Novel Low-Temperature Electrolyte Using Isoxazole as the Main Solvent for Lithium-Ion Batteries

Tan, Sha; Rodrigo, Undugodage Dilhari; Shadike, Zulipiya; Lucht, Brett; Xu, Kang; Wang, Chunsheng; Yang, Xiao-Qing; Hu, Enyuan

doi:10.1021/acsami.1c05894

Title: Novel Low-Temperature Electrolyte Using Isoxazole as the Main Solvent for Lithium-Ion Batteries

Journal Article · Wed May 19 00:00:00 EDT 2021 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.1c05894· OSTI ID:1784490

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Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Rhode Island, Kingston, RI (United States)
Army Research Lab., Adelphi, MD (United States)
Univ. of Maryland, College Park, MD (United States)

A novel electrolyte system with an excellent low temperature performance for lithium-ion batteries (LIBs) has been developed and studied. It was discovered for the first time, in this work, that when isoxazole (IZ) was used as the main solvent, the ionic conductivity of the electrolyte for LIBs is more than doubled in a temperature range between -20 and 20 °C compared to the baseline electrolyte using ethylene carbonate–ethyl methyl carbonate as solvents. To solve the problem of solvent cointercalation into the graphite anode and/or electrolyte decomposition, the lithium difluoro(oxalato)borate (LiDFOB) salt and fluoroethylene carbonate (FEC) additive were used to form a stable solid electrolyte interphase on the surface of the graphite anode. Benefitting from the high ionic conductivity at low temperature, cells using a new electrolyte with 1 M LiDFOB in FEC/IZ (1:10, vol %) solvents demonstrated a very high reversible capacity of 187.5 mAh g^-1 at -20 °C, while the baseline electrolyte only delivered a reversible capacity of 23.1 mAh g^-1.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Vehicle Technologies Office (VTO)

Grant/Contract Number:: SC0012704

OSTI ID:: 1784490

Report Number(s):: BNL-221452-2021-JAAM

Journal Information:: ACS Applied Materials and Interfaces, Vol. 13, Issue 21; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (30)

