Safe and Durable High-Temperature Lithium–Sulfur Batteries via Molecular Layer Deposited Coating

Li, Xia; Lushington, Andrew; Sun, Qian; Xiao, Wei; Liu, Jian; Wang, Biqiong; Ye, Yifan; Nie, Kaiqi; Hu, Yongfeng; Xiao, Qunfeng; Li, Ruying; Guo, Jinghua; Sham, Tsun -Kong; Sun, Xueliang

doi:10.1021/acs.nanolett.6b00577

Safe and Durable High-Temperature Lithium–Sulfur Batteries via Molecular Layer Deposited Coating

Journal Article · Fri May 13 00:00:00 EDT 2016 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.6b00577· OSTI ID:1415959

Li, Xia ^[1]; Lushington, Andrew ^[1]; Sun, Qian ^[1]; Xiao, Wei ^[1]; Liu, Jian ^[2]; Wang, Biqiong ^[1]; Ye, Yifan ^[3]; Nie, Kaiqi ^[3]; Hu, Yongfeng ^[4]; Xiao, Qunfeng ^[4]; Li, Ruying ^[1]; Guo, Jinghua ^[3]; Sham, Tsun -Kong ^[1]; Sun, Xueliang ^[1]

Univ. of Western Ontario, London, ON (Canada)
Univ. of Western Ontario, London, ON (Canada); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Canadian Light Source, Saskatoon, SK (Canada)

Here, Lithium-sulfur (Li-S) battery is a promising high energy storage candidate in electric vehicles. However, the commonly employed ether based electrolyte does not enable to realize safe high-temperature Li-S batteries due to the low boiling and flash temperatures. Traditional carbonate based electrolyte obtains safe physical properties at high temperature but does not complete reversible electrochemical reaction for most Li-S batteries. Here we realize safe high temperature Li-S batteries on universal carbon-sulfur electrodes by molecular layer deposited (MLD) alucone coating. Sulfur cathodes with MLD coating complete the reversible electrochemical process in carbonate electrolyte and exhibit a safe and ultrastable cycle life at high temperature, which promise practicable Li-S batteries for electric vehicles and other large-scale energy storage systems.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1415959

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 6 Vol. 16; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (42)

