Ethanol Reduced Molybdenum Trioxide for Li-ion Capacitors

Li, Tianqi; Beidaghi, Majid; Xiao, Xu; Huang, Liang; Hu, Zhimi; Sun, Wanmei; Chen, Xun; Gogotsi, Yury G.; Zhou, Jun

doi:10.1016/j.nanoen.2016.05.004

Ethanol Reduced Molybdenum Trioxide for Li-ion Capacitors

Journal Article · Fri May 06 00:00:00 EDT 2016 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2016.05.004· OSTI ID:1346635

Li, Tianqi ^[1]; Beidaghi, Majid ^[2]; Xiao, Xu ^[1]; Huang, Liang ^[1]; Hu, Zhimi ^[1]; Sun, Wanmei ^[1]; Chen, Xun ^[1]; Gogotsi, Yury G. ^[3]; Zhou, Jun ^[1]

Huazhong University of Science and Technology, Wuhan (China)
Auburn Univ., AL (United States)
Drexel Univ., Philadelphia, PA (United States)

Orthorhombic molybdenum trioxide (α-MoO₃) is a layered oxide with promising performance as electrode material for Li-ion capacitors. In this study, we show that expansion of the interlayer spacing (by ~0.32 Å) of the structure along the b-axis, introduced by partial reduction of α-MoO₃ and formation of MoO_3-x (x=0.06–0.43), results in enhanced diffusion of Li ions. Binder-free hybrid electrodes made of MoO_3-x nanobelts and carbon nanotubes show excellent electrical conductivity. The combination of increased interlayer spacing and enhanced electron transport leads to high gravimetric and volumetric capacitances of about 420 F/g or F/cm³ and excellent cycle life of binder-free MoO_3-x electrodes.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1346635

Alternate ID(s):: OSTI ID: 1338416
OSTI ID: 22942544
OSTI ID: 1387837

Journal Information:: Nano Energy, Journal Name: Nano Energy Vol. 26; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (36)

