Synthesis, characterization and thermodynamic study of carbon dioxide adsorption on akaganéite

Roque-Malherbe, R.; Lugo, F.; Rivera-Maldonado, C.; Polanco-Estrella, R.; Uwakweh, O.

doi:10.1016/j.cap.2015.01.016

Synthesis, characterization and thermodynamic study of carbon dioxide adsorption on akaganéite

Journal Article · Wed Apr 01 00:00:00 EDT 2015 · Current Applied Physics

DOI:https://doi.org/10.1016/j.cap.2015.01.016· OSTI ID:1336314

^[1]; Lugo, F. ^[2]; Rivera-Maldonado, C. ^[2]; Polanco-Estrella, R. ^[2]; Uwakweh, O. ^[2]

Univ. of Turabo (Puerto Rico); Univ. of Puerto Rico, Mayaguez (Puerto Rico); Universidad del Turabo
Univ. of Turabo (Puerto Rico); Univ. of Puerto Rico, Mayaguez (Puerto Rico)

A mixture of akaganeite nanoparticles and sodium salts was synthesized and modi fied, first by washing, and then by Li exchange. The structural characterization of the produced materials was performed with: powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, thermogravimetric analysis, diffuse reflectance infrared Fourier transform spectrometry, Mossbauer spectros- € copy and magnetization measurements. Additionally low pressure nitrogen and high pressure carbon dioxide adsorption experiments were performed. The sum of the characterization information made possible to conclude that the produced akaganeite phases crystallized in a structure exhibiting the symmetry of the I2/m space group, where the measured equivalent spherical diameter of the akaganeite crystallites yielded 9 nm, as well, the tested phases exhibited a standard behaviour under heating and displayed a superparamagnetic behaviour. Finally the high pressure carbon dioxide adsorption experiments demonstrated a pressure-responsive framework opening event due to a structural transformation of the adsorbent framework induced by the guest molecules. This fact opens new applications for akaganeite as a high pressure adsorbent.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Turabo (Puerto Rico)

Sponsoring Organization:: USDOE; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0000672

OSTI ID:: 1336314

Alternate ID(s):: OSTI ID: 1251914

Journal Information:: Current Applied Physics, Journal Name: Current Applied Physics Journal Issue: 4 Vol. 15; ISSN 1567-1739

Publisher:: Korean Physical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (45)

