Atmospheric chemistry of 1-octene, 1-decene and cyclohexene
Conference
·
OSTI ID:127050
- DGA, Inc., Ventura, CA (United States)
- California Institute of Technology, Pasadena, CA (United States)
The atmospheric reactions of the 3 olefins 1-octene, 1-decene and cyclohexene have been studied in laboratory experiments involving olefin-ozone mixtures in the dark (with cyclohexane added to scavenge OH) and olefin-NO mxitures in sunlight. Carbonyl products of the ozone-olefin and OH-olefin reactions have been identified. The corresponding reactions mechanisms are outlined. Carbonyl yields have been measured for the ozone-olefin reaction. Sunlight irradiation of olefin-NO mixtures led to the formation of high molecular weight peroxyacyl nitrates, RC(O)OONO{sub 2}, which have been characterized.
- OSTI ID:
- 127050
- Report Number(s):
- CONF-950402--
- Country of Publication:
- United States
- Language:
- English
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