Confined Ultrathin Pd‐Ce Nanowires with Outstanding Moisture and SO 2 Tolerance in Methane Combustion

Peng, Honggen; Rao, Cheng; Zhang, Ning; Wang, Xiang; Liu, Wenming; Mao, Wenting; Han, Lu; Zhang, Pengfei; Dai, Sheng

doi:10.1002/ange.201803393

Title: Confined Ultrathin Pd‐Ce Nanowires with Outstanding Moisture and SO ₂ Tolerance in Methane Combustion

Journal Article · Tue Jun 12 00:00:00 EDT 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201803393· OSTI ID:1460458

Peng, Honggen ^[1]; Rao, Cheng ^[2]; Zhang, Ning ^[2]; Wang, Xiang ^[2]; Liu, Wenming ^[2]; Mao, Wenting ^[3];

^[3]; Zhang, Pengfei ^[4];

^[5]

Institute of Applied Chemistry College of Chemistry Nanchang University Nanchang 330031 P. R. China, Chemical Sciences Division Oak Ridge National Laboratory Oak Ridge TN 37830 USA
Institute of Applied Chemistry College of Chemistry Nanchang University Nanchang 330031 P. R. China
School of Chemistry and Chemical Engineering Shanghai Jiao Tong University Shanghai 200240 P. R. China
School of Chemistry and Chemical Engineering Shanghai Jiao Tong University Shanghai 200240 P. R. China, Department of Chemistry University of Tennessee Knoxville TN 37996 USA
Chemical Sciences Division Oak Ridge National Laboratory Oak Ridge TN 37830 USA, Department of Chemistry University of Tennessee Knoxville TN 37996 USA

Abstract An efficient strategy (enhanced metal oxide interaction and core–shell confinement to inhibit the sintering of noble metal) is presented confined ultrathin Pd‐CeO _x nanowire (2.4 nm) catalysts for methane combustion, which enable CH ₄ total oxidation at a low temperature of 350 °C, much lower than that of a commercial Pd/Al ₂ O ₃ catalyst (425 °C). Importantly, unexpected stability was observed even under harsh conditions (800 °C, water vapor, and SO ₂ ), owing to the confinement and shielding effect of the porous silica shell together with the promotion of CeO ₂ . Pd‐CeO _x solid solution nanowires (Pd‐Ce NW) as cores and porous silica as shells (Pd‐CeNW@SiO ₂ ) were rationally prepared by a facile and direct self‐assembly strategy for the first time. This strategy is expected to inspire more active and stable catalysts for use under severe conditions (vehicle emissions control, reforming, and water–gas shift reaction).

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Sponsoring Organization:: USDOE

OSTI ID:: 1460458

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 130 Journal Issue: 29; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Title: Confined Ultrathin Pd‐Ce Nanowires with Outstanding Moisture and SO ₂ Tolerance in Methane Combustion