The theory of adsorption equilibrium, based on the thermodynamics of vacancy solutions Bering, B. P.; Serpinskii, V. V. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 23, Issue 11 https://doi.org/10.1007/BF00922108	journal	November 1974
Solution thermodynamics of adsorption in microporous adsorbents Roque-Malherbe, R. Journal of Thermal Analysis, Vol. 32, Issue 5 https://doi.org/10.1007/BF01913336	journal	September 1987
Synthesis of α- and β-FeOOH iron oxide nanoparticles in non-ionic surfactant medium Bashir, S.; McCabe, R. W.; Boxall, C. Journal of Nanoparticle Research, Vol. 11, Issue 3 https://doi.org/10.1007/s11051-008-9467-z	journal	August 2008
Magnetic properties of ferritin and akaganeite nanoparticles in aqueous suspension Koralewski, Marceli; Pochylski, Mikołaj; Gierszewski, Jacek Journal of Nanoparticle Research, Vol. 15, Issue 9 https://doi.org/10.1007/s11051-013-1902-0	journal	August 2013
Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate Waychunas, G. A.; Rea, B. A.; Fuller, C. C. Geochimica et Cosmochimica Acta, Vol. 57, Issue 10 https://doi.org/10.1016/0016-7037(93)90567-G	journal	May 1993
On thermodynamics of adsorption in micropores Bering, B. P.; Dubinin, M. M.; Serpinsky, V. V. Journal of Colloid and Interface Science, Vol. 38, Issue 1 https://doi.org/10.1016/0021-9797(72)90233-0	journal	January 1972
Thermal behaviour in air of iron oxyhydroxides obtained from the method of homogeneous precipitation Goñi-Elizalde, S.; García-Clavel, Ma E. Thermochimica Acta, Vol. 129, Issue 2 https://doi.org/10.1016/0040-6031(88)87348-9	journal	July 1988
On the Néel temperature of βFeOOH: Structural dependence and its implications Chambaere, D.; De Grave, E. Journal of Magnetism and Magnetic Materials, Vol. 42, Issue 3 https://doi.org/10.1016/0304-8853(84)90107-0	journal	May 1984
Surface chemistry of carbon dioxide Freund, H. -J.; Roberts, M. W. Surface Science Reports, Vol. 25, Issue 8 https://doi.org/10.1016/S0167-5729(96)00007-6	journal	January 1996
Thermal decomposition of β-FeOOH Musić, S.; Krehula, S.; Popović, S. Materials Letters, Vol. 58, Issue 3-4 https://doi.org/10.1016/S0167-577X(03)00522-6	journal	January 2004
Complementary approach to the volume filling theory of adsorption in zeolites Roque-Malherbe, Rolando Microporous and Mesoporous Materials, Vol. 41, Issue 1-3 https://doi.org/10.1016/S1387-1811(00)00296-1	journal	December 2000
Phosphate adsorption on synthetic goethite and akaganeite Chitrakar, Ramesh; Tezuka, Satoko; Sonoda, Akinari Journal of Colloid and Interface Science, Vol. 298, Issue 2 https://doi.org/10.1016/j.jcis.2005.12.054	journal	June 2006
Adsorptive removal of arsenites by a nanocrystalline hybrid surfactant–akaganeite sorbent Deliyanni, E. A.; Nalbandian, L.; Matis, K. A. Journal of Colloid and Interface Science, Vol. 302, Issue 2 https://doi.org/10.1016/j.jcis.2006.07.007	journal	October 2006
Calculation of the energy of adsorption of n-paraffins in nanoporous crystalline and ordered acid catalysts, and its relationship with the activation energy of the monomolecular catalytic cracking reaction Roque-Malherbe, Rolando; Diaz-Castro, F. Journal of Molecular Catalysis A: Chemical, Vol. 280, Issue 1-2 https://doi.org/10.1016/j.molcata.2007.11.011	journal	February 2008
Varying the microstructural properties of ZnO particles using different synthesis routes Šarić, Ankica; Musić, Svetozar; Ivanda, Mile Journal of Molecular Structure, Vol. 993, Issue 1-3 https://doi.org/10.1016/j.molstruc.2010.10.018	journal	May 2011
Comparative study of phosphates removal from aqueous solutions by nanocrystalline akaganéite and hybrid surfactant-akaganéite Deliyanni, E.; Peleka, E.; Lazaridis, N. Separation and Purification Technology, Vol. 52, Issue 3 https://doi.org/10.1016/j.seppur.2006.05.028	journal	January 2007
