Isotopic evidence for reductive immobilization of uranium across a roll-front mineral deposit

Brown, Shaun T.; Basu, Anirban; Christensen, John N.; Reimus, Paul; Heikoop, Jeffrey; Simmons, Ardyth; Woldegabriel, Giday; Maher, Kate; Weaver, Karrie; Clay, James; DePaolo, Donald J.

doi:10.1021/acs.est.6b00626

Title: Isotopic evidence for reductive immobilization of uranium across a roll-front mineral deposit

Journal Article · Fri May 20 00:00:00 EDT 2016 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.6b00626· OSTI ID:1260414

Brown, Shaun T. ^[1]; Basu, Anirban ^[1]; Christensen, John N. ^[2]; Reimus, Paul ^[3]; Heikoop, Jeffrey ^[3]; Simmons, Ardyth ^[3]; Woldegabriel, Giday ^[3]; Maher, Kate ^[4]; Weaver, Karrie ^[4]; Clay, James ^[5]; DePaolo, Donald J. ^[1]

Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Stanford Univ., Stanford, CA (United States)
Power Resources Inc., Douglas, WY (United States)

We use uranium (U) isotope ratios to detect and quantify the extent of natural U reduction in groundwater across a roll front redox gradient. Our study was conducted at the Smith Ranch-Highland in situ recovery (ISR) U mine in eastern Wyoming, USA, where economic U deposits occur in the Paleocene Fort Union formation. To evaluate the fate of aqueous U in and adjacent to the ore body, we investigated the chemical composition and isotope ratios of groundwater samples from the roll-front type ore body and surrounding monitoring wells of a previously mined area. The ²³⁸U/²³⁵U of groundwater varies by approximately 3‰ and is correlated with U concentrations. Fluid samples down-gradient of the ore zone are the most depleted in ²³⁸U and have the lowest U concentrations. Activity ratios of ²³⁴U/²³⁸U are ~5.5 up-gradient of the ore zone, ~1.0 in the ore zone, and between 2.3 and 3.7 in the down-gradient monitoring wells. High-precision measurements of ²³⁴U/²³⁸U and ²³⁸U/²³⁵U allow for development of a conceptual model that evaluates both the migration of U from the ore body and the extent of natural attenuation due to reduction. We find that the premining migration of U down-gradient of the delineated ore body is minimal along eight transects due to reduction in or adjacent to the ore body, whereas two other transects show little or no sign of reduction in the down-gradient region. Lastly, these results suggest that characterization of U isotopic ratios at the mine planning stage, in conjunction with routine geochemical analyses, can be used to identify where more or less postmining remediation will be necessary.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1260414

Report Number(s):: LA-UR-14-23843

Journal Information:: Environmental Science and Technology, Vol. 50, Issue 12; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 31 works

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