Lithiated MoO3 Nanobelts with Greatly Improved Performance for Lithium Batteries Mai, L. Q.; Hu, B.; Chen, W. Advanced Materials, Vol. 19, Issue 21 https://doi.org/10.1002/adma.200700883	journal	November 2007
Freestanding Mesoporous VN/CNT Hybrid Electrodes for Flexible All-Solid-State Supercapacitors Xiao, Xu; Peng, Xiang; Jin, Huanyu Advanced Materials, Vol. 25, Issue 36 https://doi.org/10.1002/adma.201301465	journal	July 2013
WO 3− x /MoO 3− x Core/Shell Nanowires on Carbon Fabric as an Anode for All-Solid-State Asymmetric Supercapacitors Xiao, Xu; Ding, Tianpeng; Yuan, Longyan Advanced Energy Materials, Vol. 2, Issue 11 https://doi.org/10.1002/aenm.201200380	journal	August 2012
Inside Cover: Thiophene-Based, Radial π-Conjugation: Synthesis, Structure, and Photophysical Properties of Cyclo-1,4-phenylene-2′,5′-thienylenes (Angew. Chem. Int. Ed. 1/2015) Ito, Hideto; Mitamura, Yukari; Segawa, Yasutomo Angewandte Chemie International Edition, Vol. 54, Issue 1 https://doi.org/10.1002/anie.201410932	journal	November 2014
Carbon materials for the electrochemical storage of energy in capacitors Frackowiak, Elzbieta; Béguin, François Carbon, Vol. 39, Issue 6, p. 937-950 https://doi.org/10.1016/S0008-6223(00)00183-4	journal	May 2001
Performance of electric double-layer capacitors using carbons prepared from phenol–formaldehyde resins by KOH etching Teng, Hsisheng; Chang, Yao-Jen; Hsieh, Chien-To Carbon, Vol. 39, Issue 13, p. 1981-1987 https://doi.org/10.1016/S0008-6223(01)00027-6	journal	November 2001
Electrochemical supercapacitor material based on manganese oxide: preparation and characterization Jiang, Junhua; Kucernak, Anthony Electrochimica Acta, Vol. 47, Issue 15, p. 2381-2386 https://doi.org/10.1016/S0013-4686(02)00031-2	journal	June 2002
Properties of oxygen sites at the MoO3(010) surface: density functional theory cluster studies and photoemission experiments Tokarz-Sobieraj, R.; Hermann, K.; Witko, M. Surface Science, Vol. 489, Issue 1-3 https://doi.org/10.1016/S0039-6028(01)01169-4	journal	August 2001
Structural and electrochemical characterization of α-MoO3 nanorod-based electrochemical energy storage devices Shakir, Imran; Shahid, Muhammad; Yang, Hyoung Woo Electrochimica Acta, Vol. 56, Issue 1 https://doi.org/10.1016/j.electacta.2010.09.028	journal	December 2010
Binder free MoO3/multiwalled carbon nanotube thin film electrode for high energy density supercapacitors Aravinda, L. S.; Bhat, Udaya; Ramachandra Bhat, Badekai Electrochimica Acta, Vol. 112 https://doi.org/10.1016/j.electacta.2013.08.114	journal	December 2013
Intercalation of cations into partially reduced molybdenum oxide for high-rate pseudocapacitors Xiao, Xu; Zhang, Chuanfang (John); Lin, Shizhe Energy Storage Materials, Vol. 1 https://doi.org/10.1016/j.ensm.2015.05.001	journal	November 2015
Highly uniform deposition of MoO3 nanodots on multiwalled carbon nanotubes for improved performance of supercapacitors Mahmood, Qasim; Yun, Hyung Joong; Kim, Woo Sik Journal of Power Sources, Vol. 235 https://doi.org/10.1016/j.jpowsour.2013.01.165	journal	August 2013
Freestanding MoO3− nanobelt/carbon nanotube films for Li-ion intercalation pseudocapacitors Xiao, Xu; Peng, Zehua; Chen, Chi Nano Energy, Vol. 9 https://doi.org/10.1016/j.nanoen.2014.08.001	journal	October 2014
Charge Storage Mechanism of MnO ₂ Electrode Used in Aqueous Electrochemical Capacitor Toupin, Mathieu; Brousse, Thierry; Bélanger, Daniel Chemistry of Materials, Vol. 16, Issue 16 https://doi.org/10.1021/cm049649j	journal	August 2004
Comparative Study on MoO ₃ and H _x MoO ₃ Nanobelts: Structure and Electric Transport Hu, Xiao Kai; Qian, Yi Tai; Song, Z. T. Chemistry of Materials, Vol. 20, Issue 4 https://doi.org/10.1021/cm702942y	journal	February 2008
