Autooxidation of Np(IV) in nitric acid solutions
Journal Article
·
· Radiochemistry
OSTI ID:133089
Autooxidation of Np(IV) in 4 and 6 M HNO{sub 3}, induced by self-{alpha}-radiation, has been experimentally studies and simulated. Neptunium (IV) is oxidized mainly via reaction with Np(VI). Rate constants for the reactions Np(IV) + Np(VI) and Np(V) + Np(V) were determined by comparing experimental and calculated current and equilibrium concentrations of Np(IV) and Np(V).
- OSTI ID:
- 133089
- Journal Information:
- Radiochemistry, Journal Name: Radiochemistry Journal Issue: 1 Vol. 37; ISSN RDIOEO; ISSN 1066-3622
- Country of Publication:
- United States
- Language:
- English
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