Solution-Phase Dynamic Assembly of Permanently Interlocked Aryleneethynylene Cages through Alkyne Metathesis
Highly stable permanently interlocked aryleneethynylene molecular cages were synthesized from simple triyne monomers using dynamic alkyne metathesis. The interlocked complexes are predominantly formed in the reaction solution in the absence of any recognition motif and were isolated in a pure form using column chromatography. This study is the first example of the thermodynamically controlled solution-phase synthesis of interlocked organic cages with high stability.
- Research Organization:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- DOE Contract Number:
- AC36-08GO28308
- OSTI ID:
- 1351569
- Report Number(s):
- NREL/JA-2C00-64675
- Journal Information:
- Angewandte Chemie, Vol. 127, Issue 26; ISSN 0044-8249
- Publisher:
- German Chemical Society
- Country of Publication:
- United States
- Language:
- English
Similar Records
SolutionâPhase Dynamic Assembly of Permanently Interlocked Aryleneethynylene Cages through Alkyne Metathesis
Dynamic covalent synthesis of aryleneethynylene cages through alkyne metathesis: dimer, tetramer, or interlocked complex?
Poly(aryleneethynylene)s: Properties, Applications and Synthesis Through Alkyne Metathesis
Journal Article
·
Fri May 08 00:00:00 EDT 2015
· Angewandte Chemie
·
OSTI ID:1351569
+3 more
Dynamic covalent synthesis of aryleneethynylene cages through alkyne metathesis: dimer, tetramer, or interlocked complex?
Journal Article
·
Fri Feb 12 00:00:00 EST 2016
· Chemical Science
·
OSTI ID:1351569
+4 more
Poly(aryleneethynylene)s: Properties, Applications and Synthesis Through Alkyne Metathesis
Journal Article
·
Mon Jun 26 00:00:00 EDT 2017
· Topics in Current Chemistry
·
OSTI ID:1351569
+1 more