Solution‐Phase Dynamic Assembly of Permanently Interlocked Aryleneethynylene Cages through Alkyne Metathesis

Wang, Qi; Yu, Chao; Long, Hai; Du, Ya; Jin, Yinghua; Zhang, Wei

doi:10.1002/ange.201501679

Solution‐Phase Dynamic Assembly of Permanently Interlocked Aryleneethynylene Cages through Alkyne Metathesis (in German)

Journal Article · Fri May 08 00:00:00 EDT 2015 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201501679· OSTI ID:1786216

Wang, Qi; Yu, Chao; Long, Hai; Du, Ya; Jin, Yinghua; Zhang, Wei

Abstract

Highly stable permanently interlocked aryleneethynylene molecular cages were synthesized from simple triyne monomers using dynamic alkyne metathesis. The interlocked complexes are predominantly formed in the reaction solution in the absence of any recognition motif and were isolated in a pure form using column chromatography. This study is the first example of the thermodynamically controlled solution‐phase synthesis of interlocked organic cages with high stability.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1786216

Alternate ID(s):: OSTI ID: 1351569

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 26 Vol. 127; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: German

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