Facile ligand displacement in the bis(1,10-phenanthroline)-copper(I) complex cation by diphosphines
Journal Article
·
· J. Coord. Chem.; (United States)
Ligand substitution occurs readily at room temperature upon mixing stoichiometric quantities of (Cu(phen)/sub 2/)NO/sub 3/ and free triphenylphosphine or diphosphines Ph/sub 2/P(CH/sub 2/)/sub n/PPh/sub 2/ (n = 1-3). The resultant cationic complexes (Cu(phen)(PP))X are isolated as PF/sub 6//sup /minus// or NO/sub 3//sup /minus// salts in high yields.
- Research Organization:
- National Univ. of Singapore, Kent Ridge (China)
- OSTI ID:
- 5913980
- Journal Information:
- J. Coord. Chem.; (United States), Journal Name: J. Coord. Chem.; (United States) Vol. 18:4; ISSN JCCMB
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
14 SOLAR ENERGY
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
AZAARENES
CATIONS
CHARGED PARTICLES
CHEMICAL REACTIONS
COMPLEXES
COPPER COMPLEXES
DATA
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IONS
LIGANDS
MEDIUM TEMPERATURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHENANTHROLINES
PHOSPHINES
PHOSPHORUS COMPOUNDS
TRANSITION ELEMENT COMPLEXES
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
AZAARENES
CATIONS
CHARGED PARTICLES
CHEMICAL REACTIONS
COMPLEXES
COPPER COMPLEXES
DATA
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IONS
LIGANDS
MEDIUM TEMPERATURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHENANTHROLINES
PHOSPHINES
PHOSPHORUS COMPOUNDS
TRANSITION ELEMENT COMPLEXES