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A self-forming composite electrolyte for solid-state sodium battery with ultra-long cycle life

Journal Article · · Advanced Energy Materials (Online)
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  1. Univ. of Chinese Academy of Sciences, Beijing (China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Chinese Academy of Sciences (CAS), Beijing (China)
+ Show Author Affiliations
Replacing organic liquid electrolyte with inorganic solid electrolytes (SE) can potentially address the inherent safety problems in conventional rechargeable batteries. Furthermore, all-solid-state batteries have been plagues by the relatively low ionic conductivity of solid electrolytes and large charge-transfer resistance resulted from solid-solid interfaces between electrode materials and solid electrolytes. Here we report a new design strategy for improving the ionic conductivity of solid electrolyte by self-forming a composite material. An optimized Na+ ion conducting composite electrolyte derived from the NASICON structure was successfully synthesized, yielding ultra-high ionic conductivity of 3.4 mS cm–1 at 25°C and 14 ms cm–1 at 80°C.
Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source
Sponsoring Organization:
National Key Technologies R&D Program; National Natural Science Foundation of China; USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0012704
OSTI ID:
1326759
Alternate ID(s):
OSTI ID: 1768778
Report Number(s):
BNL--112661-2016-JA; BNL--221105-2021-JAAM; VT1201000
Journal Information:
Advanced Energy Materials (Online), Journal Name: Advanced Energy Materials (Online); ISSN 1614-6840
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

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Building Better Batteries in the Solid State: A Review journal November 2019
Electrode Engineering by Atomic Layer Deposition for Sodium‐Ion Batteries: From Traditional to Advanced Batteries journal December 2019
Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application journal March 2019
Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries journal February 2018
Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries journal January 2018
Solid-State Sodium Batteries journal February 2018
Quantification of Heterogeneous Degradation in Li‐Ion Batteries journal May 2019
Incorporating Solvate and Solid Electrolytes for All‐Solid‐State Li 2 S Batteries with High Capacity and Long Cycle Life journal May 2019
A High‐Performance Monolithic Solid‐State Sodium Battery with Ca 2+ Doped Na 3 Zr 2 Si 2 PO 12 Electrolyte journal June 2019
Correlated Migration Invokes Higher Na + ‐Ion Conductivity in NaSICON‐Type Solid Electrolytes journal October 2019
Toward High Energy Density All Solid‐State Sodium Batteries with Excellent Flexibility journal March 2020
A Flexible Solid Electrolyte with Multilayer Structure for Sodium Metal Batteries journal January 2020
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All-Solid-State Sodium Batteries journal February 2018
Enabling a Durable Electrochemical Interface via an Artificial Amorphous Cathode Electrolyte Interphase for Hybrid Solid/Liquid Lithium‐Metal Batteries journal February 2020
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All-Solid-State Sodium Batteries journal February 2018
Enabling a Durable Electrochemical Interface via an Artificial Amorphous Cathode Electrolyte Interphase for Hybrid Solid/Liquid Lithium‐Metal Batteries journal February 2020
Recent Research on Strategies to Improve Ion Conduction in Alkali Metal‐Ion Batteries journal April 2019
First Principle Material Genome Approach for All Solid‐State Batteries journal September 2019
Ionic Liquids and their Polymers in Lithium‐Sulfur Batteries journal January 2019
Electrolytes, SEI Formation, and Binders: A Review of Nonelectrode Factors for Sodium-Ion Battery Anodes journal January 2018
Progress in the Development of Sodium-Ion Solid Electrolytes journal September 2017
Designing solid-state electrolytes for safe, energy-dense batteries journal February 2020
Ionic liquids and derived materials for lithium and sodium batteries journal January 2018
Na 11 Sn 2 PS 12 : a new solid state sodium superionic conductor journal January 2018
Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries journal January 2018
Synergic antimony–niobium pentoxide nanomeshes for high-rate sodium storage journal January 2018
Revealing the chemistry of an anode-passivating electrolyte salt for high rate and stable sodium metal batteries journal January 2018
Theoretical formulation of Na 3 AO 4 X (A = S/Se, X = F/Cl) as high-performance solid electrolytes for all-solid-state sodium batteries journal January 2019
A materials perspective on magnesium-ion-based solid-state electrolytes journal January 2020

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Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
National Synchrotron Light Source
ionic liquid
self-forming
solid electrolyte
solid-state batteries
surface modification