Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies

Li, Hong; Tsai, Charlie; Koh, Ai Leen; Cai, Lili; Contryman, Alex W.; Fragapane, Alex H.; Zhao, Jiheng; Han, Hyun Soon; Manoharan, Hari C.; Abild-Pedersen, Frank; Nørskov, Jens K.; Zheng, Xiaolin

doi:10.1038/NMAT4465

Activating and optimizing MoS₂ basal planes for hydrogen evolution through the formation of strained sulphur vacancies

Journal Article · Mon Nov 09 00:00:00 EST 2015 · Nature Materials

DOI:https://doi.org/10.1038/NMAT4465· OSTI ID:1257223

Li, Hong ^[1]; ^[2]; Koh, Ai Leen ^[1]; Cai, Lili ^[1]; Contryman, Alex W. ^[3]; Fragapane, Alex H. ^[3]; Zhao, Jiheng ^[1]; Han, Hyun Soon ^[1]; Manoharan, Hari C. ^[3]; Abild-Pedersen, Frank ^[4]; Nørskov, Jens K. ^[2]; Zheng, Xiaolin ^[1]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States); Stanford Univ., Stanford, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

As a promising non-precious catalyst for the hydrogen evolution reaction, molybdenum disulphide (MoS₂) is known to contain active edge sites and an inert basal plane. Activating the MoS₂ basal plane could further enhance its HER activity but is not often a strategy for doing so. Herein, we report the first activation and optimization of the basal plane of monolayer 2H-MoS₂ for HER by introducing sulphur (S) vacancies and strain. Our theoretical and experimental results show that the S-vacancies are new catalytic sites in the basal plane, where gap states around the Fermi level allow hydrogen to bind directly to exposed Mo atoms. The hydrogen adsorption free energy (ΔG_H) can be further manipulated by straining the surface with S-vacancies, which fine-tunes the catalytic activity. Furthermore, proper combinations of S-vacancy and strain yield the optimal ΔG_H = 0 eV, which allows us to achieve the highest intrinsic HER activity among molybdenum-sulphide-based catalysts.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center on Nanostructuring for Efficient Energy Conversion (CNEEC); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1257223

Alternate ID(s):: OSTI ID: 1369993

Journal Information:: Nature Materials, Journal Name: Nature Materials Journal Issue: 1 Vol. 15; ISSN 1476-1122

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (38)

Defect-Rich MoS ₂ Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution Xie, Junfeng; Zhang, Hao; Li, Shuang Advanced Materials, Vol. 25, Issue 40 https://doi.org/10.1002/adma.201302685	journal	August 2013
Alloy Catalysts Designed from First Principles. Greeley, Jeff; Mavrikakis, Manos ChemInform, Vol. 36, Issue 1 https://doi.org/10.1002/chin.200501206	journal	January 2005
Trends in the Exchange Current for Hydrogen Evolution. Noerskov, J. K.; Bligaard, T.; Logadottir, A. ChemInform, Vol. 36, Issue 24 https://doi.org/10.1002/chin.200524023	journal	June 2005
Biomimetic Hydrogen Evolution: MoS2 Nanoparticles as Catalyst for Hydrogen Evolution Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob ChemInform, Vol. 36, Issue 25 https://doi.org/10.1002/chin.200525015	journal	June 2005
Universality in Heterogeneous Catalysis Nørskov, J. K.; Bligaard, T.; Logadottir, A. Journal of Catalysis, Vol. 209, Issue 2 https://doi.org/10.1006/jcat.2002.3615	journal	July 2002
Transition-metal doped edge sites in vertically aligned MoS2 catalysts for enhanced hydrogen evolution Wang, Haotian; Tsai, Charlie; Kong, Desheng Nano Research, Vol. 8, Issue 2 https://doi.org/10.1007/s12274-014-0677-7	journal	January 2015
Theoretical insights into the hydrogen evolution activity of layered transition metal dichalcogenides Tsai, Charlie; Chan, Karen; Nørskov, Jens K. Surface Science, Vol. 640 https://doi.org/10.1016/j.susc.2015.01.019	journal	October 2015
Trends in the Hydrogen Evolution Activity of Metal Carbide Catalysts Michalsky, Ronald; Zhang, Yin-Jia; Peterson, Andrew A. ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs500056u	journal	March 2014
Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials Benck, Jesse D.; Hellstern, Thomas R.; Kibsgaard, Jakob ACS Catalysis, Vol. 4, Issue 11 https://doi.org/10.1021/cs500923c	journal	October 2014
Biomimetic Hydrogen Evolution: MoS ₂ Nanoparticles as Catalyst for Hydrogen Evolution Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob Journal of the American Chemical Society, Vol. 127, Issue 15 https://doi.org/10.1021/ja0504690	journal	April 2005
MoS₂ Nanoparticles Grown on Graphene An Advanced Catalyst for the Hydrogen Evolution Reaction Li, Yanguang; Wang, Hailiang; Xie, Liming Journal of the American Chemical Society, Vol. 133, Issue 19, p. 7296-7299 https://doi.org/10.1021/ja201269b	journal	May 2011
Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS ₂ Nanosheets Lukowski, Mark A.; Daniel, Andrew S.; Meng, Fei Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja404523s	journal	May 2013
Hydrogen Evolution on Supported Incomplete Cubane-type [Mo₃S₄]⁴⁺ Electrocatalysts Jaramillo, Thomas F.; Bonde, Jacob; Zhang, Jingdong The Journal of Physical Chemistry C, Vol. 112, Issue 45, p. 17492-17498 https://doi.org/10.1021/jp802695e	journal	November 2008
Core–shell MoO₃–MoS₂ Nanowires for Hydrogen Evolution A Functional Design for Electrocatalytic Materials Chen, Zhebo; Cummins, Dustin; Reinecke, Benjamin N. Nano Letters, Vol. 11, Issue 10, p. 4168-4175 https://doi.org/10.1021/nl2020476	journal	October 2011
Synthesis of MoS₂ and MoSe₂ Films with Vertically Aligned Layers Kong, Desheng; Wang, Haotian; Cha, Judy J. Nano Letters, Vol. 13, Issue 3, p. 1341-1347 https://doi.org/10.1021/nl400258t	journal	February 2013
Conducting MoS ₂ Nanosheets as Catalysts for Hydrogen Evolution Reaction Voiry, Damien; Salehi, Maryam; Silva, Rafael Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl403661s	journal	November 2013
Tuning the MoS ₂ Edge-Site Activity for Hydrogen Evolution via Support Interactions Tsai, Charlie; Abild-Pedersen, Frank; Nørskov, Jens K. Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl404444k	journal	February 2014
MoS ₂ /Graphene Cocatalyst for Efficient Photocatalytic H ₂ Evolution under Visible Light Irradiation Chang, Kun; Mei, Zongwei; Wang, Tao ACS Nano, Vol. 8, Issue 7 https://doi.org/10.1021/nn5019945	journal	June 2014
Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo3S13]2− clusters Kibsgaard, Jakob; Jaramillo, Thomas F.; Besenbacher, Flemming Nature Chemistry, Vol. 6, Issue 3 https://doi.org/10.1038/nchem.1853	journal	January 2014
