Increasing the Aromatic Selectivity of Quinoline Hydrogenolysis Using Pd/MOx–Al2O3

Bachrach, Mark; Morlanes-Sanchez, Natalia; Canlas, Christian P.; Miller, Jeffrey T.; Marks, Tobin J.; Notestein, Justin M.

doi:10.1007/s10562-014-1346-x

Increasing the Aromatic Selectivity of Quinoline Hydrogenolysis Using Pd/MOx–Al2O3

Journal Article · Thu Sep 11 00:00:00 EDT 2014 · Catalysis Letters

DOI:https://doi.org/10.1007/s10562-014-1346-x· OSTI ID:1385877

Bachrach, Mark; Morlanes-Sanchez, Natalia; Canlas, Christian P.; Miller, Jeffrey T.; Marks, Tobin J.; Notestein, Justin M.

Catalysts consisting of Pd nanoparticles supported on highly dispersed TiOx–Al2O3, TaOx–Al2O3, and MoOx–Al2O3 are studied for catalytic quinoline hydrogenation and selective C–N bond cleavage at 275 °C and 20 bar H2. The Pd/MOx–Al2O3 materials exhibit significantly greater aromatic product selectivity and thus 10–15 % less required H2 for a given level of denitrogenation relative to an unmodified Pd/Al2O3 catalyst.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Institute for Atom-efficient Chemical Transformations (IACT)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1385877

Journal Information:: Catalysis Letters, Journal Name: Catalysis Letters Journal Issue: 11 Vol. 144; ISSN 1011-372X

Publisher:: Springer

Country of Publication:: United States

Language:: English

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