Shaping electrocatalysis through tailored nanomaterials

Kang, Yijin; Yang, Peidong; Markovic, Nenad M.; Stamenkovic, Vojislav R.

doi:10.1016/j.nantod.2016.08.008

Shaping electrocatalysis through tailored nanomaterials

Journal Article · Wed Sep 21 00:00:00 EDT 2016 · Nano Today

DOI:https://doi.org/10.1016/j.nantod.2016.08.008· OSTI ID:1352884

Kang, Yijin ^[1]; Yang, Peidong ^[2]; Markovic, Nenad M. ^[3]; Stamenkovic, Vojislav R. ^[3]

Univ. of Electronic Science and Technology of China, Chengdu (China). Inst. of Fundamental and Frontier Sciences
Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division

Electrocatalysis is a subclass of heterogeneous catalysis that is aimed towards increase of the electrochemical reaction rates that are taking place at the surface of electrodes. Real-world electrocatalysts are usually based on precious metals in the form of nanoparticles due to their high surface-to-volume ratio, which enables better utilization of employed materials. Ability to tailor nanostructure of an electrocatalyst is critical in order to tune their electrocatalytic properties. Over the last decade, that has mainly been achieved through implementation of fundamental studies performed on well-defined extended surfaces with distinct single crystalline and polycrystalline structures. Based on these studies, it has been demonstrated that performance of an electrocatalyst could be significantly changed through the control of size, composition, morphology and architecture of employed nanomaterials. Here, this review outlines the following steps in the process of rational development of an efficient electrocatalyst: 1) electrochemical properties of well-defined surfaces, 2) synthesis and characterization of different classes of electrocatalysts, and 3) correlation between physical properties (size, shape, composition and morphology) and electrochemical behavior (adsorption, electrocatalytic activity and durability) of electrocatalyst. In addition, this is a brief summary of the novel research platforms in the development of functional nano materials for energy conversion and storage applications such as fuel cells electrolyzers and batteries.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357

OSTI ID:: 1352884

Alternate ID(s):: OSTI ID: 1832539
OSTI ID: 1397382

Journal Information:: Nano Today, Journal Name: Nano Today Journal Issue: 5 Vol. 11; ISSN 1748-0132

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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