Interlayer gap widened $α$-phase molybdenum trioxide as high-rate anodes for dual-ion-intercalation energy storage devices

Yu, Minghao; Shao, Hui; Wang, Gang; Yang, Fan; Liang, Chaolun; Rozier, Patrick; Wang, Cai-Zhuang; Lu, Xihong; Simon, Patrice; Feng, Xinliang

doi:10.1038/s41467-020-15216-w

Interlayer gap widened $$α$$-phase molybdenum trioxide as high-rate anodes for dual-ion-intercalation energy storage devices

Journal Article · Thu Mar 12 00:00:00 EDT 2020 · Nature Communications

DOI:https://doi.org/10.1038/s41467-020-15216-w· OSTI ID:1606537

^[1]; Shao, Hui ^[2]; ^[1]; Yang, Fan ^[3]; Liang, Chaolun ^[3]; ^[2]; Wang, Cai-Zhuang ^[4]; Lu, Xihong ^[3]; Simon, Patrice ^[2]; ^[1]

Technische Univ. Dresden (Germany)
Univ. de Toulouse (France)
Sun Yat-sen Univ., Guangzhou (China)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

Employing high-rate ion-intercalation electrodes represents a feasible way to mitigate the inherent trade-off between energy density and power density for electrochemical energy storage devices, but efficient approaches to boost the charge-storage kinetics of electrodes are still needed. Here, we demonstrate a water-incorporation strategy to expand the interlayer gap of α-MoO₃, in which water molecules take the place of lattice oxygen of α-MoO₃. Accordingly, the modified α-MoO₃ electrode exhibits theoretical-value-close specific capacity (963 C g^–1 at 0.1 mV s^–1), greatly improved rate capability (from 4.4% to 40.2% at 100 mV s^–1) and boosted cycling stability (from 21 to 71% over 600 cycles). A fast-kinetics dual-ion-intercalation energy storage device is further assembled by combining the modified α-MoO₃ anode with an anion-intercalation graphite cathode, operating well over a wide discharge rate range. Our study sheds light on a promising design strategy of layered materials for high-kinetics charge storage.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: Agence Nationale de la Recherché (ANR); Alexander von Humboldt Foundation; China Scholarship Council (CSC); Deutsche Forschungsgemeinschaft (DFG); European Research Council (ERC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1606537

Report Number(s):: IS--J-10182

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 11; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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