Iron(III) Oxides from Thermal ProcessesSynthesis, Structural and Magnetic Properties, Mössbauer Spectroscopy Characterization, and Applications ^† Zboril, Radek; Mashlan, Miroslav; Petridis, Dimitris Chemistry of Materials, Vol. 14, Issue 3 https://doi.org/10.1021/cm0111074	journal	March 2002
Energetics of Bulk and Nano-Akaganeite, β-FeOOH: Enthalpy of Formation, Surface Enthalpy, and Enthalpy of Water Adsorption Mazeina, Lena; Deore, Suraj; Navrotsky, Alexandra Chemistry of Materials, Vol. 18, Issue 7 https://doi.org/10.1021/cm052543j	journal	April 2006
² H and ⁷ Li Solid-State MAS NMR Study of Local Environments and Lithium Adsorption on the Iron(III) Oxyhydroxide, Akaganeite (β-FeOOH) Kim, Jongsik; Grey, Clare P. Chemistry of Materials, Vol. 22, Issue 19 https://doi.org/10.1021/cm100816h	journal	October 2010
Polymorphous Transformations of Nanometric Iron(III) Oxide: A Review Machala, Libor; Tuček, Jiří; Zbořil, Radek Chemistry of Materials, Vol. 23, Issue 14 https://doi.org/10.1021/cm200397g	journal	July 2011
Density Functional Theory Study of Ferrihydrite and Related Fe-Oxyhydroxides Pinney, Nathan; Kubicki, James D.; Middlemiss, Derek S. Chemistry of Materials, Vol. 21, Issue 24 https://doi.org/10.1021/cm9023875	journal	December 2009
Magnetic Nanoparticles: Design and Characterization, Toxicity and Biocompatibility, Pharmaceutical and Biomedical Applications Reddy, L. Harivardhan; Arias, José L.; Nicolas, Julien Chemical Reviews, Vol. 112, Issue 11 https://doi.org/10.1021/cr300068p	journal	September 2012
Fugacity Examples David, Carl W. Journal of Chemical Education, Vol. 81, Issue 11 https://doi.org/10.1021/ed081p1653	journal	November 2004
Local Environments and Lithium Adsorption on the Iron Oxyhydroxides Lepidocrocite (γ-FeOOH) and Goethite (α-FeOOH): A ² H and ⁷ Li Solid-State MAS NMR Study Kim, Jongsik; Nielsen, Ulla Gro; Grey, Clare P. Journal of the American Chemical Society, Vol. 130, Issue 4 https://doi.org/10.1021/ja0761028	journal	January 2008
Study of the Interaction between Silica Surfaces and the Carbon Dioxide Molecule Roque-Malherbe, R.; Polanco-Estrella, R.; Marquez-Linares, F. The Journal of Physical Chemistry C, Vol. 114, Issue 41 https://doi.org/10.1021/jp107754g	journal	September 2010
The Behavior of Flexible MIL-53(Al) upon CH ₄ and CO ₂ Adsorption Boutin, Anne; Coudert, François-Xavier; Springuel-Huet, Marie-Anne The Journal of Physical Chemistry C, Vol. 114, Issue 50 https://doi.org/10.1021/jp108710h	journal	December 2010
Use of Nanoporous FeOOH as a Catalytic Support for NaHCO ₃ Decomposition Aimed at Reduction of Energy Requirement of Na ₂ CO ₃ /NaHCO ₃ Based CO ₂ Separation Technology Dutcher, Bryce; Fan, Maohong; Leonard, Brian The Journal of Physical Chemistry C, Vol. 115, Issue 31 https://doi.org/10.1021/jp204899r	journal	July 2011
Structural Effects and Interactions of Carbon Dioxide Molecules Adsorbed on Ni, Zn, and Cd Nitroprussides Roque-Malherbe, R.; Uwakweh, O. N. C.; Lozano, C. The Journal of Physical Chemistry C, Vol. 115, Issue 31 https://doi.org/10.1021/jp205104r	journal	July 2011
Variable Hydrogen Bond Strength in Akaganéite Song, Xiaowei; Boily, Jean-François The Journal of Physical Chemistry C, Vol. 116, Issue 3 https://doi.org/10.1021/jp2097108	journal	November 2011
Size Distribution and Frustrated Antiferromagnetic Coupling Effects on the Magnetic Behavior of Ultrafine Akaganéite (β-FeOOH) Nanoparticles Luna, Carlos; Ilyn, Maxim; Vega, Víctor The Journal of Physical Chemistry C, Vol. 118, Issue 36 https://doi.org/10.1021/jp5048634	journal	August 2014
Structure and Morphology Evolution of Hematite (α-Fe ₂ O ₃ ) Nanoparticles in Forced Hydrolysis of Ferric Chloride Wang, Wei; Howe, Jane Y.; Gu, Baohua The Journal of Physical Chemistry C, Vol. 112, Issue 25 https://doi.org/10.1021/jp800683j	journal	June 2008
Size Control Synthesis of Uniform β-FeOOH to High Coercive Field Porous Magnetic α-Fe ₂ O ₃ Nanorods Chaudhari, Nitin K.; Yu, Jong-Sung The Journal of Physical Chemistry C, Vol. 112, Issue 50 https://doi.org/10.1021/jp808589y	journal	November 2008
