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Combining theory and experiment in electrocatalysis: Insights into materials design

Journal Article · · Science
 [1];  [2];  [3];  [4];  [3];  [3]
  1. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States); Institute of Materials Research and Engineering, Innovis (Singapore)
  2. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States); Technical Univ. of Denmark, Kongens Lyngby (Denmark)
  3. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  4. Technical Univ. of Denmark, Kongens Lyngby (Denmark)
Electrocatalysis plays a central role in clean energy conversion, enabling a number of sustainable processes for future technologies. This review discusses design strategies for state-of-the-art heterogeneous electrocatalysts and associated materials for several different electrochemical transformations involving water, hydrogen, and oxygen, using theory as a means to rationalize catalyst performance. By examining the common principles that govern catalysis for different electrochemical reactions, we describe a systematic framework that clarifies trends in catalyzing these reactions, serving as a guide to new catalyst development while highlighting key gaps that need to be addressed. Here, we conclude by extending this framework to emerging clean energy reactions such as hydrogen peroxide production, carbon dioxide reduction, and nitrogen reduction, where the development of improved catalysts could allow for the sustainable production of a broad range of fuels and chemicals.
Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1349286
Journal Information:
Science, Journal Name: Science Journal Issue: 6321 Vol. 355; ISSN 0036-8075
Publisher:
AAASCopyright Statement
Country of Publication:
United States
Language:
English

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Polymer‐Based Synthetic Routes to Carbon‐Based Metal‐Free Catalysts journal October 2018
Engineering NiO/NiFe LDH Intersection to Bypass Scaling Relationship for Oxygen Evolution Reaction via Dynamic Tridimensional Adsorption of Intermediates journal January 2019
Promoting Electrocatalysis upon Aerogels journal December 2018
Recent Progress in Electrically Rechargeable Zinc–Air Batteries journal December 2018
Recent Advances in Carbon‐Based Metal‐Free Electrocatalysts journal December 2018
Exceptional Performance of Hierarchical Ni-Fe (hydr)oxide@NiCu Electrocatalysts for Water Splitting journal December 2018
Enhancing Electrocatalytic Water Splitting by Strain Engineering journal February 2019
Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting journal February 2019
Rechargeable Zn–CO 2 Electrochemical Cells Mimicking Two‐Step Photosynthesis journal February 2019
Pt‐Based Nanocrystal for Electrocatalytic Oxygen Reduction journal December 2018
Cr‐Doped FeNi–P Nanoparticles Encapsulated into N‐Doped Carbon Nanotube as a Robust Bifunctional Catalyst for Efficient Overall Water Splitting journal February 2019
Transition‐Metal‐Doped RuIr Bifunctional Nanocrystals for Overall Water Splitting in Acidic Environments journal February 2019
In Situ Transmission Electron Microscopy for Energy Materials and Devices journal June 2019
Ultrafine Dual‐Phased Carbide Nanocrystals Confined in Porous Nitrogen‐Doped Carbon Dodecahedrons for Efficient Hydrogen Evolution Reaction journal June 2019
Ambient Fast Synthesis and Active Sites Deciphering of Hierarchical Foam‐Like Trimetal–Organic Framework Nanostructures as a Platform for Highly Efficient Oxygen Evolution Electrocatalysis journal March 2019
Supported Noble‐Metal Single Atoms for Heterogeneous Catalysis journal July 2019
Electrode Materials Engineering in Electrocatalytic CO 2 Reduction: Energy Input and Conversion Efficiency journal October 2019
2D Electrocatalysts for Converting Earth‐Abundant Simple Molecules into Value‐Added Commodity Chemicals: Recent Progress and Perspectives journal October 2019
Boosting Oxygen Evolution Reaction by Creating Both Metal Ion and Lattice‐Oxygen Active Sites in a Complex Oxide journal November 2019
Toward Efficient Carbon and Water Cycles: Emerging Opportunities with Single‐Site Catalysts Made of 3d Transition Metals journal November 2019
A General Method for Transition Metal Single Atoms Anchored on Honeycomb‐Like Nitrogen‐Doped Carbon Nanosheets journal January 2020
Zinc‐Mediated Template Synthesis of Fe‐N‐C Electrocatalysts with Densely Accessible Fe‐N x Active Sites for Efficient Oxygen Reduction journal January 2020
Overall Water-Splitting Electrocatalysts Based on 2D CoNi-Metal-Organic Frameworks and Its Derivative journal August 2018
Interfaces of (Ultra)thin Polymer Films in Organic Electronics journal September 2018
Multifunctional High‐Performance Electrocatalytic Properties of Nb 2 O 5 Incorporated Carbon Nanofibers as Pt Support Catalyst journal July 2019
Boron‐Modified Electron Transfer in Metallic 1T MoSe 2 for Enhanced Inherent Activity on Per‐Catalytic Site toward Hydrogen Evolution journal November 2019
Theoretical Analysis of Surface Active Sites in Defective 2H and 1T′ MoS 2 Polymorphs for Hydrogen Evolution Reaction: Quantifying the Total Activity of Point Defects journal January 2020
Atomically Thin 2D Multinary Nanosheets for Energy-Related Photo, Electrocatalysis journal May 2018
Design of Efficient Bifunctional Oxygen Reduction/Evolution Electrocatalyst: Recent Advances and Perspectives journal July 2017
