Reversible Control of Interfacial Magnetism through Ionic-Liquid-Assisted Polarization Switching

Herklotz, Andreas; Guo, Er-Jia; Wong, Anthony T.; Meyer, Tricia L.; Dai, Sheng; Ward, T. Zac; Lee, Ho Nyung; Fitzsimmons, Michael R.

doi:10.1021/acs.nanolett.6b04949

Title: Reversible Control of Interfacial Magnetism through Ionic-Liquid-Assisted Polarization Switching

Journal Article · Mon Feb 06 00:00:00 EST 2017 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.6b04949· OSTI ID:1343529

; Guo, Er-Jia; Wong, Anthony T.; Meyer, Tricia L.;

; Ward, T. Zac; Lee, Ho Nyung; Fitzsimmons, Michael R.

The ability to control magnetism of materials via electric field enables a myriad of technological innovations in information storage, sensing, and computing. In this paper, we use ionic-liquid-assisted ferroelectric switching to demonstrate reversible modulation of interfacial magnetism in a multiferroic heterostructure composed of ferromagnetic (FM) La_0.8Sr_0.2MnO₃ and ferroelectric (FE) PbZr_0.2Ti_0.8O₃. It is shown that ionic liquids can be used to persistently and reversibly switch a large area of a FE film. Finally, this is a prerequisite for polarized neutron reflectometry (PNR) studies that are conducted to directly probe magnetoelectric coupling of the FE polarization to the interfacial magnetization.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1343529

Journal Information:: Nano Letters, Vol. 17, Issue 3; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 27 works

Citation information provided by
Web of Science

References (31)

