	May 2004
A Magnetically Recyclable Nanocomposite Catalyst for Olefin Epoxidation Shokouhimehr, Mohammadreza; Piao, Yuanzhe; Kim, Jaeyun Angewandte Chemie International Edition, Vol. 46, Issue 37 https://doi.org/10.1002/anie.200702386	journal	September 2007
Recent Developments in Palladium-Based Bimetallic Catalysts Liao, Fenglin; Lo, Tsz Woon Benedict; Tsang, Shik Chi Edman ChemCatChem, Vol. 7, Issue 14 https://doi.org/10.1002/cctc.201500245	journal	June 2015
Pd nanoparticles embedded in sponge-like porous silica as a Suzuki–Miyaura catalyst: Similarities and differences with homogeneous catalysts Budroni, G.; Corma, A.; Garcia, H. Journal of Catalysis, Vol. 251, Issue 2 https://doi.org/10.1016/j.jcat.2007.07.027	journal	October 2007
Iron-iron oxide core–shell nanoparticles are active and magnetically recyclable olefin and alkyne hydrogenation catalysts in protic and aqueous media Hudson, Reuben; Rivière, Antoine; Cirtiu, Ciprian M. Chemical Communications, Vol. 48, Issue 27 https://doi.org/10.1039/c2cc16438h	journal	January 2012
Ultrafast Growth of Highly Branched Palladium Nanostructures for Catalysis Watt, John; Cheong, Soshan; Toney, Michael F. ACS Nano, Vol. 4, Issue 1 https://doi.org/10.1021/nn901277k	journal	December 2009
Magnetically retrievable catalysts for asymmetric synthesis Nasir Baig, R. B.; Nadagouda, Mallikarjuna N.; Varma, Rajender S. Coordination Chemistry Reviews, Vol. 287 https://doi.org/10.1016/j.ccr.2014.12.017	journal	March 2015
Catalytic and kinetic study of the liquid-phase hydrogenation of acetophenone over Cu/SiO2 catalyst Bertero, Nicolás M.; Apesteguía, Carlos R.; Marchi, Alberto J. Applied Catalysis A: General, Vol. 349, Issue 1-2 https://doi.org/10.1016/j.apcata.2008.07.014	journal	October 2008
Designing bimetallic catalysts for a green and sustainable future Sankar, Meenakshisundaram; Dimitratos, Nikolaos; Miedziak, Peter J. Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35296f	journal	January 2012
Synthesis and Structural Characterization of Branched Palladium Nanostructures Watt, John; Young, Neil; Haigh, Sarah Advanced Materials, Vol. 21, Issue 22 https://doi.org/10.1002/adma.200900272	journal	June 2009
Enhanced Nanoparticle Size Control by Extending LaMer’s Mechanism Vreeland, Erika C.; Watt, John; Schober, Gretchen B. Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02510	journal	August 2015
Benzene Formation at 70 °C by Coupling of Propylene on Supported Pd Nanoclusters Chou, Ju; Zhang, Siyan; Sun, Shouli Angewandte Chemie, Vol. 117, Issue 30 https://doi.org/10.1002/ange.200500022	journal	July 2005
The use of ultrasmall iron(0) nanoparticles as catalysts for the selective hydrogenation of unsaturated C–C bonds Kelsen, Vinciane; Wendt, Bianca; Werkmeister, Svenja Chemical Communications, Vol. 49, Issue 33 https://doi.org/10.1039/c3cc00152k	journal	January 2013
Gold-Palladium Core-Shell Nanocrystals with Size and Shape Control Optimized for Catalytic Performance Henning, Anna M.; Watt, John; Miedziak, Peter J. Angewandte Chemie, Vol. 125, Issue 5 https://doi.org/10.1002/ange.201207824	journal	December 2012
A Highly Water-Dispersible/Magnetically Separable Palladium Catalyst: Selective Transfer Hydrogenation or Direct Reductive N-Formylation of Nitroarenes in Water Karimi, Babak; Mansouri, Fariborz; Vali, Hojatollah ChemPlusChem, Vol. 80, Issue 12 https://doi.org/10.1002/cplu.201500302	journal	August 2015
Nano-magnetite (Fe3O4) as a support for recyclable catalysts in the development of sustainable methodologies Gawande, Manoj B.; Branco, Paula S.; Varma, Rajender S. Chemical Society Reviews, Vol. 42, Issue 8 https://doi.org/10.1039/c3cs35480f	journal	January 2013
Effect of Pd Nanoparticle Size on the Catalytic Hydrogenation of Allyl Alcohol Wilson, Orla M.; Knecht, Marc R.; Garcia-Martinez, Joaquin C. Journal of the American Chemical Society, Vol. 128, Issue 14, p. 4510-4511 https://doi.org/10.1021/ja058217m	journal	April 2006
