Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph

Roque-Malherbe, R.; Carballo, E.; Polanco, R.; Lugo, F.; Lozano, C.

doi:10.1016/j.jpcs.2015.04.009

Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph

Journal Article · Thu May 14 00:00:00 EDT 2015 · Journal of Physics and Chemistry of Solids

DOI:https://doi.org/10.1016/j.jpcs.2015.04.009· OSTI ID:1336313

Roque-Malherbe, R. ^[1]; Carballo, E. ^[2]; Polanco, R. ^[2]; Lugo, F. ^[2]; Lozano, C. ^[2]

University of Turabo, Gurabo (Puerto Rico); University of Puerto Rico-Mayaguez (United States); Universidad del Turabo
University of Turabo, Gurabo (Puerto Rico); University of Puerto Rico-Mayaguez (United States)

The key questions addressed here were: the structure elucidation and the investigation of the adsorption space and framework expansion effect of a Cu(II) hexacyanoferrate (III) polymorph (labeled Cu-PBA-I). The structural analysis was performed with a broad set of characterization methods. In addition, a low and high pressure carbon dioxide adsorption investigation was performed, assuming, to comprehend the adsorption experiments, that the adsorbent plus the adsorbed phase were a solid solution. The Cu-PBA-I presented the following composition, K_1/4 Cu (II) [Fe (III)(CN)₆]_3/4 ∙ _1/4 nH₂O, exhibited an antiferromagnetic behavior and displayed a thermally stable I4 2 m space group lattice in the degassed state. Furthermore, the low pressure adsorption study allowed the calculation of the micropore volume, W¼0.09 cm³ /g and the isosteric heat of adsorption, q_iso=19 kJ/mol; further, the high pressure adsorption data revealed an extremely high adsorption capacity owing to a framework expansion effect. Finally, the DRIFTS spectrum of adsorbed CO₂ displayed peaks corresponding to carbon dioxide physically adsorbed and interacting with electron accepting Lewis acid sites. Hence, was produced an excellent adsorbent which combine porosity and anti-ferromagnetism, antagonist properties rarely found together.

View Accepted Manuscript (DOE)

Research Organization:: University of Turabo, Gurabo (Puerto Rico)

Sponsoring Organization:: USDOE; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0000672

OSTI ID:: 1336313

Alternate ID(s):: OSTI ID: 1246689

Journal Information:: Journal of Physics and Chemistry of Solids, Journal Name: Journal of Physics and Chemistry of Solids Journal Issue: C Vol. 86; ISSN 0022-3697

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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