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.623	journal	April 2010
Optoelectronic crystal of artificial atoms in strain-textured molybdenum disulphide Li, Hong; Contryman, Alex W.; Qian, Xiaofeng Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8381	journal	June 2015
Alloy catalysts designed from first principles Greeley, Jeff; Mavrikakis, Manos Nature Materials, Vol. 3, Issue 11 https://doi.org/10.1038/nmat1223	journal	October 2004
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob Nature Materials, Vol. 5, Issue 11, p. 909-913 https://doi.org/10.1038/nmat1752	journal	October 2006
Engineering the surface structure of MoS₂ to preferentially expose active edge sites for electrocatalysis Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N. Nature Materials, Vol. 11, Issue 11, p. 963-969 https://doi.org/10.1038/nmat3439	journal	October 2012
Vapour phase growth and grain boundary structure of molybdenum disulphide atomic layers Najmaei, Sina; Liu, Zheng; Zhou, Wu Nature Materials, Vol. 12, Issue 8, p. 754-759 https://doi.org/10.1038/nmat3673	journal	June 2013
Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution Voiry, Damien; Yamaguchi, Hisato; Li, Junwen Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3700	journal	July 2013
Influence of water on elementary reaction steps in electrocatalysis Gohda, Yoshihiro; Schnur, Sebastian; Groß, Axel Faraday Discuss., Vol. 140 https://doi.org/10.1039/B802270D	journal	January 2009
Hydrogen evolution on nano-particulate transition metal sulfides Bonde, Jacob; Moses, Poul G.; Jaramillo, Thomas F. Faraday Discuss., Vol. 140 https://doi.org/10.1039/B803857K	journal	January 2009
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts Merki, Daniel; Hu, Xile Energy & Environmental Science, Vol. 4, Issue 10, 3878 https://doi.org/10.1039/c1ee01970h	journal	January 2011
Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts Chen, Wei-Fu; Muckerman, James T.; Fujita, Etsuko Chemical Communications, Vol. 49, Issue 79 https://doi.org/10.1039/c3cc44076a	journal	January 2013
Controlled argon beam-induced desulfurization of monolayer molybdenum disulfide Ma, Quan; Odenthal, Patrick M.; Mann, John Journal of Physics: Condensed Matter, Vol. 25, Issue 25 https://doi.org/10.1088/0953-8984/25/25/252201	journal	May 2013
Kohn-Sham potential with discontinuity for band gap materials Kuisma, M.; Ojanen, J.; Enkovaara, J. Physical Review B, Vol. 82, Issue 11 https://doi.org/10.1103/PhysRevB.82.115106	journal	September 2010
Density functionals for surface science: Exchange-correlation model development with Bayesian error estimation Wellendorff, Jess; Lundgaard, Keld T.; Møgelhøj, Andreas Physical Review B, Vol. 85, Issue 23 https://doi.org/10.1103/PhysRevB.85.235149	journal	June 2012
Self-Assembly of Subnanometer-Diameter Single-Wall MoS2 Nanotubes Remskar, M.; Mrzel, A.; Skraba, Z. Science, Vol. 292, Issue 5516 https://doi.org/10.1126/science.1059011	journal	April 2001
Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007
Trends in the Exchange Current for Hydrogen Evolution Nørskov, J. K.; Bligaard, T.; Logadottir, A. Journal of The Electrochemical Society, Vol. 152, Issue 3 https://doi.org/10.1149/1.1856988	journal	January 2005
“Stretching” the energy landscape of oxides—Effects on electrocatalysis and diffusion Yildiz, Bilge MRS Bulletin, Vol. 39, Issue 2 https://doi.org/10.1557/mrs.2014.8	journal	February 2014
Kohn-Sham potential with discontinuity for band gap materials Kuisma, M.; Ojanen, J.; Enkovaara, J. arXiv https://doi.org/10.48550/arxiv.1003.0296	text	January 2010

Cited By (280)

Surface-Shielding Nanostructures Derived from Self-Assembled Block Copolymers Enable Reliable Plasma Doping for Few-Layer Transition Metal Dichalcogenides Yim, Soonmin; Sim, Dong Min; Park, Woon Ik Advanced Functional Materials, Vol. 26, Issue 31 https://doi.org/10.1002/adfm.201600654	journal	June 2016
Promoting Active Sites in Core-Shell Nanowire Array as Mott-Schottky Electrocatalysts for Efficient and Stable Overall Water Splitting Hou, Jungang; Sun, Yiqing; Wu, Yunzhen Advanced Functional Materials, Vol. 28, Issue 4 https://doi.org/10.1002/adfm.201704447	journal	November 2017
A Type of 1 nm Molybdenum Carbide Confined within Carbon Nanomesh as Highly Efficient Bifunctional Electrocatalyst Cheng, Zhihua; Fu, Qiang; Han, Qing Advanced Functional Materials, Vol. 28, Issue 18 https://doi.org/10.1002/adfm.201705967	journal	January 2018
Nonprecious Intermetallic Al ₇ Cu ₄ Ni Nanocrystals Seamlessly Integrated in Freestanding Bimodal Nanoporous Copper for Efficient Hydrogen Evolution Catalysis Sun, Jie-Song; Wen, Zi; Han, Li-Ping Advanced Functional Materials, Vol. 28, Issue 14 https://doi.org/10.1002/adfm.201706127	journal	January 2018
Surface Defect Engineering in 2D Nanomaterials for Photocatalysis Xiong, Jun; Di, Jun; Xia, Jiexiang Advanced Functional Materials, Vol. 28, Issue 39 https://doi.org/10.1002/adfm.201801983	journal	July 2018
Heterostructures for Electrochemical Hydrogen Evolution Reaction: A Review Zhao, Guoqiang; Rui, Kun; Dou, Shi Xue Advanced Functional Materials, Vol. 28, Issue 43 https://doi.org/10.1002/adfm.201803291	journal	August 2018
Surface Modulation of Hierarchical MoS ₂ Nanosheets by Ni Single Atoms for Enhanced Electrocatalytic Hydrogen Evolution Zhang, Huabin; Yu, Le; Chen, Tao Advanced Functional Materials, Vol. 28, Issue 51 https://doi.org/10.1002/adfm.201807086	journal	October 2018
MoS _x @NiO Composite Nanostructures: An Advanced Nonprecious Catalyst for Hydrogen Evolution Reaction in Alkaline Media Ibupoto, Zafar Hussain; Tahira, Aneela; Tang, PengYi Advanced Functional Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adfm.201807562	journal	January 2019
Nanoscale Selective Passivation of Electrodes Contacting a 2D Semiconductor Lihter, Martina; Graf, Michael; Iveković, Damir Advanced Functional Materials, Vol. 30, Issue 6 https://doi.org/10.1002/adfm.201907860	journal	December 2019
Activating Basal Planes of NiPS ₃ for Hydrogen Evolution by Nonmetal Heteroatom Doping Wang, Jun; Li, Xinzhe; Wei, Bin Advanced Functional Materials, Vol. 30, Issue 12 https://doi.org/10.1002/adfm.201908708	journal	February 2020
Superior Chemical Sensing Performance of Black Phosphorus: Comparison with MoS ₂ and Graphene Cho, Soo-Yeon; Lee, Youhan; Koh, Hyeong-Jun Advanced Materials, Vol. 28, Issue 32 https://doi.org/10.1002/adma.201601167	journal	June 2016