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction journal January 2018
2D Assembly of Confined Space toward Enhanced CO 2 Electroreduction journal July 2018
Metal-Air Batteries: From Static to Flow System journal August 2018
Local Charge Distribution Engineered by Schottky Heterojunctions toward Urea Electrolysis journal August 2018
Exploring Indium-Based Ternary Thiospinel as Conceivable High-Potential Air-Cathode for Rechargeable Zn-Air Batteries journal September 2018
3D Architectures of Quaternary Co-Ni-S-P/Graphene Hybrids as Highly Active and Stable Bifunctional Electrocatalysts for Overall Water Splitting journal October 2018
Simultaneous Achieving of High Faradaic Efficiency and CO Partial Current Density for CO 2 Reduction via Robust, Noble‐Metal‐Free Zn Nanosheets with Favorable Adsorption Energy journal April 2019
Ni‐Metalloid (B, Si, P, As, and Te) Alloys as Water Oxidation Electrocatalysts journal May 2019
Surface Engineering of 3D Gas Diffusion Electrodes for High‐Performance H 2 Production with Nonprecious Metal Catalysts journal September 2019
Oxygen Reduction Reactions on Single‐ or Few‐Atom Discrete Active Sites for Heterogeneous Catalysis journal September 2019
Atomically Dispersed Mo Supported on Metallic Co 9 S 8 Nanoflakes as an Advanced Noble‐Metal‐Free Bifunctional Water Splitting Catalyst Working in Universal pH Conditions journal December 2019
Hierarchical Hollow Nanoprisms Based on Ultrathin Ni-Fe Layered Double Hydroxide Nanosheets with Enhanced Electrocatalytic Activity towards Oxygen Evolution journal December 2017
Elektrifizierung der organischen Synthese journal March 2018
Die lokale Oberflächenstruktur und -zusammensetzung bestimmt die Wasserstoffentwicklung an Eisen-Nickelsulfiden journal March 2018
Reaction Mechanisms of Well-Defined Metal-N 4 Sites in Electrocatalytic CO 2 Reduction journal November 2018
A Porous Pyrochlore Y 2 [Ru 1.6 Y 0.4 ]O 7– δ Electrocatalyst for Enhanced Performance towards the Oxygen Evolution Reaction in Acidic Media journal September 2018
Activating Inert Metallic Compounds for High‐Rate Lithium–Sulfur Batteries Through In Situ Etching of Extrinsic Metal journal January 2019
Highly Active Cobalt‐Based Electrocatalysts with Facile Incorporation of Dopants for the Oxygen Evolution Reaction journal March 2019
Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO 2 Electroreduction journal February 2019
In Situ Coupling of Single Molecules Driven by Gold‐Catalyzed Electrooxidation journal July 2019
Promoting Subordinate, Efficient Ruthenium Sites with Interstitial Silicon for Pt‐Like Electrocatalytic Activity journal July 2019
In situ Spectroscopic Insight into the Origin of the Enhanced Performance of Bimetallic Nanocatalysts towards the Oxygen Reduction Reaction (ORR) journal September 2019
Selective CO 2 Electroreduction to Ethylene and Multicarbon Alcohols via Electrolyte‐Driven Nanostructuring journal November 2019
Metal–Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction journal December 2019
Boron‐Induced Electronic‐Structure Reformation of CoP Nanoparticles Drives Enhanced pH‐Universal Hydrogen Evolution journal January 2020
The Common Intermediates of Oxygen Evolution and Dissolution Reactions during Water Electrolysis on Iridium journal February 2018
The Hydrogen Evolution Reaction in Alkaline Solution: From Theory, Single Crystal Models, to Practical Electrocatalysts journal May 2018
Core-Shell Structuring of Pure Metallic Aerogels towards Highly Efficient Platinum Utilization for the Oxygen Reduction Reaction journal February 2018
Electrifying Organic Synthesis journal March 2018
Spatially Confined Assembly of Monodisperse Ruthenium Nanoclusters in a Hierarchically Ordered Carbon Electrode for Efficient Hydrogen Evolution journal April 2018
An Amorphous Noble-Metal-Free Electrocatalyst that Enables Nitrogen Fixation under Ambient Conditions journal March 2018
Anodic Hydrazine Oxidation Assists Energy-Efficient Hydrogen Evolution over a Bifunctional Cobalt Perselenide Nanosheet Electrode journal May 2018
Competition between H and CO for Active Sites Governs Copper-Mediated Electrosynthesis of Hydrocarbon Fuels journal July 2018
CO 2 Overall Splitting by a Bifunctional Metal‐Free Electrocatalyst journal October 2018
Put the Sun in the Tank: Future Developments in Sustainable Energy Systems journal November 2018
A Porous Pyrochlore Y 2 [Ru 1.6 Y 0.4 ]O 7– δ Electrocatalyst for Enhanced Performance towards the Oxygen Evolution Reaction in Acidic Media journal October 2018
Integrated Valorization of Desalination Brine through NaOH Recovery: Opportunities and Challenges journal May 2019
Highly Active Cobalt‐Based Electrocatalysts with Facile Incorporation of Dopants for the Oxygen Evolution Reaction journal March 2019
Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO 2 Electroreduction journal May 2019
Bipyridine-Assisted Assembly of Au Nanoparticles on Cu Nanowires To Enhance the Electrochemical Reduction of CO 2 journal August 2019
Fluorographdiyne: A Metal‐Free Catalyst for Applications in Water Reduction and Oxidation journal September 2019
Three‐Phase Photocatalysis for the Enhanced Selectivity and Activity of CO 2 Reduction on a Hydrophobic Surface journal September 2019
Synergistically Interactive Pyridinic‐N–MoP Sites: Identified Active Centers for Enhanced Hydrogen Evolution in Alkaline Solution journal September 2019
Single‐Crystal Cobalt Phosphate Nanosheets for Biomimetic Oxygen Evolution in Neutral Electrolytes journal September 2019