Adsorption in Porous Materials at High Pressure: Theory and Experiment Myers, A. L.; Monson, P. A. Langmuir, Vol. 18, Issue 26 https://doi.org/10.1021/la026399h	journal	December 2002
Net Adsorption: A Thermodynamic Framework for Supercritical Gas Adsorption and Storage in Porous Solids Gumma, Sasidhar; Talu, Orhan Langmuir, Vol. 26, Issue 22 https://doi.org/10.1021/la102186q	journal	November 2010
Rapid Characterization of Agglomerate Aerosols by In Situ Mass−Mobility Measurements Scheckman, Jacob H.; McMurry, Peter H.; Pratsinis, Sotiris E. Langmuir, Vol. 25, Issue 14 https://doi.org/10.1021/la900441e	journal	July 2009
Calorimetric Heats of Adsorption and Adsorption Isotherms. 2. O ₂ , N ₂ , Ar, CO ₂ , CH ₄ , C ₂ H ₆ , and SF ₆ on NaX, H-ZSM-5, and Na-ZSM-5 Zeolites Dunne, J. A.; Rao, M.; Sircar, S. Langmuir, Vol. 12, Issue 24 https://doi.org/10.1021/la960496r	journal	January 1996
CO ₂ As an Adsorptive To Characterize Carbon Molecular Sieves and Activated Carbons Cazorla-Amorós, D.; Alcañiz-Monge, J.; de la Casa-Lillo, M. A. Langmuir, Vol. 14, Issue 16 https://doi.org/10.1021/la980198p	journal	August 1998
The effect of phosphonate-based growth modifiers on the morphology of hematite nanoparticles formed via acid hydrolysis of ferric chloride solutions Jones, Franca; Ogden, Mark I.; Oliveira, Allan CrystEngComm, Vol. 5, Issue 30 https://doi.org/10.1039/b302911e	journal	January 2003
The osmotic framework adsorbed solution theory: predicting mixture coadsorption in flexible nanoporous materials Coudert, François-Xavier Physical Chemistry Chemical Physics, Vol. 12, Issue 36 https://doi.org/10.1039/c003434g	journal	January 2010
The nature of iron in Akaganéite (β-FeOOH) Childs, Cw; Goodman, Ba; Paterson, E. Australian Journal of Chemistry, Vol. 33, Issue 1 https://doi.org/10.1071/CH9800015	journal	January 1980
Supermagnetism Bedanta, Subhankar; Kleemann, Wolfgang Journal of Physics D: Applied Physics, Vol. 42, Issue 1 https://doi.org/10.1088/0022-3727/42/1/013001	journal	December 2008
New analysis of the Mössbauer spectra of akaganeite Barrero, C. A.; García, K. E.; Morales, A. L. Journal of Physics: Condensed Matter, Vol. 18, Issue 29 https://doi.org/10.1088/0953-8984/18/29/020	journal	July 2006
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Size-Driven Structural and Thermodynamic Complexity in Iron Oxides Navrotsky, A.; Mazeina, L.; Majzlan, J. Science, Vol. 319, Issue 5870 https://doi.org/10.1126/science.1148614	journal	March 2008
Neutron and temperature-resolved synchrotron X-ray powder diffraction study of akaganéite Post, Jeffrey E.; Heaney, Peter J.; Von Dreele, Robert B. American Mineralogist, Vol. 88, Issue 5-6 https://doi.org/10.2138/am-2003-5-607	journal	May 2003

Cited By (1)

Influences of As( v ), Sb( iii ), and Hg( ii ) ions on the nucleation and growth of akaganeite Villacorta, Verónica; García, Karen Edilma; Greneche, Jean-Marc CrystEngComm, Vol. 21, Issue 46 https://doi.org/10.1039/c9ce01345h	journal	January 2019

Similar Records

Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph

Journal Article · Wed May 13 20:00:00 EDT 2015 · Journal of Physics and Chemistry of Solids · OSTI ID:1336313

Direct Structural Identification of Gas Induced Gate‐Opening Coupled with Commensurate Adsorption in a Microporous Metal–Organic Framework

Journal Article · Wed Jul 06 20:00:00 EDT 2016 · Chemistry - A European Journal · OSTI ID:1400463

Study of the surface chemistry and morphology of single walled carbon nanotube–magnetite composites

Journal Article · Wed Jan 26 23:00:00 EST 2011 · Journal of Solid State Chemistry · OSTI ID:1335968

Related Subjects

71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS

Synthesis, characterization and thermodynamic study of carbon dioxide adsorption on akaganéite

Citation Formats

References (45)

Cited By (1)

Similar Records

Related Subjects