Weyl Semimetals as Hydrogen Evolution Catalysts Rajamathi, Catherine R.; Gupta, Uttam; Kumar, Nitesh Advanced Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adma.201606202	journal	March 2017
Atomic Defects in Two-Dimensional Materials: From Single-Atom Spectroscopy to Functionalities in Opto-/Electronics, Nanomagnetism, and Catalysis Hong, Jinhua; Jin, Chuanhong; Yuan, Jun Advanced Materials, Vol. 29, Issue 14 https://doi.org/10.1002/adma.201606434	journal	March 2017
Defect Chemistry of Nonprecious-Metal Electrocatalysts for Oxygen Reactions Yan, Dafeng; Li, Yunxiao; Huo, Jia Advanced Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adma.201606459	journal	May 2017
Regulating Water-Reduction Kinetics in Cobalt Phosphide for Enhancing HER Catalytic Activity in Alkaline Solution Xu, Kun; Ding, Hui; Zhang, Mengxing Advanced Materials, Vol. 29, Issue 28 https://doi.org/10.1002/adma.201606980	journal	May 2017
Direct Synthesis of Large-Area 2D Mo ₂ C on In Situ Grown Graphene Geng, Dechao; Zhao, Xiaoxu; Chen, Zhongxin Advanced Materials, Vol. 29, Issue 35 https://doi.org/10.1002/adma.201700072	journal	July 2017
Synergistic Phase and Disorder Engineering in 1T-MoSe ₂ Nanosheets for Enhanced Hydrogen-Evolution Reaction Yin, Ying; Zhang, Yumin; Gao, Tangling Advanced Materials, Vol. 29, Issue 28 https://doi.org/10.1002/adma.201700311	journal	May 2017
Ultrathin Two‐Dimensional Multinary Layered Metal Chalcogenide Nanomaterials Tan, Chaoliang; Lai, Zhuangchai; Zhang, Hua Advanced Materials, Vol. 29, Issue 37 https://doi.org/10.1002/adma.201701392	journal	July 2017
Unveiling Active Sites for the Hydrogen Evolution Reaction on Monolayer MoS ₂ Zhang, Jing; Wu, Jingjie; Guo, Hua Advanced Materials, Vol. 29, Issue 42 https://doi.org/10.1002/adma.201701955	journal	September 2017
Layered-Double-Hydroxide Nanosheets as Efficient Visible-Light-Driven Photocatalysts for Dinitrogen Fixation Zhao, Yufei; Zhao, Yunxuan; Waterhouse, Geoffrey I. N. Advanced Materials, Vol. 29, Issue 42 https://doi.org/10.1002/adma.201703828	journal	September 2017
Structurally Deformed MoS ₂ for Electrochemically Stable, Thermally Resistant, and Highly Efficient Hydrogen Evolution Reaction Chen, Yen-Chang; Lu, Ang-Yu; Lu, Ping Advanced Materials, Vol. 29, Issue 44 https://doi.org/10.1002/adma.201703863	journal	October 2017
Atomic Vacancies Control of Pd-Based Catalysts for Enhanced Electrochemical Performance Zuo, Yunpeng; Rao, Dewei; Li, Shuo Advanced Materials, Vol. 30, Issue 1 https://doi.org/10.1002/adma.201704171	journal	November 2017
Porous Microrod Arrays Constructed by Carbon-Confined NiCo@NiCoO ₂ Core@Shell Nanoparticles as Efficient Electrocatalysts for Oxygen Evolution Xu, Han; Shi, Zi-Xiao; Tong, Ye-Xiang Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201705442	journal	April 2018
Preparation of High-Percentage 1T-Phase Transition Metal Dichalcogenide Nanodots for Electrochemical Hydrogen Evolution Tan, Chaoliang; Luo, Zhimin; Chaturvedi, Apoorva Advanced Materials, Vol. 30, Issue 9 https://doi.org/10.1002/adma.201705509	journal	January 2018
Plasma-Assisted Synthesis and Surface Modification of Electrode Materials for Renewable Energy Dou, Shuo; Tao, Li; Wang, Ruilun Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201705850	journal	February 2018
Vertical 1T-TaS ₂ Synthesis on Nanoporous Gold for High-Performance Electrocatalytic Applications Huan, Yahuan; Shi, Jianping; Zou, Xiaolong Advanced Materials, Vol. 30, Issue 15 https://doi.org/10.1002/adma.201705916	journal	March 2018
An Ultrastable Ionic Chemiresistor Skin with an Intrinsically Stretchable Polymer Electrolyte Jin, Ming Liang; Park, Sangsik; Kim, Jong-Seon Advanced Materials, Vol. 30, Issue 20 https://doi.org/10.1002/adma.201706851	journal	March 2018
Nitrogen-Doped CoP Electrocatalysts for Coupled Hydrogen Evolution and Sulfur Generation with Low Energy Consumption Zhou, Qingwen; Shen, Zihan; Zhu, Chao Advanced Materials, Vol. 30, Issue 27 https://doi.org/10.1002/adma.201800140	journal	May 2018
The Atomic Circus: Small Electron Beams Spotlight Advanced Materials Down to the Atomic Scale Wu, Haijun; Zhao, Xiaoxu; Guan, Cao Advanced Materials, Vol. 30, Issue 47 https://doi.org/10.1002/adma.201802402	journal	October 2018
Iron Vacancies Induced Bifunctionality in Ultrathin Feroxyhyte Nanosheets for Overall Water Splitting Liu, Bin; Wang, Yun; Peng, Hui-Qing Advanced Materials, Vol. 30, Issue 36 https://doi.org/10.1002/adma.201803144	journal	July 2018
Rhenium-Doped and Stabilized MoS ₂ Atomic Layers with Basal-Plane Catalytic Activity Yang, Shi-Ze; Gong, Yongji; Manchanda, Priyanka Advanced Materials, Vol. 30, Issue 51 https://doi.org/10.1002/adma.201803477	journal	October 2018
Interfacial Electron Transfer of Ni ₂ P-NiP ₂ Polymorphs Inducing Enhanced Electrochemical Properties Liu, Tong; Li, Anran; Wang, Chengbo Advanced Materials, Vol. 30, Issue 46 https://doi.org/10.1002/adma.201803590	journal	October 2018
Heterostructures Based on 2D Materials: A Versatile Platform for Efficient Catalysis Shifa, Tofik Ahmed; Wang, Fengmei; Liu, Yang Advanced Materials, Vol. 31, Issue 45 https://doi.org/10.1002/adma.201804828	journal	October 2018
Strain Engineering of 2D Materials: Issues and Opportunities at the Interface Dai, Zhaohe; Liu, Luqi; Zhang, Zhong Advanced Materials, Vol. 31, Issue 45 https://doi.org/10.1002/adma.201805417	journal	January 2019
Morphology‐Controlled Metal Sulfides and Phosphides for Electrochemical Water Splitting Joo, Jinwhan; Kim, Taekyung; Lee, Jaeyoung Advanced Materials, Vol. 31, Issue 14 https://doi.org/10.1002/adma.201806682	journal	February 2019
Enhancing Electrocatalytic Water Splitting by Strain Engineering You, Bo; Tang, Michael T.; Tsai, Charlie Advanced Materials, Vol. 31, Issue 17 https://doi.org/10.1002/adma.201807001	journal	February 2019
Well‐Dispersed Nickel‐ and Zinc‐Tailored Electronic Structure of a Transition Metal Oxide for Highly Active Alkaline Hydrogen Evolution Reaction Ling, Tao; Zhang, Tong; Ge, Binghui Advanced Materials, Vol. 31, Issue 16 https://doi.org/10.1002/adma.201807771	journal	February 2019
Discovery of Superconductivity in 2M WS 2 with Possible Topological Surface States Fang, Yuqiang; Pan, Jie; Zhang, Dongqin Advanced Materials https://doi.org/10.1002/adma.201901942	journal	June 2019