High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium journal September 2019
Identification of Key Reversible Intermediates in Self‐Reconstructed Nickel‐Based Hybrid Electrocatalysts for Oxygen Evolution journal November 2019
High‐Curvature Transition‐Metal Chalcogenide Nanostructures with a Pronounced Proximity Effect Enable Fast and Selective CO 2 Electroreduction journal February 2020
Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts journal January 2020
Reversible and Selective CO 2 to HCO 2 Electrocatalysis near the Thermodynamic Potential journal February 2020
Boron‐Induced Electronic‐Structure Reformation of CoP Nanoparticles Drives Enhanced pH‐Universal Hydrogen Evolution journal January 2020
Electrocatalytic hydrogen evolution using triaryl corrole cobalt complex journal May 2020
Bottom‐Up Fabrication of a Sandwich‐Like Carbon/Graphene Heterostructure with Built‐In FeNC Dopants as Non‐Noble Electrocatalyst for Oxygen Reduction Reaction journal December 2019
g-C 3 N 4 /CeO 2 /Fe 3 O 4 Ternary Composite as an Efficient Bifunctional Catalyst for Overall Water Splitting journal November 2018
Methylamine Treated Mn 3 O 4 Nanoparticles as a Highly Efficient Water Oxidation Catalyst under Neutral Condition journal February 2019
Ultra‐Small Molybdenum Carbide Nanoparticles in situ Entrapped in Mesoporous Carbon Spheres as Efficient Catalysts for Hydrogen Evolution journal May 2019
Activity‐Stability Volcano Plots for Material Optimization in Electrocatalysis journal June 2019
Nitrogen‐doped Graphene Chainmail Wrapped IrCo Alloy Particles on Nitrogen‐doped Graphene Nanosheet for Highly Active and Stable Full Water Splitting journal October 2019
Chemical Doped Ternary and Quaternary Transition‐Metal‐Based Electrocatalysts for Hydrogen Evolution Reaction journal September 2019
Role of Iron on the Structure and Stability of Ni 3.2 Fe/Al 2 O 3 during Dynamic CO 2 Methanation for P2X Applications journal September 2019
Atomic Insights of Iron Doping in Nickel Hydroxide Nanosheets for Enhanced Oxygen Catalysis to Boost Broad Temperature Workable Zinc−Air Batteries journal October 2019
Stannites – A New Promising Class of Durable Electrocatalysts for Efficient Water Oxidation journal December 2019
Experimental and Theoretical Insights of MoS 2 /Mo 3 N 2 Nanoribbon‐Electrocatalysts for Efficient Hydrogen Evolution Reaction journal October 2019
Vanadium Doped Nickel Phosphide Nanosheets Self‐Assembled Microspheres as a High‐Efficiency Oxygen Evolution Catalyst journal December 2019
Self-Templated Synthesis of Co 1- x S Porous Hexagonal Microplates for Efficient Electrocatalytic Oxygen Evolution journal February 2018
Recent Advances on Non-precious Metal Porous Carbon-based Electrocatalysts for Oxygen Reduction Reaction journal March 2018
Impact of Textural Properties of Mesoporous Porphyrinic Carbon Electrocatalysts on Oxygen Reduction Reaction Activity journal April 2018
Electrochemical Energy Conversion and Storage with Zeolitic Imidazolate Framework Derived Materials: A Perspective journal October 2018
Fe@Fe 2 P Core‐Shell Nanorods Encapsulated in Nitrogen Doped Carbon Nanotubes as Robust and Stable Electrocatalyst Toward Hydrogen Evolution journal January 2019
Microstructural Engineering of Heterogeneous P−S−Co Interface for Oxygen and Hydrogen Evolution journal July 2019
Amorphous Cobalt Boride Nanosheets Directly Grown on Nickel Foam: Controllable Alternately Dipping Deposition for Efficient Oxygen Evolution journal July 2019
Effective Strain Engineering of IrO 2 Toward Improved Oxygen Evolution Catalysis through a Catalyst‐Support System journal August 2019
Molybdenum Carbide-Based Electrocatalysts for Hydrogen Evolution Reaction journal July 2017
Hollow Bimetallic Zinc Cobalt Phosphosulfides for Efficient Overall Water Splitting journal December 2018
B, N Co‐Doped Three‐Dimensional Carbon Aerogels with Excellent Electrochemical Performance for the Oxygen Reduction Reaction journal January 2019
Facile and Large‐Scale Fabrication of Sub‐3 nm PtNi Nanoparticles Supported on Porous Carbon Sheet: A Bifunctional Material for the Hydrogen Evolution Reaction and Hydrogenation journal May 2019
In Situ Transformation of Prussian‐Blue Analogue‐Derived Bimetallic Carbide Nanocubes by Water Oxidation: Applications for Energy Storage and Conversion journal September 2019
Exploring the Influence of Halogen Coordination Effect of Stable Bimetallic MOFs on Oxygen Evolution Reaction journal October 2019
Zn−Co−S Colloidal Nanocrystal Clusters as Efficient and Durable Bifunctional Electrocatalysts For Full Water Splitting journal April 2019
On the Possibilities and Considerations of Interfacing Ultra‐High Vacuum Equipment with an Electrochemical Setup journal September 2019
Superoxide Decay Pathways in Oxygen Reduction Reaction on Carbon‐Based Catalysts Evidenced by Theoretical Calculations journal February 2019
Selective Electrocatalytic H 2 O 2 Generation by Cobalt@N‐Doped Graphitic Carbon Core–Shell Nanohybrids journal March 2019
Edge/Defect Sites in α‐Co 1− m Fe m (OH) x Nanoplates Responsible for Water Oxidation Activity journal May 2019
Direct Growth of CNTs@CoS x Se 2(1− x ) on Carbon Cloth for Overall Water Splitting journal July 2019
Catalyst–Electrolyte Interactions in Aqueous Reline Solutions for Highly Selective Electrochemical CO 2 Reduction journal November 2019