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO₂ (Anatase) Nanoparticles Wang, John; Polleux, Julien; Lim, James The Journal of Physical Chemistry C, Vol. 111, Issue 40, p. 14925-14931 https://doi.org/10.1021/jp074464w	journal	October 2007
Fast Synthesis of α-MoO ₃ Nanorods with Controlled Aspect Ratios and Their Enhanced Lithium Storage Capabilities Chen, Jun Song; Cheah, Yan Ling; Madhavi, Srinivasan The Journal of Physical Chemistry C, Vol. 114, Issue 18 https://doi.org/10.1021/jp1017482	journal	April 2010
Ultralong α-MoO ₃ Nanobelts: Synthesis and Effect of Binder Choice on Their Lithium Storage Properties Wang, Zhiyu; Madhavi, Srinivasan; Lou, Xiong Wen (David) The Journal of Physical Chemistry C, Vol. 116, Issue 23 https://doi.org/10.1021/jp304216z	journal	May 2012
Effect of Surface Structure on Behavior of RuO ₂ Electrodes in Sulfuric Acid Aqueous Solution Doubova, L. M.; De Battisti, A.; Daolio, S. Russian Journal of Electrochemistry, Vol. 40, Issue 11 https://doi.org/10.1023/B:RUEL.0000048642.73284.4f	journal	November 2004
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors Brezesinski, Torsten; Wang, John; Tolbert, Sarah H. Nature Materials, Vol. 9, Issue 2 https://doi.org/10.1038/nmat2612	journal	January 2010
Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon Pech, David; Brunet, Magali; Durou, Hugo Nature Nanotechnology, Vol. 5, Issue 9, p. 651-654 https://doi.org/10.1038/nnano.2010.162	journal	August 2010
Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials Acerce, Muharrem; Voiry, Damien; Chhowalla, Manish Nature Nanotechnology, Vol. 10, Issue 4 https://doi.org/10.1038/nnano.2015.40	journal	March 2015
Facile synthesis of α-MoO3 nanobelts and their pseudocapacitive behavior in an aqueous Li2SO4 solution Jiang, Jianbo; Liu, Jinlong; Peng, Sanjun Journal of Materials Chemistry A, Vol. 1, Issue 7 https://doi.org/10.1039/c2ta01120d	journal	January 2013
Pseudocapacitive oxide materials for high-rate electrochemical energy storage Augustyn, Veronica; Simon, Patrice; Dunn, Bruce Energy & Environmental Science, Vol. 7, Issue 5 https://doi.org/10.1039/c3ee44164d	journal	January 2014
Flexible and conductive MXene films and nanocomposites with high capacitance Ling, Zheng; Ren, Chang E.; Zhao, Meng-Qiang Proceedings of the National Academy of Sciences, Vol. 111, Issue 47 https://doi.org/10.1073/pnas.1414215111	journal	November 2014
MATERIALS SCIENCE: Electrochemical Capacitors for Energy Management Miller, J. R.; Simon, P. Science, Vol. 321, Issue 5889 https://doi.org/10.1126/science.1158736	journal	August 2008
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
Where Do Batteries End and Supercapacitors Begin? Simon, P.; Gogotsi, Y.; Dunn, B. Science, Vol. 343, Issue 6176 https://doi.org/10.1126/science.1249625	journal	March 2014
A Nickel Metal Hydride Battery for Electric Vehicles Ovshinsky, S. R.; Fetcenko, M. A.; Ross, J. Science, Vol. 260, Issue 5105 https://doi.org/10.1126/science.260.5105.176	journal	April 1993
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries Padhi, A. K. Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194 https://doi.org/10.1149/1.1837571	journal	April 1997
Effects of Microencapsulation of Hydrogen Storage Alloy on the Performances of Sealed Nickel/Metal Hydride Batteries Sakai, Tetsuo; Ishikawa, Hiroshi; Oguro, Keisuke Journal of The Electrochemical Society, Vol. 134, Issue 3 https://doi.org/10.1149/1.2100509	journal	March 1987
Crystalline MnO[sub 2] as Possible Alternatives to Amorphous Compounds in Electrochemical Supercapacitors Brousse, Thierry; Toupin, Mathieu; Dugas, Romain Journal of The Electrochemical Society, Vol. 153, Issue 12 https://doi.org/10.1149/1.2352197	journal	January 2006