Nanowire Genome: A Magic Toolbox for 1D Nanostructures He, Zhen; Yang, Yuan; Liang, Hai‐Wei Advanced Materials, Vol. 31, Issue 51 https://doi.org/10.1002/adma.201902807	journal	September 2019
Colloidal Synthesis of Mo-Ni Alloy Nanoparticles as Bifunctional Electrocatalysts for Efficient Overall Water Splitting Zhang, Taotao; Liu, Xiaowang; Cui, Xin Advanced Materials Interfaces, Vol. 5, Issue 13 https://doi.org/10.1002/admi.201800359	journal	May 2018
2D Transition Metal Dichalcogenide Thin Films Obtained by Chemical Gas Phase Deposition Techniques Park, Gyu-Hyeon; Nielsch, Kornelius; Thomas, Andy Advanced Materials Interfaces, Vol. 6, Issue 3 https://doi.org/10.1002/admi.201800688	journal	October 2018
Transition Metal-Doped Edge-Terminated MoS ₂ Superstructures as Efficient Catalysts for H ₂ Production Ding, Jiabao; Shao, Qi; Bai, Shuxing Advanced Materials Interfaces, Vol. 5, Issue 24 https://doi.org/10.1002/admi.201801370	journal	October 2018
Directly Assembled 3D Molybdenum Disulfide on Silicon Wafer for Efficient Photoelectrochemical Water Reduction Andoshe, Dinsefa Mensur; Jin, Gangtae; Lee, Chang-Soo Advanced Sustainable Systems, Vol. 2, Issue 3 https://doi.org/10.1002/adsu.201700142	journal	January 2018
Nickel Hydr(oxy)oxide Nanoparticles on Metallic MoS ₂ Nanosheets: A Synergistic Electrocatalyst for Hydrogen Evolution Reaction Zhang, Xing; Liang, Yongye Advanced Science, Vol. 5, Issue 2 https://doi.org/10.1002/advs.201700644	journal	December 2017
Recent Progress on Layered Double Hydroxides and Their Derivatives for Electrocatalytic Water Splitting Wang, Yanyong; Yan, Dafeng; El Hankari, Samir Advanced Science, Vol. 5, Issue 8 https://doi.org/10.1002/advs.201800064	journal	May 2018
Engineering MoS ₂ Basal Planes for Hydrogen Evolution via Synergistic Ruthenium Doping and Nanocarbon Hybridization Zhang, Xing; Zhou, Feng; Zhang, Shen Advanced Science, Vol. 6, Issue 10 https://doi.org/10.1002/advs.201900090	journal	March 2019
Reversing Interfacial Catalysis of Ambipolar WSe ₂ Single Crystal Wang, Zegao; Wu, Hong‐Hui; Li, Qiang Advanced Science, Vol. 7, Issue 3 https://doi.org/10.1002/advs.201901382	journal	December 2019
Air and Water-Stable n-Type Doping and Encapsulation of Flexible MoS ₂ Devices with SU8 Kung, Yen-Cheng; Hosseini, Nahid; Dumcenco, Dumitru Advanced Electronic Materials, Vol. 5, Issue 1 https://doi.org/10.1002/aelm.201800492	journal	November 2018
Probing the Electronic Properties of Monolayer MoS ₂ via Interaction with Molecular Hydrogen Rezende, Natália P.; Cadore, Alisson R.; Gadelha, Andreij C. Advanced Electronic Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aelm.201800591	journal	December 2018
Metallic Twin Boundaries Boost the Hydrogen Evolution Reaction on the Basal Plane of Molybdenum Selenotellurides Kosmala, Tomasz; Coy Diaz, Horacio; Komsa, Hannu-Pekka Advanced Energy Materials, Vol. 8, Issue 20 https://doi.org/10.1002/aenm.201800031	journal	April 2018
Local Charge Distribution Engineered by Schottky Heterojunctions toward Urea Electrolysis Li, Caicai; Liu, Youwen; Zhuo, Zhiwen Advanced Energy Materials, Vol. 8, Issue 27 https://doi.org/10.1002/aenm.201801775	journal	August 2018
Applications of Plasma in Energy Conversion and Storage Materials Liang, Hanfeng; Ming, Fangwang; Alshareef, Husam N. Advanced Energy Materials, Vol. 8, Issue 29 https://doi.org/10.1002/aenm.201801804	journal	August 2018
Benchmarking the Activity, Stability, and Inherent Electrochemistry of Amorphous Molybdenum Sulfide for Hydrogen Production Escalera-López, Daniel; Lou, Zhiheng; Rees, Neil V. Advanced Energy Materials, Vol. 9, Issue 8 https://doi.org/10.1002/aenm.201802614	journal	January 2019
Vacancy in Ultrathin 2D Nanomaterials toward Sustainable Energy Application Bai, Fan; Xu, Liang; Zhai, Xiaoying Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902107	journal	November 2019
Atomically Dispersed Mo Supported on Metallic Co ₉ S ₈ Nanoflakes as an Advanced Noble‐Metal‐Free Bifunctional Water Splitting Catalyst Working in Universal pH Conditions Wang, Ligang; Duan, Xinxuan; Liu, Xijun Advanced Energy Materials, Vol. 10, Issue 4 https://doi.org/10.1002/aenm.201903137	journal	December 2019
Porous Molybdenum Phosphide Nano-Octahedrons Derived from Confined Phosphorization in UIO-66 for Efficient Hydrogen Evolution Yang, Jian; Zhang, Fengjun; Wang, Xin Angewandte Chemie, Vol. 128, Issue 41 https://doi.org/10.1002/ange.201604315	journal	July 2016
Rational Control of the Selectivity of a Ruthenium Catalyst for Hydrogenation of 4-Nitrostyrene by Strain Regulation Mao, Junjie; Chen, Wenxing; Sun, Wenming Angewandte Chemie, Vol. 129, Issue 39 https://doi.org/10.1002/ange.201706645	journal	August 2017
Modulierung der elektronischen Strukturen anorganischer Nanomaterialien für eine effiziente elektrokatalytische Wasserspaltung Du, Xinchuan; Huang, Jianwen; Zhang, Junjun Angewandte Chemie, Vol. 131, Issue 14 https://doi.org/10.1002/ange.201810104	journal	February 2019
Simultaneous Manipulation of O‐Doping and Metal Vacancy in Atomically Thin Zn ₁₀ In ₁₆ S ₃₄ Nanosheet Arrays toward Improved Photoelectrochemical Performance Meng, Linxing; Rao, Dewei; Tian, Wei Angewandte Chemie, Vol. 130, Issue 51 https://doi.org/10.1002/ange.201811632	journal	December 2018
Negative Charging of Transition‐Metal Phosphides via Strong Electronic Coupling for Destabilization of Alkaline Water You, Bo; Zhang, Yadong; Jiao, Yan Angewandte Chemie, Vol. 131, Issue 34 https://doi.org/10.1002/ange.201906683	journal	July 2019
Intercalated Iridium Diselenide Electrocatalysts for Efficient pH‐Universal Water Splitting Zheng, Tingting; Shang, Chunyan; He, Zhihai Angewandte Chemie, Vol. 131, Issue 41 https://doi.org/10.1002/ange.201909369	journal	September 2019
Rational Control of the Selectivity of a Ruthenium Catalyst for Hydrogenation of 4-Nitrostyrene by Strain Regulation Mao, Junjie; Chen, Wenxing; Sun, Wenming Angewandte Chemie International Edition, Vol. 56, Issue 39 https://doi.org/10.1002/anie.201706645	journal	August 2017
Post-Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization Hirsch, Andreas; Hauke, Frank Angewandte Chemie International Edition, Vol. 57, Issue 16 https://doi.org/10.1002/anie.201708211	journal	February 2018