Electrostatic carrier doping to perovskite transition-metal oxides Inoue, I. H. Semiconductor Science and Technology, Vol. 20, Issue 4 https://doi.org/10.1088/0268-1242/20/4/013	journal	March 2005
Ferroelectric-field-effect-enhanced electroresistance in metal/ferroelectric/semiconductor tunnel junctions Wen, Zheng; Li, Chen; Wu, Di Nature Materials, Vol. 12, Issue 7 https://doi.org/10.1038/nmat3649	journal	May 2013
Piezoelectrically induced resistance modulations in La0.7Sr0.3MnO3∕Pb(Zr,Ti)O3 field effect devices Thiele, C.; Dörr, K.; Schultz, L. Applied Physics Letters, Vol. 87, Issue 16 https://doi.org/10.1063/1.2108129	journal	October 2005
Full Electric Control of Exchange Bias Wu, S. M.; Cybart, Shane A.; Yi, D. Physical Review Letters, Vol. 110, Issue 6 https://doi.org/10.1103/PhysRevLett.110.067202	journal	February 2013
Strongly coupled phase transition in ferroelectric/correlated electron oxide heterostructures Jiang, Lu; Seok Choi, Woo; Jeen, Hyoungjeen Applied Physics Letters, Vol. 101, Issue 4 https://doi.org/10.1063/1.4738784	journal	July 2012
Colossal magnetoresistive manganite-based ferroelectric field-effect transistor on Si Zhao, T.; Ogale, S. B.; Shinde, S. R. Applied Physics Letters, Vol. 84, Issue 5 https://doi.org/10.1063/1.1644321	journal	February 2004
Electric field effect in correlated oxide systems Ahn, C. H.; Triscone, J. -M.; Mannhart, J. Nature, Vol. 424, Issue 6952 https://doi.org/10.1038/nature01878	journal	August 2003
Magnetoelectric Effects in Complex Oxides with Competing Ground States Molegraaf, Hajo J. A.; Hoffman, Jason; Vaz, Carlos A. F. Advanced Materials, Vol. 21, Issue 34 https://doi.org/10.1002/adma.200900278	journal	September 2009
Control of magnetism in Pb(Zr _0.2 Ti _0.8 )O ₃ /La _0.8 Sr _0.2 MnO ₃ multiferroic heterostructures (invited) Vaz, C. A. F.; Hoffman, J.; Segal, Y. Journal of Applied Physics, Vol. 109, Issue 7 https://doi.org/10.1063/1.3540694	journal	April 2011
Electric modulation of magnetization at the BaTiO ₃ /La _0.67 Sr _0.33 MnO ₃ interfaces Lu, H.; George, T. A.; Wang, Y. Applied Physics Letters, Vol. 100, Issue 23 https://doi.org/10.1063/1.4726427	journal	June 2012
Physics of thin-film ferroelectric oxides Dawber, M.; Rabe, K. M.; Scott, J. F. Reviews of Modern Physics, Vol. 77, Issue 4 https://doi.org/10.1103/RevModPhys.77.1083	journal	October 2005
Enhancing interfacial magnetization with a ferroelectric Meyer, Tricia L.; Herklotz, Andreas; Lauter, Valeria Physical Review B, Vol. 94, Issue 17 https://doi.org/10.1103/PhysRevB.94.174432	journal	November 2016
Suppressed Dependence of Polarization on Epitaxial Strain in Highly Polar Ferroelectrics Lee, Ho Nyung; Nakhmanson, Serge M.; Chisholm, Matthew F. Physical Review Letters, Vol. 98, Issue 21 https://doi.org/10.1103/PhysRevLett.98.217602	journal	May 2007
Electrostatic Gating of Ultrathin Films Goldman, A. M. Annual Review of Materials Research, Vol. 44, Issue 1 https://doi.org/10.1146/annurev-matsci-070813-113407	journal	July 2014
Upward ferroelectric self-poling in (001) oriented PbZr _0.2 Ti _0.8 O ₃ epitaxial films with compressive strain Luo, Ying; Li, Xueyan; Chang, Lei AIP Advances, Vol. 3, Issue 12 https://doi.org/10.1063/1.4840595	journal	December 2013
Thickness-Dependent Crossover from Charge- to Strain-Mediated Magnetoelectric Coupling in Ferromagnetic/Piezoelectric Oxide Heterostructures Spurgeon, Steven R.; Sloppy, Jennifer D.; Kepaptsoglou, Despoina Maria (Demie) ACS Nano, Vol. 8, Issue 1 https://doi.org/10.1021/nn405636c	journal	December 2013
Magnetic Properties at Surface Boundary of a Half-Metallic Ferromagnet ${La}_{0.7} {Sr}_{0.3} {MnO}_{3}$ Park, J. -H.; Vescovo, E.; Kim, H. -J. Physical Review Letters, Vol. 81, Issue 9 https://doi.org/10.1103/PhysRevLett.81.1953	journal	August 1998
Surface behavior of La2∕3Ca1∕3MnO3 epitaxial thin films Abad, Ll.; Martínez, B.; Balcells, Ll. Applied Physics Letters, Vol. 87, Issue 21 https://doi.org/10.1063/1.2133925	journal	November 2005
Insulator-metal transition induced by interlayer coupling in ${La}_{0.6} {Sr}_{0.4} {MnO}_{3} /$ ${SrTiO}_{3}$ superlattices Izumi, M.; Ogimoto, Y.; Okimoto, Y. Physical Review B, Vol. 64, Issue 6 https://doi.org/10.1103/PhysRevB.64.064429	journal	July 2001
Critical thickness and orbital ordering in ultrathin ${La}_{0.7} {Sr}_{0.3} {MnO}_{3}$ films Huijben, M.; Martin, L. W.; Chu, Y. -H. Physical Review B, Vol. 78, Issue 9 https://doi.org/10.1103/PhysRevB.78.094413	journal	September 2008
Tuning the entanglement between orbital reconstruction and charge transfer at a film surface Cui, B.; Song, C.; Li, F. Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04206	journal	February 2014
Reversible Ferromagnetic Phase Transition in Electrode-Gated Manganites Cui, Bin; Song, Cheng; Wang, Guangyue Advanced Functional Materials, Vol. 24, Issue 46 https://doi.org/10.1002/adfm.201402007	journal	September 2014
Ferroelectric control of magnetization in La $_{1 - x}$ Sr $_{x}$ MnO $_{3}$ manganites: A first-principles study Chen, Hanghui; Ismail-Beigi, Sohrab Physical Review B, Vol. 86, Issue 2 https://doi.org/10.1103/PhysRevB.86.024433	journal	July 2012
Direct observation of ferroelectric field effect and vacancy-controlled screening at the BiFeO3/LaxSr1−xMnO3 interface Kim, Young-Min; Morozovska, Anna; Eliseev, Eugene Nature Materials, Vol. 13, Issue 11 https://doi.org/10.1038/nmat4058	journal	August 2014
Prediction of electrically induced magnetic reconstruction at the manganite/ferroelectric interface Burton, J. D.; Tsymbal, E. Y. Physical Review B, Vol. 80, Issue 17 https://doi.org/10.1103/PhysRevB.80.174406	journal	November 2009
Tunneling Electroresistance Induced by Interfacial Phase Transitions in Ultrathin Oxide Heterostructures Jiang, Lu; Choi, Woo Seok; Jeen, Hyoungjeen Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl4025598	journal	November 2013
Ferroelectric capped magnetization in multiferroic PZT/LSMO tunnel junctions Kumar, Ashok; Barrionuevo, D.; Ortega, N. Applied Physics Letters, Vol. 106, Issue 13 https://doi.org/10.1063/1.4916732	journal	March 2015
Control of Emergent Properties at a Correlated Oxide Interface with Graphene Zhou, You; Park, Jungwon; Shi, Jian Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl504170d	journal	February 2015
Suppression of Metal-Insulator Transition in VO2 by Electric Field-Induced Oxygen Vacancy Formation Jeong, J.; Aetukuri, N.; Graf, T. Science, Vol. 339, Issue 6126 https://doi.org/10.1126/science.1230512	journal	March 2013
Facet-Independent Electric-Field-Induced Volume Metallization of Tungsten Trioxide Films Altendorf, Simone G.; Jeong, Jaewoo; Passarello, Donata Advanced Materials, Vol. 28, Issue 26 https://doi.org/10.1002/adma.201505631	journal	May 2016
GenX : an extensible X-ray reflectivity refinement program utilizing differential evolution Björck, Matts; Andersson, Gabriella Journal of Applied Crystallography, Vol. 40, Issue 6 https://doi.org/10.1107/S0021889807045086	journal	November 2007