Cited By (18)

Super-Capacitive Performance of Manganese Dioxide/Graphene Nano-Walls Electrodes Deposited on Stainless Steel Current Collectors Amade, Roger; Muyshegyan-Avetisyan, Arevik; Martí González, Joan Materials, Vol. 12, Issue 3 https://doi.org/10.3390/ma12030483	journal	February 2019
Molybdenum Oxide Nanosheets with Tunable Plasmonic Resonance: Aqueous Exfoliation Synthesis and Charge Storage Applications Etman, Ahmed S.; Wang, Ligang; Edström, Kristina Advanced Functional Materials, Vol. 29, Issue 4 https://doi.org/10.1002/adfm.201806699	journal	November 2018
Paper-Based Electrodes for Flexible Energy Storage Devices Yao, Bin; Zhang, Jing; Kou, Tianyi Advanced Science, Vol. 4, Issue 7 https://doi.org/10.1002/advs.201700107	journal	May 2017
Cation Intercalation in Manganese Oxide Nanosheets: Effects on Lithium and Sodium Storage Lu, Ke; Hu, Ziyu; Xiang, Zhonghua Angewandte Chemie, Vol. 128, Issue 35 https://doi.org/10.1002/ange.201605102	journal	July 2016
Cation Intercalation in Manganese Oxide Nanosheets: Effects on Lithium and Sodium Storage Lu, Ke; Hu, Ziyu; Xiang, Zhonghua Angewandte Chemie International Edition, Vol. 55, Issue 35 https://doi.org/10.1002/anie.201605102	journal	July 2016
Quantum-Dot-Mediated Controlled Synthesis of Dual Oxides of Molybdenum from MoS ₂ : Quantification of Supercapacitor Efficacy Mandal, Debasish; Routh, Parimal; Nandi, Arun K. Chemistry - An Asian Journal, Vol. 13, Issue 24 https://doi.org/10.1002/asia.201801173	journal	November 2018
Flexible Freestanding MoO _{3− x} –Carbon Nanotubes–Nanocellulose Paper Electrodes for Charge‐Storage Applications Etman, Ahmed S.; Wang, Zhaohui; El Ghazaly, Ahmed ChemSusChem, Vol. 12, Issue 23 https://doi.org/10.1002/cssc.201902394	journal	November 2019
Free‐standing Reduced Graphene Oxide/MoO _{3‐ x} Composite Film with High Performance for Flexible Supercapacitors Yu, Ms. Le; Zhao, Shi‐Xi; Wang, Yi‐Feng ChemistrySelect, Vol. 4, Issue 31 https://doi.org/10.1002/slct.201901816	journal	August 2019
Chemical reduction implanted oxygen vacancy on the surface of 1D MoO3−x/g-C3N4 composite for boosted LED light-driven photoactivity Huang, Liying; Zhang, Fei; Li, Yeping Journal of Materials Science, Vol. 54, Issue 7 https://doi.org/10.1007/s10853-018-03227-4	journal	December 2018
High-performance Li-ion capacitor based on black-TiO2-x/graphene aerogel anode and biomass-derived microporous carbon cathode Zhu, Guoyin; Ma, Lianbo; Lin, Huinan Nano Research, Vol. 12, Issue 7 https://doi.org/10.1007/s12274-019-2427-3	journal	May 2019
V2O5 encapsulated MWCNTs in 2D surface architecture: Complete solid-state bendable highly stabilized energy efficient supercapacitor device Pandit, Bidhan; Dubal, Deepak P.; Gómez-Romero, Pedro Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep43430	journal	March 2017
Highly conductive and flexible molybdenum oxide nanopaper for high volumetric supercapacitor electrode Huang, Liang; Yao, Bin; Sun, Jiyu Journal of Materials Chemistry A, Vol. 5, Issue 6 https://doi.org/10.1039/c6ta10433a	journal	January 2017
Recent advances in chemical methods for activating carbon and metal oxide based electrodes for supercapacitors Kou, Tianyi; Yao, Bin; Liu, Tianyu J. Mater. Chem. A, Vol. 5, Issue 33 https://doi.org/10.1039/c7ta05003h	journal	January 2017
Pseudocapacitance contribution in boron-doped graphite sheets for anion storage enables high-performance sodium-ion capacitors Yu, Feng; Liu, Zaichun; Zhou, Renwu Materials Horizons, Vol. 5, Issue 3 https://doi.org/10.1039/c8mh00156a	journal	January 2018
Transition metal oxides for aqueous sodium-ion electrochemical energy storage Boyd, Shelby; Augustyn, Veronica Inorganic Chemistry Frontiers, Vol. 5, Issue 5 https://doi.org/10.1039/c8qi00148k	journal	January 2018
Perovskite KNi _0.1 Co _0.9 F ₃ as a pseudocapacitive conversion anode for high-performance nonaqueous Li-ion capacitors and dual-ion batteries Xu, Qilei; Ding, Rui; Shi, Wei Journal of Materials Chemistry A, Vol. 7, Issue 14 https://doi.org/10.1039/c9ta00493a	journal	January 2019
Oxygen vacancy-enriched MoO _3−x nanobelts for asymmetric supercapacitors with excellent room/low temperature performance Wu, Qi-Long; Zhao, Shi-Xi; Yu, Le Journal of Materials Chemistry A, Vol. 7, Issue 21 https://doi.org/10.1039/c9ta03471d	journal	January 2019
Improvement of the thermoelectric properties of a MoO ₃ monolayer through oxygen vacancies Zheng, Wenwen; Cao, Wei; Wang, Ziyu Beilstein Journal of Nanotechnology, Vol. 10 https://doi.org/10.3762/bjnano.10.199	journal	January 2019

Similar Records

Polymerization of aniline in the interlayer space of molybdenum trioxide and its electrochemical properties

Journal Article · Sat Aug 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry · OSTI ID:21370518

Synthesis and characterization of α-MoO{sub 3} nanobelt composite positive electrode materials for lithium battery application

Journal Article · Mon Jun 15 00:00:00 EDT 2015 · Materials Research Bulletin · OSTI ID:22475797

Interlayer gap widened $α$-phase molybdenum trioxide as high-rate anodes for dual-ion-intercalation energy storage devices

Journal Article · Wed Mar 11 20:00:00 EDT 2020 · Nature Communications · OSTI ID:1606537

Related Subjects

25 ENERGY STORAGE

Ethanol Reduced Molybdenum Trioxide for Li-ion Capacitors

Citation Formats

References (36)

Cited By (18)

Similar Records

Related Subjects