Modulating Electronic Structures of Inorganic Nanomaterials for Efficient Electrocatalytic Water Splitting Du, Xinchuan; Huang, Jianwen; Zhang, Junjun Angewandte Chemie International Edition, Vol. 58, Issue 14 https://doi.org/10.1002/anie.201810104	journal	March 2019
Simultaneous Manipulation of O‐Doping and Metal Vacancy in Atomically Thin Zn ₁₀ In ₁₆ S ₃₄ Nanosheet Arrays toward Improved Photoelectrochemical Performance Meng, Linxing; Rao, Dewei; Tian, Wei Angewandte Chemie International Edition, Vol. 57, Issue 51 https://doi.org/10.1002/anie.201811632	journal	December 2018
Activating Inert Metallic Compounds for High‐Rate Lithium–Sulfur Batteries Through In Situ Etching of Extrinsic Metal Zhao, Meng; Peng, Hong‐Jie; Zhang, Ze‐Wen Angewandte Chemie International Edition, Vol. 58, Issue 12 https://doi.org/10.1002/anie.201812062	journal	March 2019
Intercalated Iridium Diselenide Electrocatalysts for Efficient pH‐Universal Water Splitting Zheng, Tingting; Shang, Chunyan; He, Zhihai Angewandte Chemie International Edition, Vol. 58, Issue 41 https://doi.org/10.1002/anie.201909369	journal	October 2019
High‐Resolution Electrochemical Mapping of the Hydrogen Evolution Reaction on Transition‐Metal Dichalcogenide Nanosheets Takahashi, Yasufumi; Kobayashi, Yu; Wang, Ziqian Angewandte Chemie International Edition, Vol. 59, Issue 9 https://doi.org/10.1002/anie.201912863	journal	January 2020
Defect Engineering of MoS ₂ and Its Impacts on Electrocatalytic and Photocatalytic Behavior in Hydrogen Evolution Reactions Zhang, Yuxiao; Kuwahara, Yasutaka; Mori, Kohsuke Chemistry – An Asian Journal https://doi.org/10.1002/asia.201801594	journal	December 2018
Ultrafine Ruthenium Oxide Nanoparticles Supported on Molybdenum Oxide Nanosheets as Highly Efficient Electrocatalyst for Hydrogen Evolution in Acidic Medium Sadhanala, Hari Krishna; Harika, Villa Krishna; Penki, Tirupathi Rao ChemCatChem, Vol. 11, Issue 5 https://doi.org/10.1002/cctc.201801990	journal	February 2019
Beyond 1T‐phase? Synergistic Electronic Structure and Defects Engineering in 2H‐MoS _2x Se _2(1‐x) Nanosheets for Enhanced Hydrogen Evolution Reaction and Sodium Storage Wang, Ran; Li, Xiaofeng; Gao, Tangling ChemCatChem, Vol. 11, Issue 14 https://doi.org/10.1002/cctc.201900682	journal	June 2019
The Holy Grail in Platinum‐Free Electrocatalytic Hydrogen Evolution: Molybdenum‐Based Catalysts and Recent Advances Zhuang, Zechao; Huang, Jiazhao; Li, Yong ChemElectroChem, Vol. 6, Issue 14 https://doi.org/10.1002/celc.201900143	journal	June 2019
Reduced graphene oxide‐based materials for electrochemical energy conversion reactions Choi, Seokhoon; Kim, Changyeon; Suh, Jun Min Carbon Energy, Vol. 1, Issue 1 https://doi.org/10.1002/cey2.13	journal	September 2019
Optimizing interfacial electronic coupling with metal oxide to activate inert polyaniline for superior electrocatalytic hydrogen generation Huang, Zhen‐Feng; Song, Jiajia; Du, Yonghua Carbon Energy, Vol. 1, Issue 1 https://doi.org/10.1002/cey2.3	journal	September 2019
CoSe ₂ /MoSe ₂ Heterostructures with Enriched Water Adsorption/Dissociation Sites towards Enhanced Alkaline Hydrogen Evolution Reaction Zhao, Guoqiang; Li, Peng; Rui, Kun Chemistry - A European Journal, Vol. 24, Issue 43 https://doi.org/10.1002/chem.201801693	journal	June 2018
Activating the MoS ₂ Basal Plane by Controllable Fabrication of Pores for an Enhanced Hydrogen Evolution Reaction Geng, Shuo; Liu, Hu; Yang, Weiwei Chemistry - A European Journal, Vol. 24, Issue 71 https://doi.org/10.1002/chem.201804658	journal	November 2018
Surface Modifications of Ti ₂ CO ₂ for Obtaining High Hydrogen Evolution Reaction Activity and Conductivity: A Computational Approach Wang, Shuo; Chen, Liang; Wu, Yang ChemPhysChem, Vol. 19, Issue 24 https://doi.org/10.1002/cphc.201800899	journal	November 2018
Enhanced 1T′-Phase Stabilization and Chemical Reactivity in a MoTe ₂ Monolayer through Contact with a 2D Ca ₂ N Electride Tang, Qing ChemPhysChem, Vol. 20, Issue 4 https://doi.org/10.1002/cphc.201801047	journal	January 2019
MoS ₂ Quantum Dots@TiO ₂ Nanotube Arrays: An Extended-Spectrum-Driven Photocatalyst for Solar Hydrogen Evolution Wang, Qun; Huang, Jianying; Sun, Hongtao ChemSusChem, Vol. 11, Issue 10 https://doi.org/10.1002/cssc.201800379	journal	May 2018
Unveiling Electrochemical Reaction Pathways of CO ₂ Reduction to C _N Species at S‐Vacancies of MoS ₂ Kang, Sungwoo; Han, Seungwu; Kang, Youngho ChemSusChem, Vol. 12, Issue 12 https://doi.org/10.1002/cssc.201900779	journal	May 2019
2 D Materials for Inhibiting the Shuttle Effect in Advanced Lithium–Sulfur Batteries Ali, Tariq; Yan, Chenglin ChemSusChem, Vol. 13, Issue 6 https://doi.org/10.1002/cssc.201901981	journal	March 2020
Two‐Dimensional MoS ₂ for Li−S Batteries: Structural Design and Electronic Modulation Cao, Yiqi; Lin, Yan; Wu, Jianbo ChemSusChem, Vol. 13, Issue 6 https://doi.org/10.1002/cssc.201902688	journal	March 2020
Facile hydrothermal synthesis of 3D flower‐like La‐MoS ₂ nanostructure for photocatalytic hydrogen energy production Nadeem Riaz, Khalid; Yousaf, Nadeem; Bilal Tahir, Muhammad International Journal of Energy Research, Vol. 43, Issue 1 https://doi.org/10.1002/er.4286	journal	October 2018
Effects of Precursor Concentration on Dimensional Size, Defect State, and Gas Sensing Performance of MoS ₂ Sheets Synthesized by Hydrothermal Method Lee, Chang Min; Park, Geun Chul; Ahn, Cheol Hyoun physica status solidi (a), Vol. 215, Issue 20 https://doi.org/10.1002/pssa.201800079	journal	July 2018
Enhanced Gas Sensing Performance of Surface‐Activated MoS ₂ Nanosheets Made by Hydrothermal Method with Excess Sulfur Precursor Lee, Chang Min; Jin, Chan Ho; Ahn, Cheol Hyoun physica status solidi (a), Vol. 216, Issue 9 https://doi.org/10.1002/pssa.201800999	journal	April 2019
High-Sulfur-Vacancy Amorphous Molybdenum Sulfide as a High Current Electrocatalyst in Hydrogen Evolution Lu, Ang-Yu; Yang, Xiulin; Tseng, Chien-Chih Small, Vol. 12, Issue 40 https://doi.org/10.1002/smll.201602107	journal	August 2016
Emerging 0D Transition-Metal Dichalcogenides for Sensors, Biomedicine, and Clean Energy Li, Bang Lin; Setyawati, Magdiel Inggrid; Zou, Hao Lin Small, Vol. 13, Issue 31 https://doi.org/10.1002/smll.201700527	journal	June 2017
Ultrathin Two-Dimensional Nanostructured Materials for Highly Efficient Water Oxidation Zhang, Wang; Zhou, Kun Small, Vol. 13, Issue 32 https://doi.org/10.1002/smll.201700806	journal	June 2017