Tin Oxide with Controlled Morphology and Crystallinity by Atomic Layer Deposition onto Graphene Nanosheets for Enhanced Lithium Storage Li, Xifei; Meng, Xiangbo; Liu, Jian Advanced Functional Materials, Vol. 22, Issue 8 https://doi.org/10.1002/adfm.201101068	journal	February 2012
Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries Elazari, Ran; Salitra, Gregory; Garsuch, Arnd Advanced Materials, Vol. 23, Issue 47, p. 5641-5644 https://doi.org/10.1002/adma.201103274	journal	November 2011
Emerging Applications of Atomic Layer Deposition for Lithium-Ion Battery Studies Meng, Xiangbo; Yang, Xiao-Qing; Sun, Xueliang Advanced Materials, Vol. 24, Issue 27 https://doi.org/10.1002/adma.201200397	journal	June 2012
Liquid-Type Cathode Enabled by 3D Sponge-Like Carbon Nanotubes for High Energy Density and Long Cycling Life of Li-S Batteries Pu, Xiong; Yang, Gang; Yu, Choongho Advanced Materials, Vol. 26, Issue 44 https://doi.org/10.1002/adma.201403337	journal	October 2014
Plasma-Enhanced Atomic Layer Deposition of Ultrathin Oxide Coatings for Stabilized Lithium-Sulfur Batteries Kim, Hyea; Lee, Jung Tae; Lee, Dong-Chan Advanced Energy Materials, Vol. 3, Issue 10 https://doi.org/10.1002/aenm.201300253	journal	June 2013
Radical or Not Radical: Revisiting Lithium-Sulfur Electrochemistry in Nonaqueous Electrolytes Cuisinier, Marine; Hart, Connor; Balasubramanian, Mahalingam Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201401801	journal	January 2015
Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries Lin, Zhan; Liu, Zengcai; Fu, Wujun Angewandte Chemie International Edition, Vol. 52, Issue 29 https://doi.org/10.1002/anie.201300680	journal	June 2013
X-ray Absorption Near-Edge Structure and Nuclear Magnetic Resonance Study of the Lithium-Sulfur Battery and its Components Patel, Manu U. M.; Arčon, Iztok; Aquilanti, Giuliana ChemPhysChem, Vol. 15, Issue 5 https://doi.org/10.1002/cphc.201300972	journal	February 2014
Using X-ray absorption to probe sulfur oxidation states in complex molecules Vairavamurthy, A. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 54, Issue 12 https://doi.org/10.1016/S1386-1425(98)00153-X	journal	October 1998
Sulfur–carbon composite electrode for all-solid-state Li/S battery with Li₂S–P₂S₅ solid electrolyte Nagao, Motohiro; Hayashi, Akitoshi; Tatsumisago, Masahiro Electrochimica Acta, Vol. 56, Issue 17, p. 6055-6059 https://doi.org/10.1016/j.electacta.2011.04.084	journal	July 2011
Role of LiNO3 in rechargeable lithium/sulfur battery Zhang, Sheng S. Electrochimica Acta, Vol. 70 https://doi.org/10.1016/j.electacta.2012.03.081	journal	May 2012
Electrochemical properties of ether-based electrolytes for lithium/sulfur rechargeable batteries Barchasz, Céline; Leprêtre, Jean-Claude; Patoux, Sébastien Electrochimica Acta, Vol. 89 https://doi.org/10.1016/j.electacta.2012.11.001	journal	February 2013
Effect of chemical reactivity of polysulfide toward carbonate-based electrolyte on the electrochemical performance of Li–S batteries Yim, Taeeun; Park, Min-Sik; Yu, Ji-Sang Electrochimica Acta, Vol. 107 https://doi.org/10.1016/j.electacta.2013.06.039	journal	September 2013
All-solid-state Li–sulfur batteries with mesoporous electrode and thio-LISICON solid electrolyte Nagao, Miki; Imade, Yuki; Narisawa, Haruto Journal of Power Sources, Vol. 222 https://doi.org/10.1016/j.jpowsour.2012.08.041	journal	January 2013
High temperature stabilization of lithium–sulfur cells with carbon nanotube current collector Kim, Hyea; Lee, Jung Tae; Yushin, Gleb Journal of Power Sources, Vol. 226 https://doi.org/10.1016/j.jpowsour.2012.10.028	journal	March 2013
A review on the key issues for lithium-ion battery management in electric vehicles Lu, Languang; Han, Xuebing; Li, Jianqiu Journal of Power Sources, Vol. 226, p. 272-288 https://doi.org/10.1016/j.jpowsour.2012.10.060	journal	March 2013
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions Zhang, Sheng S. Journal of Power Sources, Vol. 231, p. 153-162 https://doi.org/10.1016/j.jpowsour.2012.12.102	journal	June 2013
A review on lithium-ion battery ageing mechanisms and estimations for automotive applications Barré, Anthony; Deguilhem, Benjamin; Grolleau, Sébastien Journal of Power Sources, Vol. 241 https://doi.org/10.1016/j.jpowsour.2013.05.040	journal	November 2013
Systematical electrochemical study on the parasitic shuttle-effect in lithium-sulfur-cells at different temperatures and different rates Busche, Martin Rolf; Adelhelm, Philipp; Sommer, Heino Journal of Power Sources, Vol. 259 https://doi.org/10.1016/j.jpowsour.2014.02.075	journal	August 2014
Entrapment of sulfur in hierarchical porous graphene for lithium–sulfur batteries with high rate performance from −40 to 60°C Huang, Jia-Qi; Liu, Xiao-Fei; Zhang, Qiang Nano Energy, Vol. 2, Issue 2 https://doi.org/10.1016/j.nanoen.2012.10.003	journal	March 2013
Reactivation of dissolved polysulfides in Li–S batteries based on atomic layer deposition of Al2O3 in nanoporous carbon cloth Han, Xiaogang; Xu, Yunhua; Chen, Xinyi Nano Energy, Vol. 2, Issue 6 https://doi.org/10.1016/j.nanoen.2013.05.003	journal	November 2013
High-performance lithium/sulfur cells with a bi-functionally immobilized sulfur cathode Lin, Zhan; Nan, Caiyun; Ye, Yifan Nano Energy, Vol. 9 https://doi.org/10.1016/j.nanoen.2014.08.003	journal	October 2014
Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium–Sulfur Batteries Gordin, Mikhail L.; Dai, Fang; Chen, Shuru ACS Applied Materials & Interfaces, Vol. 6, Issue 11 https://doi.org/10.1021/am501665s	journal	May 2014
New Approaches for High Energy Density Lithium–Sulfur Battery Cathodes Evers, Scott; Nazar, Linda F. Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar3001348	journal	June 2012
Molecular Layer Deposition of Alucone Polymer Films Using Trimethylaluminum and Ethylene Glycol Dameron, A. A.; Seghete, D.; Burton, B. B. Chemistry of Materials, Vol. 20, Issue 10 https://doi.org/10.1021/cm7032977	journal	May 2008
Smaller Sulfur Molecules Promise Better Lithium–Sulfur Batteries Xin, Sen; Gu, Lin; Zhao, Na-Hong Journal of the American Chemical Society, Vol. 134, Issue 45 https://doi.org/10.1021/ja308170k	journal	October 2012
Alucone Alloys with Tunable Properties Using Alucone Molecular Layer Deposition and Al ₂ O ₃ Atomic Layer Deposition Lee, Byoung H.; Yoon, Byunghoon; Anderson, Virginia R. The Journal of Physical Chemistry C, Vol. 116, Issue 5 https://doi.org/10.1021/jp209003h	journal	February 2012
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz401763d	journal	September 2013
Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability Wang, Hailiang; Yang, Yuan; Liang, Yongye Nano Letters, Vol. 11, Issue 7, p. 2644-2647 https://doi.org/10.1021/nl200658a	journal	July 2011
Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries Zheng, Guangyuan; Yang, Yuan; Cha, Judy J. Nano Letters, Vol. 11, Issue 10, p. 4462-4467 https://doi.org/10.1021/nl2027684	journal	October 2011
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
Sulfur: not a “silent” element any more Jalilehvand, Farideh Chem. Soc. Rev., Vol. 35, Issue 12 https://doi.org/10.1039/B417595F	journal	January 2006
Multi-electron reaction materials for high energy density batteries Gao, Xue-Ping; Yang, Han-Xi Energy Environ. Sci., Vol. 3, Issue 2 https://doi.org/10.1039/B916098A	journal	January 2010
Superior stable sulfur cathodes of Li–S batteries enabled by molecular layer deposition Li, Xia; Lushington, Andrew; Liu, Jian Chemical Communications, Vol. 50, Issue 68 https://doi.org/10.1039/C4CC04097J	journal	January 2014
Understanding the degradation mechanism of rechargeable lithium/sulfur cells: a comprehensive study of the sulfur–graphene oxide cathode after discharge–charge cycling Feng, Xuefei; Song, Min-Kyu; Stolte, Wayne C. Phys. Chem. Chem. Phys., Vol. 16, Issue 32 https://doi.org/10.1039/C4CP01341G	journal	January 2014
Lithium–sulfur batteries: from liquid to solid cells Lin, Zhan; Liang, Chengdu Journal of Materials Chemistry A, Vol. 3, Issue 3 https://doi.org/10.1039/C4TA04727C	journal	January 2015
Solid state lithiation–delithiation of sulphur in sub-nano confinement: a new concept for designing lithium–sulphur batteries Fu, Chengyin; Wong, Bryan M.; Bozhilov, Krassimir N. Chemical Science, Vol. 7, Issue 2 https://doi.org/10.1039/C5SC03419A	journal	January 2016
Enhancement of long stability of sulfur cathode by encapsulating sulfur into micropores of carbon spheres Zhang, B.; Qin, X.; Li, G. R. Energy & Environmental Science, Vol. 3, Issue 10 https://doi.org/10.1039/c002639e	journal	January 2010
Molecular structure and stability of dissolved lithium polysulfide species Vijayakumar, M.; Govind, Niranjan; Walter, Eric Phys. Chem. Chem. Phys., Vol. 16, Issue 22 https://doi.org/10.1039/c4cp00889h	journal	January 2014
Elegant design of electrode and electrode/electrolyte interface in lithium-ion batteries by atomic layer deposition Liu, Jian; Sun, Xueliang Nanotechnology, Vol. 26, Issue 2 https://doi.org/10.1088/0957-4484/26/2/024001	journal	December 2014
Fabrication of organic interfacial layers by molecular layer deposition: Present status and future opportunities Zhou, Han; Bent, Stacey F. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 31, Issue 4 https://doi.org/10.1116/1.4804609	journal	July 2013
On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries Aurbach, Doron; Pollak, Elad; Elazari, Ran Journal of The Electrochemical Society, Vol. 156, Issue 8, p. A694-A702 https://doi.org/10.1149/1.3148721	journal	January 2009