Cited By (12)

Voltage‐Control of Magnetism in All‐Solid‐State and Solid/Liquid Magnetoelectric Composites Molinari, Alan; Hahn, Horst; Kruk, Robert Advanced Materials, Vol. 31, Issue 26 https://doi.org/10.1002/adma.201806662	journal	February 2019
Electric-Field Control of Oxygen Vacancies and Magnetic Phase Transition in a Cobaltite/Manganite Bilayer Cui, B.; Song, C.; Li, F. Physical Review Applied, Vol. 8, Issue 4 https://doi.org/10.1103/physrevapplied.8.044007	journal	October 2017
Relating Franck-Condon blockade to redox chemistry in the single-particle picture Bevan, Kirk H.; Roy-Gobeil, Antoine; Miyahara, Yoichi The Journal of Chemical Physics, Vol. 149, Issue 10 https://doi.org/10.1063/1.5043480	journal	September 2018
Electrolyte-gated magnetoelectric actuation: Phenomenology, materials, mechanisms, and prospective applications Navarro-Senent, Cristina; Quintana, Alberto; Menéndez, Enric APL Materials, Vol. 7, Issue 3 https://doi.org/10.1063/1.5080284	journal	March 2019
Spatially Resolved Large Magnetization in Ultrathin BiFeO ₃ Guo, Er-Jia; Petrie, Jonathan R.; Roldan, Manuel A. Advanced Materials, Vol. 29, Issue 32 https://doi.org/10.1002/adma.201700790	journal	June 2017
Water printing of ferroelectric polarization Tian, Yu; Wei, Lanying; Zhang, Qinghua Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06369-w	journal	September 2018
Removal of the Magnetic Dead Layer by Geometric Design Guo, Er-Jia; Roldan, Manuel A.; Charlton, Timothy Advanced Functional Materials, Vol. 28, Issue 30 https://doi.org/10.1002/adfm.201800922	journal	May 2018
Ferroelectric field control of charge density in oxide films with polarization reversal by electric double layer Nishino, Ryutaro; Kozuka, Yusuke; Kagawa, Fumitaka Applied Physics Letters, Vol. 113, Issue 14 https://doi.org/10.1063/1.5047558	journal	October 2018
Ionic Gating of Ultrathin and Leaky Ferroelectrics Sharma, Yogesh; Wong, Anthony T.; Herklotz, Andreas Advanced Materials Interfaces, Vol. 6, Issue 5 https://doi.org/10.1002/admi.201801723	journal	January 2019
Phase-field simulations of surface charge-induced polarization switching Liu, Di; Zhao, Ru; Jafri, Hasnain Mehdi Applied Physics Letters, Vol. 114, Issue 11 https://doi.org/10.1063/1.5083126	journal	March 2019
Insulating-to-conducting behavior and band profile across the La0.9Ba0.1MnO3/Nb:SrTiO3 epitaxial interface Li, W.; Kleibeuker, Je; Wu, R. American Physical Society (APS) https://doi.org/10.17863/cam.22887	journalarticle	January 2017
Voltage-Control of Magnetism in All-Solid-State and Solid/Liquid Magnetoelectric Composites Molinari, A.; Hahn, H.; Kruk, R. Karlsruhe https://doi.org/10.5445/ir/1000092768	text	January 2019

Similar Records

Strain vs. charge mediated magnetoelectric coupling across the magnetic oxide/ferroelectric interfaces

Journal Article · Mon Apr 29 00:00:00 EDT 2019 · RSC Advances · OSTI ID:1343529

Paudel, Binod; Vasiliev, Igor; Hammouri, Mahmoud; +4 more

Ferroelectric Self-Polarization Controlled Magnetic Stratification and Magnetic Coupling in Ultrathin La_0.67Sr_0.33MnO₃ Films

Journal Article · Thu Jun 17 00:00:00 EDT 2021 · ACS Applied Materials and Interfaces · OSTI ID:1343529

Liu, Chao; Liu, Yaohua; Zhang, Bangmin; +11 more

Electric field induced reversible 180° magnetization switching through tuning of interfacial exchange bias along magnetic easy-axis in multiferroic laminates

Journal Article · Wed Nov 18 00:00:00 EST 2015 · Scientific Reports · OSTI ID:1343529

Xue, Xu; Zhou, Ziyao; Peng, Bin; +8 more

Related Subjects

36 MATERIALS SCIENCE
ferroelectric field effect
ionic liquid gating
Magnetoelectric coupling
polarized neutron reflectometry
strongly correlated oxide

Title: Reversible Control of Interfacial Magnetism through Ionic-Liquid-Assisted Polarization Switching

Citation Formats

References (31)

Cited By (12)

Similar Records

Related Subjects