Synergetic Exfoliation and Lateral Size Engineering of MoS ₂ for Enhanced Photocatalytic Hydrogen Generation Yin, Lisha; Hai, Xiao; Chang, Kun Small, Vol. 14, Issue 14 https://doi.org/10.1002/smll.201704153	journal	March 2018
Prereduction of Metal Oxides via Carbon Plasma Treatment for Efficient and Stable Electrocatalytic Hydrogen Evolution Zhang, Yongqi; Ouyang, Bo; Xu, Kun Small, Vol. 14, Issue 17 https://doi.org/10.1002/smll.201800340	journal	April 2018
Metallic MoS ₂ for High Performance Energy Storage and Energy Conversion Jiao, Yucong; Hafez, Ahmed M.; Cao, Daxian Small, Vol. 14, Issue 36 https://doi.org/10.1002/smll.201800640	journal	July 2018
Sulfur-Deficient Bismuth Sulfide/Nitrogen-Doped Carbon Nanofibers as Advanced Free-Standing Electrode for Asymmetric Supercapacitors Zong, Wei; Lai, Feili; He, Guanjie Small, Vol. 14, Issue 32 https://doi.org/10.1002/smll.201801562	journal	July 2018
Edge-Terminated MoS ₂ Nanoassembled Electrocatalyst via In Situ Hybridization with 3D Carbon Network Chung, Dong Young; Yoo, Ji Mun; Park, Subin Small, Vol. 14, Issue 36 https://doi.org/10.1002/smll.201802191	journal	August 2018
Conductive Molybdenum Sulfide for Efficient Electrocatalytic Hydrogen Evolution Gao, Xueqing; Qi, Jing; Wan, Shanhong Small, Vol. 14, Issue 48 https://doi.org/10.1002/smll.201803361	journal	October 2018
Aligned Heterointerface-Induced 1T-MoS ₂ Monolayer with Near-Ideal Gibbs Free for Stable Hydrogen Evolution Reaction Zhang, Kan; Jin, Bingjun; Gao, Yujie Small, Vol. 15, Issue 8 https://doi.org/10.1002/smll.201804903	journal	January 2019
Unveiling the Interfacial Effects for Enhanced Hydrogen Evolution Reaction on MoS ₂ /WTe ₂ Hybrid Structures Zhou, Yu; Pondick, Joshua V.; Silva, Jose Luis Small, Vol. 15, Issue 19 https://doi.org/10.1002/smll.201900078	journal	April 2019
Superior Hydrogen Evolution Reaction Performance in 2H‐MoS ₂ to that of 1T Phase Zhang, Wencui; Liao, Xiaobin; Pan, Xuelei Small, Vol. 15, Issue 31 https://doi.org/10.1002/smll.201900964	journal	June 2019
Dual‐Additive Assisted Chemical Vapor Deposition for the Growth of Mn‐Doped 2D MoS ₂ with Tunable Electronic Properties Cai, Zhengyang; Shen, Tianze; Zhu, Qi Small, Vol. 16, Issue 15 https://doi.org/10.1002/smll.201903181	journal	October 2019
Extending the Colloidal Transition Metal Dichalcogenide Library to ReS ₂ Nanosheets for Application in Gas Sensing and Electrocatalysis Martín‐García, Beatriz; Spirito, Davide; Bellani, Sebastiano Small, Vol. 15, Issue 52 https://doi.org/10.1002/smll.201904670	journal	December 2019
Rational Design of Transition Metal-Based Materials for Highly Efficient Electrocatalysis Dou, Shuo; Wang, Xin; Wang, Shuangyin Small Methods, Vol. 3, Issue 1 https://doi.org/10.1002/smtd.201800211	journal	September 2018
Earth Abundant Electrocatalyst Majhi, Kartick Chandra; Karfa, Paramita; Madhuri, Rashmi Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 1-28 https://doi.org/10.1007/978-3-030-27161-9_1	book	January 2020
State-of-the-Art Advances and Perspectives for Electrocatalysis Ramohlola, Kabelo E.; Hato, Mpitloane J.; Monama, Gobeng R. Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 311-352 https://doi.org/10.1007/978-3-030-27161-9_13	book	January 2020
Two-Dimensional Transition Metal Dichalcogenides: An Overview Liang, Tao; Cai, Yu; Chen, Hongzheng Two Dimensional Transition Metal Dichalcogenides https://doi.org/10.1007/978-981-13-9045-6_1	book	January 2019
Tuning oxygen vacancies in two-dimensional iron-cobalt oxide nanosheets through hydrogenation for enhanced oxygen evolution activity Zhuang, Linzhou; Jia, Yi; He, Tianwei Nano Research, Vol. 11, Issue 6 https://doi.org/10.1007/s12274-018-2050-8	journal	May 2018
Defect engineering of molybdenum disulfide through ion irradiation to boost hydrogen evolution reaction performance Sun, Cheng; Wang, Peipei; Wang, Hao Nano Research, Vol. 12, Issue 7 https://doi.org/10.1007/s12274-019-2400-1	journal	April 2019
Amorphous MoS2 confined in nitrogen-doped porous carbon for improved electrocatalytic stability toward hydrogen evolution reaction Lu, Shaojie; Wang, Wenjing; Yang, Shengshuang Nano Research, Vol. 12, Issue 12 https://doi.org/10.1007/s12274-019-2563-9	journal	November 2019
Few-layered ReS2 nanosheets grown on graphene as electrocatalyst for hydrogen evolution reaction Gao, Han; Yue, Hu-Hu; Qi, Fei Rare Metals, Vol. 37, Issue 12 https://doi.org/10.1007/s12598-018-1121-z	journal	September 2018
Efficient Mechanochemical Preparation of Graphene-Like Molybdenum Disulfide and Graphene-Based Composite Electrocatalysts for Hydrogen Evolution Reaction Posudievsky, Oleg Yu.; Kozarenko, Olga A.; Dyadyun, Vyacheslav S. Electrocatalysis, Vol. 10, Issue 5 https://doi.org/10.1007/s12678-019-00532-7	journal	April 2019
Structure design of CeO2–MoS2 composites and their efficient activity for imine synthesis Chen, Ling-Yan; Xu, Fang-Fang; Zhang, Jingjin Applied Nanoscience, Vol. 10, Issue 1 https://doi.org/10.1007/s13204-019-01114-1	journal	July 2019
Defective MoS2 electrocatalyst for highly efficient hydrogen evolution through a simple ball-milling method Zhang, Li-Fang; Ke, Xiaoxing; Ou, Gang Science China Materials, Vol. 60, Issue 9 https://doi.org/10.1007/s40843-017-9086-9	journal	September 2017
Three dimensional carbon substrate materials for electrolysis of water Zhang, Xinglin; Shao, Jinjun; Huang, Wei Science China Materials, Vol. 61, Issue 9 https://doi.org/10.1007/s40843-018-9295-8	journal	June 2018
Engineering Two-Dimensional Materials and Their Heterostructures as High-Performance Electrocatalysts Yu, Qiangmin; Luo, Yuting; Mahmood, Azhar Electrochemical Energy Reviews, Vol. 2, Issue 3 https://doi.org/10.1007/s41918-019-00045-3	journal	May 2019
Engineering surface atomic structure of single-crystal cobalt (II) oxide nanorods for superior electrocatalysis Ling, Tao; Yan, Dong-Yang; Jiao, Yan Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12876	journal	September 2016
Multiscale structural and electronic control of molybdenum disulfide foam for highly efficient hydrogen production Deng, Jiao; Li, Haobo; Wang, Suheng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14430	journal	April 2017
Two-dimensional Mo1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering Tao, Quanzheng; Dahlqvist, Martin; Lu, Jun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14949	journal	April 2017
Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution Tsai, Charlie; Li, Hong; Park, Sangwook Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15113	journal	April 2017
Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics Zhang, Jian; Wang, Tao; Liu, Pan Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15437	journal	May 2017
Erratum: Corrigendum: Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies Li, Hong; Tsai, Charlie; Koh, Ai Leen Nature Materials, Vol. 15, Issue 3 https://doi.org/10.1038/nmat4564	journal	February 2016
Coordination polymer structure and revisited hydrogen evolution catalytic mechanism for amorphous molybdenum sulfide Tran, Phong D.; Tran, Thu V.; Orio, Maylis Nature Materials, Vol. 15, Issue 6 https://doi.org/10.1038/nmat4588	journal	March 2016
The role of electronic coupling between substrate and 2D MoS2 nanosheets in electrocatalytic production of hydrogen Voiry, Damien; Fullon, Raymond; Yang, Jieun Nature Materials, Vol. 15, Issue 9 https://doi.org/10.1038/nmat4660	journal	June 2016
Degradation behaviors and mechanisms of MoS2 crystals relevant to bioabsorbable electronics Chen, Xiang; Shinde, Sachin M.; Dhakal, Krishna P. NPG Asia Materials, Vol. 10, Issue 8 https://doi.org/10.1038/s41427-018-0078-6	journal	August 2018
Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering Ling, Tao; Yan, Dong-Yang; Wang, Hui Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01872-y	journal	November 2017
Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles Neagu, Dragos; Papaioannou, Evangelos I.; Ramli, Wan K. W. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01880-y	journal	November 2017
Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting Fan, Xiujun; Liu, Yuanyue; Chen, Shuai Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04248-y	journal	May 2018
Photoinduced semiconductor-metal transition in ultrathin troilite FeS nanosheets to trigger efficient hydrogen evolution Zhou, Gang; Shan, Yun; Wang, Longlu Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08358-z	journal	January 2019
Boundary activated hydrogen evolution reaction on monolayer MoS2 Zhu, Jianqi; Wang, Zhi-Chang; Dai, Huijia Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09269-9	journal	March 2019
Unconventional CN vacancies suppress iron-leaching in Prussian blue analogue pre-catalyst for boosted oxygen evolution catalysis Yu, Zi-You; Duan, Yu; Liu, Jian-Dang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10698-9	journal	June 2019
Identifying substitutional oxygen as a prolific point defect in monolayer transition metal dichalcogenides Barja, Sara; Refaely-Abramson, Sivan; Schuler, Bruno Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11342-2	journal	July 2019
Balancing hydrogen adsorption/desorption by orbital modulation for efficient hydrogen evolution catalysis Li, Feng; Han, Gao-Feng; Noh, Hyuk-Jun Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12012-z	journal	September 2019
The rapid electrochemical activation of MoTe2 for the hydrogen evolution reaction McGlynn, Jessica C.; Dankwort, Torben; Kienle, Lorenz Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12831-0	journal	October 2019
Polymorphic cobalt diselenide as extremely stable electrocatalyst in acidic media via a phase-mixing strategy Zhang, Xiao-Long; Hu, Shao-Jin; Zheng, Ya-Rong Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12992-y	journal	November 2019
Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide Suryanto, Bryan H. R.; Wang, Yun; Hocking, Rosalie K. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13415-8	journal	December 2019
Engineering grain boundaries at the 2D limit for the hydrogen evolution reaction He, Yongmin; Tang, Pengyi; Hu, Zhili Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13631-2	journal	January 2020
Strain-driven growth of ultra-long two-dimensional nano-channels Zhu, Chao; Yu, Maolin; Zhou, Jiadong Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14521-8	journal	February 2020
Asymmetric MXene/monolayer transition metal dichalcogenide heterostructures for functional applications Li, Baihai; Guo, Haoran; Wang, Yunrui npj Computational Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41524-019-0155-6	journal	February 2019
Spontaneous doping of the basal plane of MoS2 single layers through oxygen substitution under ambient conditions Pető, János; Ollár, Tamás; Vancsó, Péter Nature Chemistry, Vol. 10, Issue 12 https://doi.org/10.1038/s41557-018-0136-2	journal	September 2018
Hydrogen to the rescue No authors listed Nature Materials, Vol. 17, Issue 7, p. 565-565 https://doi.org/10.1038/s41563-018-0129-y	journal	June 2018
Ultrahigh-current-density niobium disulfide catalysts for hydrogen evolution Yang, Jieun; Mohmad, Abdul Rahman; Wang, Yan Nature Materials, Vol. 18, Issue 12 https://doi.org/10.1038/s41563-019-0463-8	journal	August 2019
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting Roger, Isolda; Shipman, Michael A.; Symes, Mark D. Nature Reviews Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/s41570-016-0003	journal	January 2017
Low-dimensional catalysts for hydrogen evolution and CO2 reduction Voiry, Damien; Shin, Hyeon Suk; Loh, Kian Ping Nature Reviews Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s41570-017-0105	journal	January 2018
Theory-guided design of catalytic materials using scaling relationships and reactivity descriptors Zhao, Zhi-Jian; Liu, Sihang; Zha, Shenjun Nature Reviews Materials, Vol. 4, Issue 12 https://doi.org/10.1038/s41578-019-0152-x	journal	November 2019
In-situ visualization of hydrogen evolution sites on helium ion treated molybdenum dichalcogenides under reaction conditions Mitterreiter, Elmar; Liang, Yunchang; Golibrzuch, Matthias npj 2D Materials and Applications, Vol. 3, Issue 1 https://doi.org/10.1038/s41699-019-0107-5	journal	July 2019
Lithiation-induced amorphization of Pd3P2S8 for highly efficient hydrogen evolution Zhang, Xiao; Luo, Zhimin; Yu, Peng Nature Catalysis, Vol. 1, Issue 6 https://doi.org/10.1038/s41929-018-0072-y	journal	May 2018
Atomic-layer soft plasma etching of MoS2 Xiao, Shaoqing; Xiao, Peng; Zhang, Xuecheng Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19945	journal	January 2016
One-Step Hydrothermal Fabrication of Three-dimensional MoS2 Nanoflower using Polypyrrole as Template for Efficient Hydrogen Evolution Reaction Lu, Xin; Lin, Yingwu; Dong, Haifeng Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep42309	journal	February 2017