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Foldable interpenetrated metal-organic frameworks/carbon nanotubes thin film for lithium–sulfur batteries Mao, Yiyin; Li, Gaoran; Guo, Yi Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14628	journal	March 2017
A high-energy sulfur cathode in carbonate electrolyte by eliminating polysulfides via solid-phase lithium-sulfur transformation Li, Xia; Banis, Mohammad; Lushington, Andrew Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06877-9	journal	October 2018
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Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms Sun, Qian; Lau, Kah Chun; Geng, Dongsheng Batteries & Supercaps, Vol. 1, Issue 2 https://doi.org/10.1002/batt.201800024	journal	May 2018
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Honeycomb-like Nitrogen and Sulfur Dual-Doped Hierarchical Porous Biomass-Derived Carbon for Lithium-Sulfur Batteries Chen, Manfang; Jiang, Shouxin; Huang, Cheng ChemSusChem, Vol. 10, Issue 8 https://doi.org/10.1002/cssc.201700050	journal	March 2017
A Li ₂ S-Based Sacrificial Layer for Stable Operation of Lithium-Sulfur Batteries Ren, Y. X.; Zhao, T. S.; Liu, M. Energy Technology, Vol. 6, Issue 11 https://doi.org/10.1002/ente.201800372	journal	October 2018
Nb ₂ O ₅ /RGO Nanocomposite Modified Separators with Robust Polysulfide Traps and Catalytic Centers for Boosting Performance of Lithium–Sulfur Batteries Guo, Pengqian; Sun, Kai; Shang, Xiaonan Small, Vol. 15, Issue 40 https://doi.org/10.1002/smll.201902363	journal	August 2019
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Lithium−sulfur batteries
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ether based electrolyte
high temperature
molecular layer deposition

Safe and Durable High-Temperature Lithium–Sulfur Batteries via Molecular Layer Deposited Coating

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