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Liquefaction processes and systems and liquefaction process intermediate compositions

Patent ·
OSTI ID:1261631

Liquefaction processes are provided that can include: providing a biomass slurry solution having a temperature of at least 300.degree. C. at a pressure of at least 2000 psig; cooling the solution to a temperature of less than 150.degree. C.; and depressurizing the solution to release carbon dioxide from the solution and form at least part of a bio-oil foam. Liquefaction processes are also provided that can include: filtering the biomass slurry to remove particulates; and cooling and depressurizing the filtered solution to form the bio-oil foam. Liquefaction systems are provided that can include: a heated biomass slurry reaction zone maintained above 300.degree. C. and at least 2000 psig and in continuous fluid communication with a flash cooling/depressurization zone maintained below 150.degree. C. and between about 125 psig and about atmospheric pressure. Liquefaction systems are also provided that can include a foam/liquid separation system. Liquefaction process intermediate compositions are provided that can include a bio-oil foam phase separated from an aqueous biomass solids solution.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Number(s):
9,388,364
Application Number:
14/738,563
OSTI ID:
1261631
Country of Publication:
United States
Language:
English

References (7)

Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies journal January 2008
Life cycle comparison of hydrothermal liquefaction and lipid extraction pathways to renewable diesel from algae journal June 2012
Supercritical water gasification of an aqueous by-product from biomass hydrothermal liquefaction with novel Ru modified Ni catalysts journal September 2011
SunCHem: an integrated process for the hydrothermal production of methane from microalgae and CO2 mitigation journal February 2009
Hydrothermal liquefaction of biomass: Developments from batch to continuous process journal February 2015
Numerical Simulation of CO2 Gas Microbubble of Foamy Oil journal January 2014
Hydrothermal liquefaction of biomass: A review of subcritical water technologies journal May 2011

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