Single vs double atom catalyst for N 2 activation in nitrogen reduction reaction: A DFT perspective journal January 2020
Recent Studies on Bifunctional Perovskite Electrocatalysts in Oxygen Evolution, Oxygen Reduction, and Hydrogen Evolution Reactions under Alkaline Electrolyte journal May 2019
Nitrogen and Sulfur Co-Doped Hollow Carbon Nanospheres Derived from Surface-Attached Polyelectrolyte Monolayers journal March 2018
Self-Supportive NiFe hydroxide with High Electrocatalytic Activity for Oxygen and Hydrogen Evolution Reaction journal February 2019
Fe‐doped CoNi 0.5 P Hierarchical Arrays as Efficient Bifunctional Electrocatalysts for Overall Water Splitting: Evolution of Morphology and Coordination of Catalytic Performance journal June 2019
Electrocatalytic Activity and Stability of 3D Ordered N‐doped Hierarchically Porous Carbon Supported Pt Catalyst for Methanol Oxidation and Oxygen Reduction Reactions journal November 2019
Reduced Graphene Oxide-Wrapped Co 9- x Fe x S 8 /Co,Fe-N-C Composite as Bifunctional Electrocatalyst for Oxygen Reduction and Evolution journal January 2018
Cobalt Phosphide Composite Encapsulated within N,P-Doped Carbon Nanotubes for Synergistic Oxygen Evolution journal April 2018
Electronic Structure Evolution in Tricomponent Metal Phosphides with Reduced Activation Energy for Efficient Electrocatalytic Oxygen Evolution journal August 2018
MoS 2 /NiS Yolk–Shell Microsphere‐Based Electrodes for Overall Water Splitting and Asymmetric Supercapacitor journal November 2018
Abundant Ce 3+ Ions in Au‐CeO x Nanosheets to Enhance CO 2 Electroreduction Performance journal April 2019
Big to Small: Ultrafine Mo 2 C Particles Derived from Giant Polyoxomolybdate Clusters for Hydrogen Evolution Reaction journal February 2019
Cu,N‐Codoped Carbon Nanodisks with Biomimic Stomata‐Like Interconnected Hierarchical Porous Topology as Efficient Electrocatalyst for Oxygen Reduction Reaction journal August 2019
Amorphous Intermediate Derivative from ZIF‐67 and Its Outstanding Electrocatalytic Activity journal December 2019
Metal‐Layer Assisted Growth of Ultralong Quasi‐2D MOF Nanoarrays on Arbitrary Substrates for Accelerated Oxygen Evolution journal November 2019
Ultrathin Amorphous Nickel Doped Cobalt Phosphates with Highly Ordered Mesoporous Structures as Efficient Electrocatalyst for Oxygen Evolution Reaction journal January 2020
Modeling of Electrocatalytic Dinitrogen Reduction on Microstructured Electrodes journal October 2018
Modulating the Electronic Structure of Single‐Atom Catalysts on 2D Nanomaterials for Enhanced Electrocatalytic Performance journal March 2019
Single Atoms on Graphene for Energy Storage and Conversion journal April 2019
Direct Synthesis of Metal‐Doped Phosphorene with Enhanced Electrocatalytic Hydrogen Evolution journal April 2019
Nitrogen‐Doped Porous Carbon Supported Nonprecious Metal Single‐Atom Electrocatalysts: from Synthesis to Application journal May 2019
Nickel‐Doping Effect on Mn 3 O 4 Nanoparticles for Electrochemical Water Oxidation under Neutral Condition journal January 2020
Advances and challenges in modeling solvated reaction mechanisms for renewable fuels and chemicals journal August 2019
Perovskite Materials in Electrocatalysis book January 2020
A review of the synthesis and characterization of anion exchange membranes journal May 2018
Molten-salt synthesis of porous La0.6Sr0.4Co0.2Fe0.8O2.9 perovskite as an efficient electrocatalyst for oxygen evolution journal April 2018
Review on photocatalytic and electrocatalytic artificial nitrogen fixation for ammonia synthesis at mild conditions: Advances, challenges and perspectives journal May 2019
Hexagonal boron nitride nanosheet for effective ambient N2 fixation to NH3 journal March 2019
Exposing Cu-Rich {110} Active Facets in PtCu nanostars for boosting electrochemical performance toward multiple liquid fuels electrooxidation journal March 2019
One-pot synthesis and shape control of metal selenides, sulfides and oxides with oxalic acid as the reducing reagent journal January 2019
Determination of Specific Electrocatalytic Sites in the Oxidation of Small Molecules on Crystalline Metal Surfaces journal January 2019
Oxygen Reduction Reactions of Fe-N-C Catalysts: Current Status and the Way Forward journal March 2019
Electrode Materials for Rechargeable Zinc-Ion and Zinc-Air Batteries: Current Status and Future Perspectives journal May 2019
Engineering Two-Dimensional Materials and Their Heterostructures as High-Performance Electrocatalysts journal May 2019
Recent advances of nanoporous metal-based catalyst: synthesis, application and perspectives journal August 2019
Electrochemical Behavior of Carbon Electrodes for In Situ Redox Studies in a Transmission Electron Microscope journal October 2019
Oriented electron transmission in polyoxometalate-metalloporphyrin organic framework for highly selective electroreduction of CO2 journal October 2018
Molecular cobalt corrole complex for the heterogeneous electrocatalytic reduction of carbon dioxide journal August 2019
Statistical learning goes beyond the d-band model providing the thermochemistry of adsorbates on transition metals journal October 2019
New frontiers for the materials genome initiative journal April 2019
Atomically dispersed platinum supported on curved carbon supports for efficient electrocatalytic hydrogen evolution journal June 2019
Considerations for the scaling-up of water splitting catalysts journal May 2019
