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Molecular Layer Deposition for Surface Modification of Lithium-Ion Battery Electrodes

Journal Article · · Advanced Materials Interfaces
 [1];  [2]
  1. National Renewable Energy Lab. (NREL), Golden, CO (United States). Center for Chemistry and Nanoscience
  2. Univ. of Colorado, Boulder, CO (United States). Dept. of Chemistry and Biochemistry and Dept. of Mechanical Engineering
This review presents the MLD process and its outstanding attributes for electrochemical applications and is inspired by recent successes in applying molecular layer deposition (MLD) to stabilize lithium-ion (Li-ion) electrodes. Furthermore, this review discusses various MLD materials and their implementation in Li-ion electrodes. The rationale behind these emerging uses of MLD is examined to motivate future efforts on the fundamental understanding of interphase chemistry and the development of new materials for enhanced electrochemical performance.
Research Organization:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1332484
Alternate ID(s):
OSTI ID: 1401248
Report Number(s):
NREL/JA--5900-66900
Journal Information:
Advanced Materials Interfaces, Journal Name: Advanced Materials Interfaces Journal Issue: 21 Vol. 3; ISSN 2196-7350
Publisher:
Wiley-VCHCopyright Statement
Country of Publication:
United States
Language:
English

References (74)

Growth and Properties of Hybrid Organic-Inorganic Metalcone Films Using Molecular Layer Deposition Techniques journal September 2012
Chemical Vapor Deposition of Conformal, Functional, and Responsive Polymer Films journal December 2009
Ultrathin Direct Atomic Layer Deposition on Composite Electrodes for Highly Durable and Safe Li-Ion Batteries journal April 2010
Emerging Applications of Atomic Layer Deposition for Lithium-Ion Battery Studies journal June 2012
Studying the Kinetics of Crystalline Silicon Nanoparticle Lithiation with In Situ Transmission Electron Microscopy journal September 2012
25th Anniversary Article: Understanding the Lithiation of Silicon and Other Alloying Anodes for Lithium-Ion Batteries journal August 2013
Reversible High-Capacity Si Nanocomposite Anodes for Lithium-ion Batteries Enabled by Molecular Layer Deposition journal December 2013
Improved Functionality of Lithium-Ion Batteries Enabled by Atomic Layer Deposition on the Porous Microstructure of Polymer Separators and Coating Electrodes journal April 2012
Unexpected Improved Performance of ALD Coated LiCoO 2 /Graphite Li-Ion Batteries journal September 2012
Conformal Coatings of Cyclized-PAN for Mechanically Resilient Si nano-Composite Anodes journal March 2013
Influence of Silicon Nanoscale Building Blocks Size and Carbon Coating on the Performance of Micro-Sized Si-C Composite Li-Ion Anodes journal July 2013
Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review journal October 2013
Molecular Layer Deposition of Hybrid Organic-Inorganic Polymer Films using Diethylzinc and Ethylene Glycol journal June 2009
Molecular Layer Deposition of Zircone and ZrO 2 /Zircone Alloy Films: Growth and Properties journal May 2013
Surface Modification of Silicon Anodes for Durable and HighEnergy Lithium-Ion Batteries journal March 2015
Molecular Layer Deposition (MLD): Monomolecular-Step Growth of Polymers with Designated Sequences journal March 2016
On the significance of the H/E ratio in wear control: a nanocomposite coating approach to optimised tribological behaviour journal November 2000
Structural studies of the new carbon-coated silicon anode materials using synchrotron-based in situ XRD journal November 2002
Thermomechanical properties of aluminum alkoxide (alucone) films created using molecular layer deposition journal October 2009
Ultrathin atomic layer deposited ZrO2 coating to enhance the electrochemical performance of Li4Ti5O12 as an anode material journal March 2013
Enhanced electrochemical performance of LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode material by ultrathin ZrO 2 coating journal February 2016
Challenges for rechargeable batteries journal August 2011
Effects of graphene and carbon coating modifications on electrochemical performance of silicon nanoparticle/graphene composite anode journal January 2014
Scaling, dimensional analysis, and indentation measurements journal August 2004
Atomic layer deposition of epitaxial ZrO2 coating on LiMn2O4 nanoparticles for high-rate lithium ion batteries at elevated temperature journal September 2013
Cross-linked aluminum dioxybenzene coating for stabilization of silicon electrodes journal April 2016
The mechanical properties of atomic layer deposited alumina for use in micro- and nano-electromechanical systems journal August 2006
Thermo-mechanical properties of alumina films created using the atomic layer deposition technique journal November 2010
Safe and Durable High-Temperature Lithium–Sulfur Batteries via Molecular Layer Deposited Coating journal May 2016
Structure and Reactivity of Alucone-Coated Films on Si and Li x Si y Surfaces journal May 2015
Surface-Coating Regulated Lithiation Kinetics and Degradation in Silicon Nanowires for Lithium Ion Battery journal April 2015
Alucone Interlayers to Minimize Stress Caused by Thermal Expansion Mismatch between Al 2 O 3 Films and Teflon Substrates journal January 2013
Growth and Properties of Hafnicone and HfO 2 /Hafnicone Nanolaminate and Alloy Films Using Molecular Layer Deposition Techniques journal September 2014
A Systematic Investigation of Polymer Binder Flexibility on the Electrode Performance of Lithium-Ion Batteries journal September 2014
Surface Chemistry for Molecular Layer Deposition of Organic and Hybrid Organic−Inorganic Polymers journal April 2009
