A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries

Liu, Fang -Chao; Shadike, Zulipiya; Wang, Xiao -Fang; Shi, Si -Qi; Zhou, Yong -Ning; Chen, Guo -Ying; Yang, Xiao -Qing; Weng, Lin -Hong; Zhao, Jing -Tai; Fu, Zheng -Wen

doi:10.1021/acs.inorgchem.6b00564

Title: A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries

Journal Article · Thu Jun 16 00:00:00 EDT 2016 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.6b00564· OSTI ID:1326753

Liu, Fang -Chao ^[1]; Shadike, Zulipiya ^[1]; Wang, Xiao -Fang ^[2]; Shi, Si -Qi ^[2]; Zhou, Yong -Ning ^[3]; Chen, Guo -Ying ^[1]; Yang, Xiao -Qing ^[4]; Weng, Lin -Hong ^[1]; Zhao, Jing -Tai ^[2]; Fu, Zheng -Wen ^[1]

Fudan Univ., Shanghai (People's Republic of China)
Shanghai Univ., Shanghai (People's Republic of China)
Fudan Univ., Shanghai (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)

A novel small-molecule compound of lithium iodine and 3-hydroxypropionitrile (HPN) has been successfully synthesized. Our combined experimental and theoretical studies indicated that LiIHPN is a Li-ion conductor, which is utterly different from the I–-anion conductor of LiI(HPN)₂ reported previously. Solid-state lithium–air batteries based on LiIHPN as the electrolyte exhibit a reversible discharge capacity of more than 2100 mAh g^–1 with a cyclic performance over 10 cycles. Lastly, our findings provide a new way to design solid-state electrolytes toward high-performance lithium–air batteries.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: SC00112704

OSTI ID:: 1326753

Report Number(s):: BNL-112647-2016-JA; R&D Project: MA453MAEA; VT1201000

Journal Information:: Inorganic Chemistry, Vol. 55, Issue 13; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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Title: A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries

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