Decoupled hydrogen and oxygen evolution by a two-step electrochemical–chemical cycle for efficient overall water splitting journal September 2019
Electrifying model catalysts for understanding electrocatalytic reactions in liquid electrolytes journal June 2018
Low-dimensional catalysts for hydrogen evolution and CO2 reduction journal January 2018
Revisiting the cold case of cold fusion journal May 2019
Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts journal March 2018
Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols journal June 2018
Impact of nanoparticle size and lattice oxygen on water oxidation on NiFeOxHy journal November 2018
Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells journal March 2019
H 2 evolution by a cobalt selenolate electrocatalyst and related mechanistic studies journal January 2017
A mechanism study on the hydrogen evolution reaction catalyzed by molybdenum disulfide complexes journal January 2018
Free-standing single-crystalline NiFe-hydroxide nanoflake arrays: a self-activated and robust electrocatalyst for oxygen evolution journal January 2018
Modelling pH and potential in dynamic structures of the water/Pt(111) interface on the atomic scale journal January 2017
Trends in adsorption of electrocatalytic water splitting intermediates on cubic ABO 3 oxides journal January 2018
Heterogeneous catalytic hydrogenation of CO 2 by metal oxides: defect engineering – perfecting imperfection journal January 2017
Identification of pH-dependent synergy on Ru/MoS 2 interface: a comparison of alkaline and acidic hydrogen evolution journal January 2017
Probing the geometry of copper and silver adatoms on magnetite: quantitative experiment versus theory journal January 2018
Electrochemical maps and movies of the hydrogen evolution reaction on natural crystals of molybdenite (MoS 2 ): basal vs. edge plane activity journal January 2017
Molybdenum diboride nanoparticles as a highly efficient electrocatalyst for the hydrogen evolution reaction journal January 2017
Bridged-multi-octahedral cobalt oxide nanocrystals with a Co-terminated surface as an oxygen evolution and reduction electrocatalyst journal January 2017
Facile electrodeposition of cauliflower-like S-doped nickel microsphere films as highly active catalysts for electrochemical hydrogen evolution journal January 2017
Electrochemical reduction of aqueous nitrogen (N 2 ) at a low overpotential on (110)-oriented Mo nanofilm journal January 2017
Template-directed synthesis of sulphur doped NiCoFe layered double hydroxide porous nanosheets with enhanced electrocatalytic activity for the oxygen evolution reaction journal January 2018
Biomass chitosan derived cobalt/nitrogen doped carbon nanotubes for the electrocatalytic oxygen reduction reaction journal January 2018
MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives journal January 2018
Iodide-derived nanostructured silver promotes selective and efficient carbon dioxide conversion into carbon monoxide journal January 2018
Electrocatalytic and photocatalytic hydrogen evolution integrated with organic oxidation journal January 2018
Nanodots of transition metal (Mo and W) disulfides grown on NiNi Prussian blue analogue nanoplates for efficient hydrogen production journal January 2018
Mesoporous S doped Fe–N–C materials as highly active oxygen reduction reaction catalyst journal January 2018
Polyoxometalate-based metal–organic framework loaded with an ultra-low amount of Pt as an efficient electrocatalyst for hydrogen production journal January 2018
On the hydrogen evolution reaction activity of graphene–hBN van der Waals heterostructures journal January 2018
Fundamental limitation of electrocatalytic methane conversion to methanol journal January 2018
Atomically-defined model catalysts in ultrahigh vacuum and in liquid electrolytes: particle size-dependent CO adsorption on Pt nanoparticles on ordered Co 3 O 4 (111) films journal January 2018
Hydrogen adsorption trends on various metal-doped Ni 2 P surfaces for optimal catalyst design journal January 2019
Single tungsten atom supported on N-doped graphyne as a high-performance electrocatalyst for nitrogen fixation under ambient conditions journal January 2019
Three-dimensionally patterned Ag–Pt alloy catalyst on planar Si photocathodes for photoelectrochemical H 2 evolution journal January 2019
Cu( ii )-nanoparticle-derived structures under CO 2 reduction conditions: a matter of shape journal January 2019
First-principles design of bifunctional oxygen reduction and evolution catalysts through bimetallic centers in metal–organic frameworks journal January 2018
N,S-Atom-coordinated Co 9 S 8 trinary dopants within a porous graphene framework as efficient catalysts for oxygen reduction/evolution reactions journal January 2018
In situ growth of metallic Ag 0 intercalated CoAl layered double hydroxides as efficient electrocatalysts for the oxygen reduction reaction in alkaline solutions journal January 2019
A comparative technoeconomic analysis of pathways for commercial electrochemical CO 2 reduction to liquid products journal January 2018
Activation of ultrathin SrTiO 3 with subsurface SrRuO 3 for the oxygen evolution reaction journal January 2018
Highly efficient hydrogen evolution triggered by a multi-interfacial Ni/WC hybrid electrocatalyst journal January 2018
Direct observation of active catalyst surface phases and the effect of dynamic self-optimization in NiFe-layered double hydroxides for alkaline water splitting journal January 2019
