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Partial electron ionization cross sections for molecules

Journal Article · · Bulletin of the American Physical Society
OSTI ID:127912
Fragment ions produced by dissociative electron impact ionization often have large amounts of kinetic energy (up to several eV). Presently performed computer simulations of the ion trajectories in a Nier-type ion source show strong discrimination effects in the extraction characteristics of such ions. Using these results a correction function is calculated here for a given potential distribution of such a Nier type ion source extraction system. This correction function has been used to correct partial ionization cross sections measured with a modified Nier type ion source in combination with a double focusing sector field mass spectrometer. The obtained results for H{sub 2}, N{sub 2}, CF{sub 4}, SF{sub 6} and C{sub 3}H{sub 8} will be presented and their occuracy will be discussed using selected previous data for comparison.
OSTI ID:
127912
Report Number(s):
CONF-920376--
Journal Information:
Bulletin of the American Physical Society, Journal Name: Bulletin of the American Physical Society Journal Issue: 9 Vol. 37; ISSN BAPSA6; ISSN 0003-0503
Country of Publication:
United States
Language:
English

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