Precise Access to the Molecular-Frame Complex Recombination Dipole through High-Harmonic Spectroscopy

Schoun, S. B.; Camper, A.; Salieres, P.; Lucchese, R. R.; Agostini, P.; DiMauro, L. F.

doi:10.1103/PhysRevLett.118.033201

Title: Precise Access to the Molecular-Frame Complex Recombination Dipole through High-Harmonic Spectroscopy

Journal Article · Thu Jan 19 00:00:00 EST 2017 · Physical Review Letters

DOI:https://doi.org/10.1103/PhysRevLett.118.033201· OSTI ID:1461115

Schoun, S. B. ^[1]; Camper, A. ^[1]; Salieres, P. ^[2]; Lucchese, R. R. ^[3]; Agostini, P. ^[1]; DiMauro, L. F. ^[1]

The Ohio State Univ., Columbus, OH (United States). Dept. of Physics
Alternative Energies and Atomic Energy Commission (CEA), Saclay (France). Interactions, Dynamics and Lasers Lab. (LIDYL)
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry

In this paper, we report on spectral intensity and group delay measurements of the highest-occupied molecular-orbital (HOMO) recombination dipole moment of $${\mathrm{N}}_{2}$$ in the molecular-frame using high harmonic spectroscopy. We take advantage of the long-wavelength $$1.3\text{ }\text{ }{\mu}\mathrm{m}$$ driving laser to isolate the HOMO in the near threshold region, 19–67 eV. Finally, the precision of our group delay measurements reveals previously unseen angle-resolved spectral features associated with autoionizing resonances, and allows quantitative comparison with cutting-edge correlated 8-channel photoionization dipole moment calculations.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Center for Scientific Research (CNRS) International Project of Scientific Cooperation (PICS) (France)

Grant/Contract Number:: FG02-04ER15614; FG02-06ER15833; 5460

OSTI ID:: 1461115

Alternate ID(s):: OSTI ID: 1341314

Journal Information:: Physical Review Letters, Vol. 118, Issue 3; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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