Development of 1100&nbsp;°C Capable Alumina-Forming Austenitic Alloys

Brady, M. P.; Muralidharan, G.; Yamamoto, Y.; Pint, B. A.

doi:10.1007/s11085-016-9667-3

Development of 1100 °C Capable Alumina-Forming Austenitic Alloys

Journal Article · Fri Nov 18 00:00:00 EST 2016 · Oxidation of Metals

DOI:https://doi.org/10.1007/s11085-016-9667-3· OSTI ID:1344247

Brady, M. P. ^[1]; Muralidharan, G. ^[1]; Yamamoto, Y. ^[1]; Pint, B. A. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Recently dalumina-forming austenitic (AFA) alloys based on ~12–32 weight % (wt%) Ni have been developed and offer an attractive combination of oxidation resistance and creep resistance at relatively low alloy cost. But, they exhibit a transition to internal oxidation and nitridation of Al above ~750–950 °C depending on composition and exposure environment. In order to identify AFA compositions capable of higher-temperature operation for applications such as ethylene cracking, the oxidation behavior of a series of developmental, as-cast nominal Fe–(25–45)Ni–(10–25)Cr–(4–5)Al–1Si–0.15Hf–0.07Y–0.01B wt% base alloys with and without Nb, Ti, and C additions was evaluated at 1100 °C in air with 10% water vapor. Furthermore, we observed protective alumina scale formation at levels of 35Ni, 25Cr, and 4Al with additions of Nb and C, indicating promise for 1100°C capable cast AFA alloys.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1344247

Journal Information:: Oxidation of Metals, Journal Name: Oxidation of Metals Journal Issue: 1-2 Vol. 87; ISSN 0030-770X

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
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Development of 1100 °C Capable Alumina-Forming Austenitic Alloys

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