Shape-Controlled Synthesis of Metal Nanostructures: The Case of Palladium Xiong, Y.; Xia, Y. Advanced Materials, Vol. 19, Issue 20 https://doi.org/10.1002/adma.200701301	journal	September 2007
Reaktionen von Eisencarbonylen mit Ammoniak: Hexammin-Eisen(II)-Carbonylferrate Hieber, Walter; Werner, Robert Chemische Berichte, Vol. 90, Issue 6 https://doi.org/10.1002/cber.19570900635	journal	June 1957
Highly Stable Amine Functionalized Iron Oxide Nanoparticles Designed for Magnetic Particle Imaging (MPI) Arami, Hamed; Krishnan, Kannan M. IEEE Transactions on Magnetics, Vol. 49, Issue 7 https://doi.org/10.1109/TMAG.2013.2245110	journal	July 2013
Liquid phase acetophenone hydrogenation on Ru/Cr/B catalysts supported on silica Casagrande, Manuela; Storaro, Loretta; Talon, Aldo Journal of Molecular Catalysis A: Chemical, Vol. 188, Issue 1-2 https://doi.org/10.1016/S1381-1169(02)00079-1	journal	September 2002
Activity, selectivity and stability of Ni and bimetallic Ni–Pt supported on zeolite Y catalysts for hydrogenation of acetophenone and its substituted derivatives Malyala, R. V.; Rode, C. V.; Arai, M. Applied Catalysis A: General, Vol. 193, Issue 1-2 https://doi.org/10.1016/S0926-860X(99)00442-1	journal	February 2000
Synthesis and Stability of Highly Crystalline and Stable Iron/Iron Oxide Core/Shell Nanoparticles for Biomedical Applications Cheong, Soshan; Ferguson, Peter; Hermans, Ian F. ChemPlusChem, Vol. 77, Issue 2 https://doi.org/10.1002/cplu.201100074	journal	January 2012
Kinetic resolution of both 1-phenylethanol enantiomers produced by hydrolysis of 1-phenylethyl acetate with Candida antarctica lipase B in different solvent systems Fan, Yongxian; Xie, Zhangming; Zhang, Huawei Kinetics and Catalysis, Vol. 52, Issue 5 https://doi.org/10.1134/S0023158411050065	journal	September 2011
A Magnetically Recyclable Nanocomposite Catalyst for Olefin Epoxidation Shokouhimehr, Mohammadreza; Piao, Yuanzhe; Kim, Jaeyun Angewandte Chemie, Vol. 119, Issue 37 https://doi.org/10.1002/ange.200702386	journal	September 2007
Magnetisch abtrennbare Nanokatalysatoren: Brücken zwischen homogener und heterogener Katalyse Shylesh, Sankaranarayanapillai; Schünemann, Volker; Thiel, Werner R. Angewandte Chemie, Vol. 122, Issue 20 https://doi.org/10.1002/ange.200905684	journal	April 2010
On the role of surface diffusion in determining the shape or morphology of noble-metal nanocrystals Xia, X.; Xie, S.; Liu, M. Proceedings of the National Academy of Sciences, Vol. 110, Issue 17 https://doi.org/10.1073/pnas.1222109110	journal	April 2013
Improving the catalytic performances of metal nanoparticles by combining shape control and encapsulation Martins, J.; Batail, N.; Silva, S. Applied Catalysis A: General, Vol. 504 https://doi.org/10.1016/j.apcata.2014.11.034	journal	September 2015

Similar Records

Confined Ultrathin Pd‐Ce Nanowires with Outstanding Moisture and SO ₂ Tolerance in Methane Combustion

Journal Article · Tue Jun 12 00:00:00 EDT 2018 · Angewandte Chemie · OSTI ID:1356218

Peng, Honggen; Rao, Cheng; Zhang, Ning; +6 more

Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO₂ Tolerance in Methane Combustion

Journal Article · Tue May 22 00:00:00 EDT 2018 · Angewandte Chemie (International Edition) · OSTI ID:1356218

Peng, Honggen; Rao, Cheng; Zhang, Ning; +6 more

Reactivity of Pd–MO₂ encapsulated catalytic systems for CO oxidation

Journal Article · Thu Jan 20 00:00:00 EST 2022 · Catalysis Science and Technology · OSTI ID:1356218

Paz Herrera, Laura; Freitas de Lima e Freitas, Lucas; Hong, Jiyun; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Magnetically Recoverable Pd/Fe3O4 Core-Shell Nanowire Clusters with Increased Hydrogenation Activity

Citation Formats

References (38)

Similar Records

Related Subjects

Title: Magnetically Recoverable Pd/Fe₃O₄ Core-Shell Nanowire Clusters with Increased Hydrogenation Activity