Facile P-C/C-H Bond-Cleavage Reactivity of Nickel Bis(diphosphine) Complexes
Journal Article
·
· Chemistry - A European Journal
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Unusual cleavage of P-C and C-H bonds of the P2N2 ligand in heteroleptic [Ni(P2N2)(diphosphine)]2+ complexes results in the formation of an iminium formyl nickelate featuring a C,P,P-tridentate coordination mode.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1290404
- Report Number(s):
- PNNL-SA--115898; KC0302010
- Journal Information:
- Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 28 Vol. 22; ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
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