Realization of highly efficient hexagonal boron nitride neutron detectors

Maity, A.; Doan, T. C.; Li, J.; Lin, J. Y.; Jiang, H. X.

doi:10.1063/1.4960522

Realization of highly efficient hexagonal boron nitride neutron detectors

Journal Article · Tue Aug 16 00:00:00 EDT 2016 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4960522· OSTI ID:1330680

Maity, A. ^[1]; Doan, T. C. ^[2]; ^[2]; ^[2]; ^[2]

Texas Tech Univ., Lubbock, TX (United States); Texas Tech University
Texas Tech Univ., Lubbock, TX (United States)

Here, we report the achievement of highly efficient ¹⁰B enriched hexagonal boron nitride (h- ¹⁰BN) direct conversion neutron detectors. These detectors were realized from freestanding 4-in. diameter h- ¹⁰BN wafers 43 μm in thickness obtained from epitaxy growth and subsequent mechanical separation from sapphire substrates. Both sides of the film were subjected to ohmic contact deposition to form a simple vertical “photoconductor-type” detector. Transport measurements revealed excellent vertical transport properties including high electrical resistivity (>10¹³ Ω cm) and mobility-lifetime (μτ) products. A much larger μτ product for holes compared to that of electrons along the c-axis of h- BN was observed, implying that holes (electrons) behave like majority (minority) carriers in undoped h- BN. Exposure to thermal neutrons from a californium-252 (²⁵²Cf) source moderated by a high density polyethylene moderator reveals that 43 μm h- ¹⁰BN detectors possess 51.4% detection efficiency at a bias voltage of 400 V, which is the highest reported efficiency for any semiconductor-based neutron detector. The results point to the possibility of obtaining highly efficient, compact solid-state neutron detectors with high gamma rejection and low manufacturing and maintenance costs.

View Accepted Manuscript (DOE)

Research Organization:: Texas Tech Univ., Lubbock, TX (United States)

Sponsoring Organization:: Department of Homeland Security (DHS); National Science Foundation (NSF); USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: NA0002927

OSTI ID:: 1330680

Alternate ID(s):: OSTI ID: 1295951

Journal Information:: Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 7 Vol. 109; ISSN APPLAB; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (24)

Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure. Kubota, Yoichi; Watanabe, Kenji; Tsuda, Osamu ChemInform, Vol. 38, Issue 45 https://doi.org/10.1002/chin.200745012	journal	November 2007
High-field effects in photoconducting cadmium sulphide Many, A. Journal of Physics and Chemistry of Solids, Vol. 26, Issue 3 https://doi.org/10.1016/0022-3697(65)90133-2	journal	March 1965
Thermal neutron detection with pyrolytic boron nitride McGregor, D. S.; Unruh, T. C.; McNeil, W. J. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 591, Issue 3 https://doi.org/10.1016/j.nima.2008.03.002	journal	July 2008
Hexagonal boron nitride epitaxial layers as neutron detector materials Li, J.; Dahal, R.; Majety, S. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 654, Issue 1 https://doi.org/10.1016/j.nima.2011.07.040	journal	October 2011
Fabrication and characterization of solid-state thermal neutron detectors based on hexagonal boron nitride epilayers Doan, T. C.; Majety, S.; Grenadier, S. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 748 https://doi.org/10.1016/j.nima.2014.02.031	journal	June 2014
Scalable large-area solid-state neutron detector with continuous p–n junction and extremely low leakage current Huang, Kuan-Chih; Dahal, Rajendra; Lu, James J.-Q. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 763, p. 260-265 https://doi.org/10.1016/j.nima.2014.06.047	journal	November 2014
Hexagonal boron nitride thin film thermal neutron detectors with high energy resolution of the reaction products Doan, T. C.; Majety, S.; Grenadier, S. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 783 https://doi.org/10.1016/j.nima.2015.02.045	journal	May 2015
Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal Watanabe, Kenji; Taniguchi, Takashi; Kanda, Hisao Nature Materials, Vol. 3, Issue 6 https://doi.org/10.1038/nmat1134	journal	May 2004
Far-ultraviolet plane-emission handheld device based on hexagonal boron nitride Watanabe, Kenji; Taniguchi, Takashi; Niiyama, Takahiro Nature Photonics, Vol. 3, Issue 10 https://doi.org/10.1038/nphoton.2009.167	journal	September 2009
Epitaxially grown semiconducting hexagonal boron nitride as a deep ultraviolet photonic material Dahal, R.; Li, J.; Majety, S. Applied Physics Letters, Vol. 98, Issue 21 https://doi.org/10.1063/1.3593958	journal	May 2011
Epitaxial growth and demonstration of hexagonal BN/AlGaN p-n junctions for deep ultraviolet photonics Majety, S.; Li, J.; Cao, X. K. Applied Physics Letters, Vol. 100, Issue 6 https://doi.org/10.1063/1.3682523	journal	February 2012
Self-powered micro-structured solid state neutron detector with very low leakage current and high efficiency Dahal, R.; Huang, K. C.; Clinton, J. Applied Physics Letters, Vol. 100, Issue 24, 243507 https://doi.org/10.1063/1.4729558	journal	June 2012
Dielectric strength, optical absorption, and deep ultraviolet detectors of hexagonal boron nitride epilayers Li, J.; Majety, S.; Dahal, R. Applied Physics Letters, Vol. 101, Issue 17 https://doi.org/10.1063/1.4764533	journal	October 2012
High aspect ratio composite structures with 48.5% thermal neutron detection efficiency Shao, Q.; Voss, L. F.; Conway, A. M. Applied Physics Letters, Vol. 102, Issue 6 https://doi.org/10.1063/1.4792703	journal	February 2013
Two-dimensional excitons in three-dimensional hexagonal boron nitride Cao, X. K.; Clubine, B.; Edgar, J. H. Applied Physics Letters, Vol. 103, Issue 19 https://doi.org/10.1063/1.4829026	journal	November 2013
Charge carrier transport properties in layer structured hexagonal boron nitride Doan, T. C.; Li, J.; Lin, J. Y. AIP Advances, Vol. 4, Issue 10 https://doi.org/10.1063/1.4898630	journal	October 2014
The origins of near band-edge transitions in hexagonal boron nitride epilayers Du, X. Z.; Li, J.; Lin, J. Y. Applied Physics Letters, Vol. 108, Issue 5 https://doi.org/10.1063/1.4941540	journal	February 2016
The physics of solid-state neutron detector materials and geometries Caruso, A. N. Journal of Physics: Condensed Matter, Vol. 22, Issue 44 https://doi.org/10.1088/0953-8984/22/44/443201	journal	October 2010
Jahn-Teller effect on exciton states in hexagonal boron nitride single crystal Watanabe, Kenji; Taniguchi, Takashi Physical Review B, Vol. 79, Issue 19 https://doi.org/10.1103/PhysRevB.79.193104	journal	May 2009
Condensed-Matter Simulation of a Three-Dimensional Anomaly Semenoff, Gordon W. Physical Review Letters, Vol. 53, Issue 26 https://doi.org/10.1103/PhysRevLett.53.2449	journal	December 1984
A Handheld Neutron-Detection Sensor System Utilizing a New Class of Boron Carbide Diode Osberg, Kevin; Schemm, Nathan; Balkir, Sina IEEE Sensors Journal, Vol. 6, Issue 6 https://doi.org/10.1109/JSEN.2006.883905	journal	January 2006
Improved High Efficiency Stacked Microstructured Neutron Detectors Backfilled With Nanoparticle $^{6}$LiF Bellinger, S. L.; Fronk, R. G.; McNeil, W. J. IEEE Transactions on Nuclear Science, Vol. 59, Issue 1 https://doi.org/10.1109/TNS.2011.2175749	journal	February 2012
Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure Kubota, Y.; Watanabe, K.; Tsuda, O. Science, Vol. 317, Issue 5840 https://doi.org/10.1126/science.1144216	journal	August 2007
Characterization and Field Emission of Sulfur-Doped Boron Nitride Synthesized by Plasma-Assisted Chemical Vapor Deposition Sugino, Takashi; Tanioka, Kazuhiko; Kawasaki, Seiji Japanese Journal of Applied Physics, Vol. 36, Issue Part 2, No. 4B https://doi.org/10.1143/JJAP.36.L463	journal	April 1997

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Anisotropic index of refraction and structural properties of hexagonal boron nitride epilayers probed by spectroscopic ellipsometry McKay, M. A.; Li, J.; Lin, J. Y. Journal of Applied Physics, Vol. 127, Issue 5 https://doi.org/10.1063/1.5134908	journal	February 2020
Natural optical anisotropy of h-BN: Highest giant birefringence in a bulk crystal through the mid-infrared to ultraviolet range Segura, A.; Artús, L.; Cuscó, R. Physical Review Materials, Vol. 2, Issue 2 https://doi.org/10.1103/physrevmaterials.2.024001	journal	February 2018
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