Towards an atomistic understanding of electrocatalytic partial hydrocarbon oxidation: propene on palladium journal January 2019
Advancing semiconductor–electrocatalyst systems: application of surface transformation films and nanosphere lithography journal January 2018
Activating rhodium phosphide-based catalysts for the pH-universal hydrogen evolution reaction journal January 2018
Metal–organic framework derived leaf-like CoSNC nanocomposites for supercapacitor electrodes journal January 2018
A three-dimensional nickel–chromium layered double hydroxide micro/nanosheet array as an efficient and stable bifunctional electrocatalyst for overall water splitting journal January 2018
Simultaneous edge and electronic control of MoS 2 nanosheets through Fe doping for an efficient oxygen evolution reaction journal January 2018
Morphology controlled synthesis of low bandgap SnSe 2 with high photodetectivity journal January 2019
A 2D metal–organic framework/Ni(OH) 2 heterostructure for an enhanced oxygen evolution reaction journal January 2019
Improved oxygen evolution activity of IrO 2 by in situ engineering of an ultra-small Ir sphere shell utilizing a pulsed laser journal January 2019
An electrochemical anodization strategy towards high-activity porous MoS 2 electrodes for the hydrogen evolution reaction journal January 2018
Insight into the adsorption of a liquid organic hydrogen carrier, perhydro- i -dibenzyltoluene ( i = m , o , p ), on Pt, Pd and PtPd planar surfaces journal January 2018
Morphology engineering of nickel molybdate hydrate nanoarray for electrocatalytic overall water splitting: from nanorod to nanosheet journal January 2018
Surface reconstruction of cobalt phosphide nanosheets by electrochemical activation for enhanced hydrogen evolution in alkaline solution journal January 2019
One-step synthesis of nickel–iron layered double hydroxides with tungstate acid anions via flash nano-precipitation for the oxygen evolution reaction journal January 2019
Probing the active sites of Co 3 O 4 for the acidic oxygen evolution reaction by modulating the Co 2+ /Co 3+ ratio journal January 2018
A theoretical study on the surface and interfacial properties of Ni 3 P for the hydrogen evolution reaction journal January 2018
Supramolecular bimetallogels: a nanofiber network for bimetal/nitrogen co-doped carbon electrocatalysts journal January 2018
Stannate derived bimetallic nanoparticles for electrocatalytic CO 2 reduction journal January 2018
Advanced perspective on the synchronized bifunctional activities of P2-type materials to implement an interconnected voltage profile for seawater batteries journal January 2018
Amorphous NiFe layered double hydroxide nanosheets decorated on 3D nickel phosphide nanoarrays: a hierarchical core–shell electrocatalyst for efficient oxygen evolution journal January 2018
MoO 3 nanosheets for efficient electrocatalytic N 2 fixation to NH 3 journal January 2018
Recent progress in single-atom electrocatalysts: concept, synthesis, and applications in clean energy conversion journal January 2018
Partially amorphous nickel–iron layered double hydroxide nanosheet arrays for robust bifunctional electrocatalysis journal January 2018
Anthocephalus cadamba shaped FeNi encapsulated carbon nanostructures for metal–air batteries as a resilient bifunctional oxygen electrocatalyst journal January 2018
Electrochemical activity of 1T′ structured rhenium selenide nanosheets via electronic structural modulation from selenium-vacancy generation journal January 2018
Structure–property relationships describing the buried interface between silicon oxide overlayers and electrocatalytic platinum thin films journal January 2018
A bifunctional and stable Ni–Co–S/Ni–Co–P bistratal electrocatalyst for 10.8%-efficient overall solar water splitting journal January 2018
Tunable nano-interfaces between MnO x and layered double hydroxides boost oxygen evolving electrocatalysis journal January 2018
3D nanoporous Ni/V 2 O 3 hybrid nanoplate assemblies for highly efficient electrochemical hydrogen evolution journal January 2018
Palladium single atoms supported by interwoven carbon nanotube and manganese oxide nanowire networks for enhanced electrocatalysis journal January 2018
Iodide-mediated templating synthesis of highly porous rhodium nanospheres for enhanced dehydrogenation of ammonia borane journal January 2018
Chainmail catalyst of ultrathin P-doped carbon shell-encapsulated nickel phosphides on graphene towards robust and efficient hydrogen generation journal January 2018
A highly efficient and durable water splitting system: platinum sub-nanocluster functionalized nickel–iron layered double hydroxide as the cathode and hierarchical nickel–iron selenide as the anode journal January 2019
Recent advances in layered double hydroxide electrocatalysts for the oxygen evolution reaction journal January 2019
Selenium vacancy-rich CoSe 2 ultrathin nanomeshes with abundant active sites for electrocatalytic oxygen evolution journal January 2019
Metal–organic frameworks: a promising platform for constructing non-noble electrocatalysts for the oxygen-reduction reaction journal January 2019
Metal–organic framework composites and their electrochemical applications journal January 2019
Nitrogen and phosphorous co-doped graphitic carbon encapsulated ultrafine OsP 2 nanoparticles: a pH universal highly durable catalyst for hydrogen evolution reaction journal January 2019