Locally Concentrated LiPF ₆ in a Carbonate-Based Electrolyte with Fluoroethylene Carbonate as a Diluent for Anode-Free Lithium Metal Batteries Hagos, Tesfaye Teka; Thirumalraj, Balamurugan; Huang, Chen-Jui ACS Applied Materials & Interfaces, Vol. 11, Issue 10 https://doi.org/10.1021/acsami.8b21052	journal	February 2019
Performance of Li-ion cells with new electrolytes conceived for low-temperature applications Sazhin, Sergey V.; Khimchenko, Mikhail Yu; Tritenichenko, Yevgeniy N. Journal of Power Sources, Vol. 87, Issue 1-2 https://doi.org/10.1016/S0378-7753(99)00434-6	journal	April 2000
Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF ₆ , LiBF ₄ , LiDFOB, LiBOB, and LiTFSI Parimalam, Bharathy S.; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0901802jes	journal	January 2018
A review on lithium-ion battery ageing mechanisms and estimations for automotive applications Barré, Anthony; Deguilhem, Benjamin; Grolleau, Sébastien Journal of Power Sources, Vol. 241 https://doi.org/10.1016/j.jpowsour.2013.05.040	journal	November 2013
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries Verma, Pallavi; Maire, Pascal; Novák, Petr Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341 https://doi.org/10.1016/j.electacta.2010.05.072	journal	September 2010
Advanced Lithium-Ion Batteries for Practical Applications: Technology, Development, and Future Perspectives Choi, Sinho; Wang, Guoxiu Advanced Materials Technologies, Vol. 3, Issue 9 https://doi.org/10.1002/admt.201700376	journal	July 2018
Surface film formation on a carbonaceous electrode: Influence of the binder chemistry El Ouatani, L.; Dedryvère, R.; Ledeuil, J. -B. Journal of Power Sources, Vol. 189, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.11.031	journal	April 2009
Improved performance of lithium-ion cells with the use of fluorinated carbonate-based electrolytes Smart, M.C.; Ratnakumar, B.V.; Ryan-Mowrey, V.S. Journal of Power Sources, Vol. 119-121, p. 359-367 https://doi.org/10.1016/S0378-7753(03)00266-0	journal	April 2003
Investigation and application of lithium difluoro(oxalate)borate (LiDFOB) as additive to improve the thermal stability of electrolyte for lithium-ion batteries Xu, Mengqing; Zhou, Liu; Hao, Liansheng Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.10.050	journal	August 2011
Dissociative electron attachment induced ring opening in five-membered heterocyclic compounds Li, Zhou; Carmichael, Ian; Ptasińska, Sylwia Physical Chemistry Chemical Physics, Vol. 20, Issue 27 https://doi.org/10.1039/C8CP02718H	journal	January 2018
Lithium and lithium ion batteries for applications in microelectronic devices: A review Wang, Yuxing; Liu, Bo; Li, Qiuyan Journal of Power Sources, Vol. 286 https://doi.org/10.1016/j.jpowsour.2015.03.164	journal	July 2015
Li ⁺ -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances Li, Qiuyan; Lu, Dongping; Zheng, Jianming ACS Applied Materials & Interfaces, Vol. 9, Issue 49 https://doi.org/10.1021/acsami.7b13887	journal	November 2017
Constructing Robust Electrode/Electrolyte Interphases to Enable Wide Temperature Applications of Lithium-Ion Batteries Liu, Bin; Li, Qiuyan; Engelhard, Mark H. ACS Applied Materials & Interfaces, Vol. 11, Issue 24 https://doi.org/10.1021/acsami.9b03821	journal	May 2019
Materials insights into low-temperature performances of lithium-ion batteries Zhu, Gaolong; Wen, Kechun; Lv, Weiqiang Journal of Power Sources, Vol. 300 https://doi.org/10.1016/j.jpowsour.2015.09.056	journal	December 2015
A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries Alvarado, Judith; Schroeder, Marshall A.; Zhang, Minghao Materials Today, Vol. 21, Issue 4 https://doi.org/10.1016/j.mattod.2018.02.005	journal	May 2018
Generation and Evolution of the Solid Electrolyte Interphase of Lithium-Ion Batteries Heiskanen, Satu Kristiina; Kim, Jongjung; Lucht, Brett L. Joule, Vol. 3, Issue 10 https://doi.org/10.1016/j.joule.2019.08.018	journal	October 2019
The recent progress of isoxazole in medicinal chemistry Zhu, Jie; Mo, Jun; Lin, Hong-zhi Bioorganic & Medicinal Chemistry, Vol. 26, Issue 12 https://doi.org/10.1016/j.bmc.2018.05.013	journal	July 2018
Role of Lithium Salt on Solid Electrolyte Interface (SEI) Formation and Structure in Lithium Ion Batteries Nie, Mengyun; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 161, Issue 6 https://doi.org/10.1149/2.054406jes	journal	January 2014
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Nitrile-assistant eutectic electrolytes for cryogenic operation of lithium ion batteries at fast charges and discharges Cho, Yoon-Gyo; Kim, Young-Soo; Sung, Dong-Gil Energy Environ. Sci., Vol. 7, Issue 5 https://doi.org/10.1039/C3EE43029D	journal	January 2014
Tailoring Low-Temperature Performance of a Lithium-Ion Battery via Rational Designing Interphase on an Anode Guo, Rude; Che, Yanxia; Lan, Guangyuan ACS Applied Materials & Interfaces, Vol. 11, Issue 41 https://doi.org/10.1021/acsami.9b12020	journal	September 2019
2,3,4,5,6-Pentafluorophenyl Methanesulfonate as a Versatile Electrolyte Additive Matches LiNi _0.5 Co _0.2 Mn _0.3 O ₂ /Graphite Batteries Working in a Wide-Temperature Range Yang, Tianxiang; Fan, Weizhen; Wang, Chengyun ACS Applied Materials & Interfaces, Vol. 10, Issue 37 https://doi.org/10.1021/acsami.8b04743	journal	August 2018
Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance Smart, M. C.; Ratnakumar, B. V.; Chin, K. B. Journal of The Electrochemical Society, Vol. 157, Issue 12 https://doi.org/10.1149/1.3501236	journal	January 2010
Electrical characteristics of 18650 Li-ion cells at low temperatures Nagasubramanian, G. Journal of Applied Electrochemistry, Vol. 31, Issue 1, p. 99-104 https://doi.org/10.1023/A:1004113825283	journal	January 2001
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267 https://doi.org/10.1021/jp3118055	journal	January 2013
Issues and challenges facing rechargeable lithium batteries Tarascon, J. -M.; Armand, M. Materials for Sustainable Energy https://doi.org/10.1142/9789814317665_0024	book	October 2010
Use of Organic Esters as Cosolvents in Electrolytes for Lithium-Ion Batteries with Improved Low Temperature Performance Smart, M. C.; Ratnakumar, B. V.; Surampudi, S. Journal of The Electrochemical Society, Vol. 149, Issue 4 https://doi.org/10.1149/1.1453407	journal	January 2002
Lithium difluorophosphate as an additive to improve the low temperature performance of LiNi0.5Co0.2Mn0.3O2/graphite cells Yang, Bowen; Zhang, Hong; Yu, Le Electrochimica Acta, Vol. 221 https://doi.org/10.1016/j.electacta.2016.10.037	journal	December 2016
Designing Low Impedance Interface Films Simultaneously on Anode and Cathode for High Energy Batteries Liao, Bo; Li, Hongying; Xu, Mengqing Advanced Energy Materials, Vol. 8, Issue 22 https://doi.org/10.1002/aenm.201800802	journal	May 2018

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25 ENERGY STORAGE
isoxazole
solid electrolyte interphase
ionic conductivity
low-temperature electrolyte
lithium ion battery

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