Increasing the Aromatic Selectivity of Quinoline Hydrogenolysis Using Pd/MOx–Al2O3
Journal Article
·
· Catalysis Letters
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemical and Biological Engineering
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemical and Biological Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemical and Biological Engineering
Catalysts consisting of Pd nanoparticles supported on highly dispersed TiOx–Al2O3, TaOx–Al2O3, and MoOx–Al2O3 are studied for catalytic quinoline hydrogenation and selective C–N bond cleavage at 275 °C and 20 bar H2. Lastly, the Pd/MOx–Al2O3 materials exhibit significantly greater aromatic product selectivity and thus 10–15 % less required H2 for a given level of denitrogenation relative to an unmodified Pd/Al2O3 catalyst.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- DOE Contract Number:
- AC0-06CH11357; SC-0006718; 86ER1311; SC0001329
- OSTI ID:
- 1347000
- Journal Information:
- Catalysis Letters, Vol. 144, Issue 11; ISSN 1011-372X
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- ENGLISH
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