NiS 2 nanodotted carnation-like CoS 2 for enhanced electrocatalytic water splitting journal January 2019
Unveiling the active sites of Ni–Fe phosphide/metaphosphate for efficient oxygen evolution under alkaline conditions journal January 2019
A robust electrocatalytic activity toward the hydrogen evolution reaction from W/W 2 C heterostructured nanoparticles coated with a N,P dual-doped carbon layer journal January 2019
Iron tungsten mixed composite as a robust oxygen evolution electrocatalyst journal January 2019
Synergistic bimetallic CoFe 2 O 4 clusters supported on graphene for ambient electrocatalytic reduction of nitrogen to ammonia journal January 2019
Fe ions modulated formation of hollow NiFe oxyphosphide spheres with enhanced oxygen evolution performance journal January 2019
A hierarchical hollow-on-hollow NiCoP electrocatalyst for efficient hydrogen evolution reaction journal January 2020
Enhancing the electrocatalytic activity of 2H-WS 2 for hydrogen evolution via defect engineering journal January 2019
Understanding electro-catalysis by using density functional theory journal January 2019
The dual-defective SnS 2 monolayers: promising 2D photocatalysts for overall water splitting journal January 2019
Confined Co 9 S 8 into a defective carbon matrix as a bifunctional oxygen electrocatalyst for rechargeable zinc–air batteries journal January 2019
Nitrogen-doped metal-free carbon catalysts for (electro)chemical CO 2 conversion and valorisation journal January 2019
Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction journal January 2020
Co/Cu-modified NiO film grown on nickel foam as a highly active and stable electrocatalyst for overall water splitting journal January 2020
Atomically dispersed metal catalysts for the oxygen reduction reaction: synthesis, characterization, reaction mechanisms and electrochemical energy applications journal January 2019
Nanomaterials for molecular signal amplification in electrochemical nucleic acid biosensing: recent advances and future prospects for point-of-care diagnostics journal January 2020
Electro-synthesized Co(OH) 2 @CoSe with Co–OH active sites for overall water splitting electrocatalysis journal January 2020
Host–guest chemistry between cyclodextrin and a hydrogen evolution catalyst cobaloxime journal January 2019
Facile synthesis of Cu 2 MoS 4 nanosheet/multi-walled carbon nanotube composites as a high-efficiency electrocatalyst for hydrogen evolution journal January 2019
Single molybdenum center supported on N-doped black phosphorus as an efficient electrocatalyst for nitrogen fixation journal January 2019
Regulating the electron density of dual transition metal sulfide heterostructures for highly efficient hydrogen evolution in alkaline electrolytes journal January 2019
Single molybdenum atom anchored on 2D Ti 2 NO 2 MXene as a promising electrocatalyst for N 2 fixation journal January 2019
Strategy to boost catalytic activity of polymeric carbon nitride: synergistic effect of controllable in situ surface engineering and morphology journal January 2019
Synthesis of low- and high-index faceted metal (Pt, Pd, Ru, Ir, Rh) nanoparticles for improved activity and stability in electrocatalysis journal January 2019
Multifunctional inorganic nanomaterials for energy applications journal January 2020
Multifunctional 2H-TaS 2 nanoflakes for efficient supercapacitors and electrocatalytic evolution of hydrogen and oxygen journal January 2019
Sulfur doping enhanced desorption of intermediates on NiCoP for efficient alkaline hydrogen evolution journal January 2020
Well-defined CoSe 2 @MoSe 2 hollow heterostructured nanocubes with enhanced dissociation kinetics for overall water splitting journal January 2020
A layer-by-layer strategy for the scalable preparation of uniform interfacial electrocatalysts with high structural tunability: a case study of a CoNP/N,P-graphene catalyst complex journal January 2020
Carbon impurity-free, novel Mn,N co-doped porous Mo 2 C nanorods for an efficient and stable hydrogen evolution reaction journal January 2019
Shaping well-defined noble-metal-based nanostructures for fabricating high-performance electrocatalysts: advances and perspectives journal January 2019
Gallic acid-assisted synthesis of nitrogen-doped carbon microspheres as efficient bifunctional materials for oxygen reduction and volumetric lithium storage journal January 2020
Efficient tri-metallic oxides NiCo 2 O 4 /CuO for the oxygen evolution reaction journal January 2019
Tailoring the composition of a one-step electrodeposited Co,Ni/Co,Ni(OH) 2 composite coating for a highly active hydrogen evolution electrode journal January 2020
Correlation between Ru–O hybridization and the oxygen evolution reaction in ruthenate epitaxial thin films journal January 2019
Planar polymer electrolyte membrane fuel cells: powering portable devices from hydrogen journal January 2020
Highly efficient and durable III–V semiconductor-catalyst photocathodes via a transparent protection layer journal January 2020
Tailorable surface sulfur chemistry of mesoporous Ni 3 S 2 particles for efficient oxygen evolution journal January 2019
Plasmonic hot charge carriers activated Ni centres of metal–organic frameworks for the oxygen evolution reaction journal January 2019
Ternary metal sulfides for electrocatalytic energy conversion journal January 2019
Syngas production from electrocatalytic CO 2 reduction with high energetic efficiency and current density journal January 2019