Deposition of Ultrathin Polythiourea Films by Molecular Layer Deposition journal October 2010
Molecular Layer Deposition of Titanicone Films using TiCl 4 and Ethylene Glycol or Glycerol: Growth and Properties journal July 2012
Molecular Layer Deposition of Alucone Polymer Films Using Trimethylaluminum and Ethylene Glycol journal May 2008
Molecular Layer Deposition of Hybrid Organic−Inorganic Alucone Polymer Films Using a Three-Step ABC Reaction Sequence journal November 2009
Electrolytes and Interphases in Li-Ion Batteries and Beyond journal October 2014
Atomic Layer Deposition: An Overview journal January 2010
Molecular Layer Deposition of Nylon 66 Films Examined Using in Situ FTIR Spectroscopy journal June 2007
Conformal Organic−Inorganic Hybrid Network Polymer Thin Films by Molecular Layer Deposition using Trimethylaluminum and Glycidol journal May 2011
Alucone Alloys with Tunable Properties Using Alucone Molecular Layer Deposition and Al 2 O 3 Atomic Layer Deposition journal February 2012
Highly Stable Ultrathin Carbosiloxane Films by Molecular Layer Deposition journal September 2013
Importance of Trimethylaluminum Diffusion in Three-Step ABC Molecular Layer Deposition Using Trimethylaluminum, Ethanolamine, and Maleic Anhydride journal December 2010
Molecular Layer Deposition of Aluminum Alkoxide Polymer Films Using Trimethylaluminum and Glycidol journal December 2011
Molecular Layer Deposition of Poly( p -phenylene terephthalamide) Films Using Terephthaloyl Chloride and p -Phenylenediamine journal March 2008
In Situ TEM Investigation of Congruent Phase Transition and Structural Evolution of Nanostructured Silicon/Carbon Anode for Lithium Ion Batteries journal February 2012
Size-Dependent Fracture of Silicon Nanoparticles During Lithiation journal January 2012
Lithium Ion Battery Peformance of Silicon Nanowires with Carbon Skin journal December 2013
In Situ Transmission Electron Microscopy Probing of Native Oxide and Artificial Layers on Silicon Nanoparticles for Lithium Ion Batteries journal October 2014
High-performance lithium battery anodes using silicon nanowires journal December 2007
Superior stable sulfur cathodes of Li–S batteries enabled by molecular layer deposition journal January 2014
Ultra-thin microporous–mesoporous metal oxide films prepared by molecular layer deposition (MLD) journal January 2009
Polymer films formed with monolayer growth steps by molecular layer deposition journal July 1991
Quantum wire and dot formation by chemical vapor deposition and molecular layer deposition of one‐dimensional conjugated polymer journal January 1992
Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process journal June 2005
Crystallinity of inorganic films grown by atomic layer deposition: Overview and general trends journal January 2013
Critical tensile strain and water vapor transmission rate for nanolaminate films grown using Al 2 O 3 atomic layer deposition and alucone molecular layer deposition journal December 2012
Molecular layer deposition of polyethylene terephthalate thin films
  • Ivanova, Tatyana V.; Maydannik, Philipp S.; Cameron, David C.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 30, Issue 1 https://doi.org/10.1116/1.3662846
journal January 2012
Fabrication of organic interfacial layers by molecular layer deposition: Present status and future opportunities journal July 2013
Molecular layer deposition of alucone films using trimethylaluminum and hydroquinone
  • Choudhury, Devika; Sarkar, Shaibal K.; Mahuli, Neha
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 33, Issue 1 https://doi.org/10.1116/1.4900934
journal January 2015
Electrical Energy Storage and Intercalation Chemistry journal June 1976
Si/TiN Nanocomposites Novel Anode Materials for Li-Ion Batteries journal January 1999
Highly Reversible Lithium Storage in Nanostructured Silicon journal January 2003
Structural Changes in Silicon Anodes during Lithium Insertion/Extraction journal January 2004
Solid Lithium-Silicon Electrode journal January 1976
Nanoindentation Investigation of HfO[sub 2] and Al[sub 2]O[sub 3] Films Grown by Atomic Layer Deposition journal January 2008
Enhanced Stability of LiCoO2 Cathodes in Lithium-Ion Batteries Using Surface Modification by Atomic Layer Deposition journal January 2010
Liquid-Phase Molecular Layer Deposition: Potential Applications to Multi-Dye Sensitization and Cancer Therapy journal January 2011
Effects of Atomic Layer Deposition of Al2O3 on the Li[Li0.20Mn0.54Ni0.13Co0.13]O2 Cathode for Lithium-Ion Batteries journal January 2011
Metalcones: Hybrid Organic–Inorganic Films Fabricated Using Atomic and Molecular Layer Deposition Techniques journal September 2011
Organic and inorganic–organic thin film structures by molecular layer deposition: A review journal January 2014

Cited By (7)

Structurally Stable Manganese Alkoxide Films Grown by Hybrid Molecular Layer Deposition for Electrochemical Applications journal August 2019
The Influence of Ultrathin Amorphous ALD Alumina and Titania on the Rate Capability of Anatase TiO 2 and LiMn 2 O 4 Lithium Ion Battery Electrodes journal March 2017
Interfacially Induced Cascading Failure in Graphite‐Silicon Composite Anodes journal December 2018
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms journal May 2018
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms journal June 2018
An overview of molecular layer deposition for organic and organic–inorganic hybrid materials: mechanisms, growth characteristics, and promising applications journal January 2017
Atomic/molecular layer deposition of Cu–organic thin films journal January 2018

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