Dual-nitrogen-source engineered Fe–N x moieties as a booster for oxygen electroreduction journal January 2019
A unique sandwich structure of a CoMnP/Ni 2 P/NiFe electrocatalyst for highly efficient overall water splitting journal January 2019
Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution journal January 2019
Synergistic electrocatalytic N 2 reduction using a PTCA nanorod–rGO hybrid journal January 2019
Chestnut-like copper cobalt phosphide catalyst for all-pH hydrogen evolution reaction and alkaline water electrolysis journal January 2019
N,P-coordinated fullerene-like carbon nanostructures with dual active centers toward highly-efficient multi-functional electrocatalysis for CO 2 RR, ORR and Zn-air battery journal January 2019
One minute from pristine carbon to an electrocatalyst for hydrogen peroxide production journal January 2019
Design and optimization of cobalt-encapsulating vertical graphene nano-hills for hydrogen evolution reaction journal January 2019
Nanostructured Co-based bifunctional electrocatalysts for energy conversion and storage: current status and perspectives journal January 2019
Tailoring the ORR and HER electrocatalytic performances of gold nanoparticles through metal–ligand interfaces journal January 2019
Neutral-pH overall water splitting catalyzed efficiently by a hollow and porous structured ternary nickel sulfoselenide electrocatalyst journal January 2019
Revealing Ni-based layered double hydroxides as high-efficiency electrocatalysts for the oxygen evolution reaction: a DFT study journal January 2019
Thermally induced top-down nanostructuring for the synthesis of a core/shell-structured CoO/CoS x electrocatalyst journal January 2019
Ambient fast, large-scale synthesis of entropy-stabilized metal–organic framework nanosheets for electrocatalytic oxygen evolution journal January 2019
Activated basal planes of WS 2 by intrinsic defects as catalysts for the electrocatalytic nitrogen reduction reaction journal January 2019
Invigorating the catalytic performance of CoP through interfacial engineering by Ni 2 P precipitation journal January 2019
SnO 2 patched ultrathin PtRh nanowires as efficient catalysts for ethanol electrooxidation journal January 2019
A vanadium–nickel oxynitride layer for enhanced electrocatalytic nitrogen fixation in neutral media journal January 2020
Promoting the electroreduction of CO 2 with oxygen vacancies on a plasma-activated SnO x /carbon foam monolithic electrode journal January 2020
Preparation of complex model electrocatalysts in ultra-high vacuum and transfer into the electrolyte for electrochemical IR spectroscopy and other techniques journal November 2018
Effect of surface-bound sulfide on oxygen reduction reaction on Pt: Breaking the scaling relationship and mechanistic insights journal January 2019
Quantifying robustness of DFT predicted pathways and activity determining elementary steps for electrochemical reactions journal January 2019
First-principles modeling of GaN(0001)/water interface: Effect of surface charging journal April 2019
Doping single transition metal atom into PtTe sheet for catalyzing nitrogen reduction and hydrogen evolution reactions journal October 2019
Screening alloy electrocatalysts by combining magnetron sputtering and scanning electrochemical microscopy journal May 2019
Chemically modified phosphorene as efficient catalyst for hydrogen evolution reaction journal October 2019
Single and double boron atoms doped nanoporous C 2 N– h 2D electrocatalysts for highly efficient N 2 reduction reaction: a density functional theory study journal May 2019
Direct versus reverse vertical two-dimensional Mo 2 C/graphene heterostructures for enhanced hydrogen evolution reaction electrocatalysis journal July 2019
An Fe–N co-doped tube-in-tube carbon nanostructure used as an efficient catalyst for the electrochemical oxygen reduction reaction journal September 2019
Fe/N-doped hollow porous carbon spheres for oxygen reduction reaction journal January 2020
Unravelling electrocatalytic properties of metal porphyrin-like complexes hosted in graphene matrices journal February 2020
Perovskites in catalysis and electrocatalysis journal November 2017
Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells journal November 2019
CO 2 electrolysis to multicarbon products at activities greater than 1 A cm −2 journal February 2020
Modulating the Volmer Step by MOF Derivatives Assembled with Heterogeneous Ni 2 P-CoP Nanocrystals in Alkaline Hydrogen Evolution Reaction journal January 2018
One-Pot Synthesis of Nanoporous Nickel Hydroxide Film as High-Performance Electrode for Asymmetric Supercapacitor journal January 2019
Urchin-Like Nanorods of Binary NiCoS Supported on Nickel Foam for Electrocatalytic Overall Water Splitting journal January 2018
Electrospun Cobalt-Doped MoS 2 Nanofibers for Electrocatalytic Hydrogen Evolution journal January 2019
Catalysts in metal–air batteries journal April 2018
Perspectives on the photoelectrochemical storage of solar energy journal January 2017
Electrochemical Surface Science: Basics and Applications book October 2019
Enhanced Electrocatalytic Activity and Stability toward the Oxygen Reduction Reaction with Unprotected Pt Nanoclusters journal November 2018
A Simple and Fast Method to Synthesize Cubic Iridium Nanoparticles with Clean Surface Free from Surfactants journal January 2019

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