Metal-free carbonaceous electrocatalysts and photocatalysts for water splitting Xu, You; Kraft, Markus; Xu, Rong Chemical Society Reviews, Vol. 45, Issue 11 https://doi.org/10.1039/c5cs00729a	journal	January 2016
In-plane interfacing effects of two-dimensional transition-metal dichalcogenide heterostructures Wei, Wei; Dai, Ying; Huang, Baibiao Physical Chemistry Chemical Physics, Vol. 18, Issue 23 https://doi.org/10.1039/c6cp02741e	journal	January 2016
Vacancies in functional materials for clean energy storage and harvesting: the perfect imperfection Li, Guowei; Blake, Graeme R.; Palstra, Thomas T. M. Chemical Society Reviews, Vol. 46, Issue 6 https://doi.org/10.1039/c6cs00571c	journal	January 2017
Design, synthesis, and energy-related applications of metal sulfides Liu, Yongchang; Li, Yang; Kang, Hongyan Materials Horizons, Vol. 3, Issue 5 https://doi.org/10.1039/c6mh00075d	journal	January 2016
p-Type transition-metal doping of large-area MoS ₂ thin films grown by chemical vapor deposition Xu, E. Z.; Liu, H. M.; Park, K. Nanoscale, Vol. 9, Issue 10 https://doi.org/10.1039/c6nr09495c	journal	January 2017
Nanostructured catalysts for electrochemical water splitting: current state and prospects Li, Xiumin; Hao, Xiaogang; Abudula, Abuliti Journal of Materials Chemistry A, Vol. 4, Issue 31 https://doi.org/10.1039/c6ta02334g	journal	January 2016
Salt-template-assisted synthesis of robust 3D honeycomb-like structured MoS ₂ and its application as a lithium-ion battery anode Zhou, Jingwen; Qin, Jian; Zhao, Naiqin Journal of Materials Chemistry A, Vol. 4, Issue 22 https://doi.org/10.1039/c6ta02565j	journal	January 2016
Three-dimensional carbon foam/N-doped graphene@MoS ₂ hybrid nanostructures as effective electrocatalysts for the hydrogen evolution reaction Park, Seung-Keun; Chung, Dong Young; Ko, Dongjin Journal of Materials Chemistry A, Vol. 4, Issue 33 https://doi.org/10.1039/c6ta03458f	journal	January 2016
Molybdenum disulfide and Au ultrasmall nanohybrids as highly active electrocatalysts for hydrogen evolution reaction Zhang, Jinxuan; Wang, Tanyuan; Liu, Lu Journal of Materials Chemistry A, Vol. 5, Issue 8 https://doi.org/10.1039/c6ta10385e	journal	January 2017
Atomic layer deposited molybdenum disulfide on Si photocathodes for highly efficient photoelectrochemical water reduction reaction Oh, Seungtaeg; Kim, Jun Beom; Song, Jun Tae Journal of Materials Chemistry A, Vol. 5, Issue 7 https://doi.org/10.1039/c6ta10707a	journal	January 2017
Single-layer MoS ₂ formation by sulfidation of molybdenum oxides in different oxidation states on Au(111) Salazar, Norberto; Beinik, Igor; Lauritsen, Jeppe V. Physical Chemistry Chemical Physics, Vol. 19, Issue 21 https://doi.org/10.1039/c7cp00958e	journal	January 2017
Tuning the activity of the inert MoS ₂ surface via graphene oxide support doping towards chemical functionalization and hydrogen evolution: a density functional study Tang, Shaobin; Wu, Weihua; Zhang, Shiyong Physical Chemistry Chemical Physics, Vol. 20, Issue 3 https://doi.org/10.1039/c7cp06636h	journal	January 2018
TMD-based highly efficient electrocatalysts developed by combined computational and experimental approaches Zhu, Changrong (Rose); Gao, Daqiang; Ding, Jun Chemical Society Reviews, Vol. 47, Issue 12 https://doi.org/10.1039/c7cs00705a	journal	January 2018
Phosphorus-Mo ₂ C@carbon nanowires toward efficient electrochemical hydrogen evolution: composition, structural and electronic regulation Shi, Zhangping; Nie, Kaiqi; Shao, Zheng-Jiang Energy & Environmental Science, Vol. 10, Issue 5 https://doi.org/10.1039/c7ee00388a	journal	January 2017
An experimental and theoretical study of an efficient polymer nano-photocatalyst for hydrogen evolution Pati, Palas Baran; Damas, Giane; Tian, Lei Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/c7ee00751e	journal	January 2017
Electrocatalysis of polysulfide conversion by sulfur-deficient MoS ₂ nanoflakes for lithium–sulfur batteries Lin, Haibin; Yang, Liuqing; Jiang, Xi Energy & Environmental Science, Vol. 10, Issue 6 https://doi.org/10.1039/c7ee01047h	journal	January 2017
MoS ₂ /TiO ₂ heterostructures as nonmetal plasmonic photocatalysts for highly efficient hydrogen evolution Guo, L.; Yang, Z.; Marcus, K. Energy & Environmental Science, Vol. 11, Issue 1 https://doi.org/10.1039/c7ee02464a	journal	January 2018
Group 6 transition metal dichalcogenide nanomaterials: synthesis, applications and future perspectives Samadi, Morasae; Sarikhani, Navid; Zirak, Mohammad Nanoscale Horizons, Vol. 3, Issue 2 https://doi.org/10.1039/c7nh00137a	journal	January 2018
Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting Chaudhari, Nitin K.; Jin, Haneul; Kim, Byeongyoon Nanoscale, Vol. 9, Issue 34 https://doi.org/10.1039/c7nr04187j	journal	January 2017
Preferential horizontal growth of tungsten sulfide on carbon and insight into active sulfur sites for the hydrogen evolution reaction Seo, Bora; Jung, Gwan Yeong; Kim, Jae Hyung Nanoscale, Vol. 10, Issue 8 https://doi.org/10.1039/c7nr08161h	journal	January 2018
A vacancy-driven phase transition in MoX ₂ (X: S, Se and Te) nanoscrolls Hwang, Da Young; Choi, Kyoung Hwan; Suh, Dong Hack Nanoscale, Vol. 10, Issue 17 https://doi.org/10.1039/c7nr08634b	journal	January 2018
Magnetism in monolayer 1T-MoS ₂ and 1T-MoS ₂ H tuned by strain Xu, Wei; Yan, Shiming; Qiao, Wen RSC Advances, Vol. 8, Issue 15 https://doi.org/10.1039/c7ra10304b	journal	January 2018
Electrochemical maps and movies of the hydrogen evolution reaction on natural crystals of molybdenite (MoS ₂ ): basal vs. edge plane activity Bentley, Cameron L.; Kang, Minkyung; Maddar, Faduma M. Chemical Science, Vol. 8, Issue 9 https://doi.org/10.1039/c7sc02545a	journal	January 2017
Molybdenum diboride nanoparticles as a highly efficient electrocatalyst for the hydrogen evolution reaction Jothi, Palani R.; Zhang, Yuemei; Scheifers, Jan P. Sustainable Energy & Fuels, Vol. 1, Issue 9 https://doi.org/10.1039/c7se00397h	journal	January 2017
Hydrogen evolution electrocatalysis with binary-nonmetal transition metal compounds Hu, Jue; Zhang, Chengxu; Meng, Xiangyue Journal of Materials Chemistry A, Vol. 5, Issue 13 https://doi.org/10.1039/c7ta00743d	journal	January 2017
Emerging two-dimensional nanomaterials for electrochemical hydrogen evolution Chen, Yunxu; Yang, Kena; Jiang, Bei Journal of Materials Chemistry A, Vol. 5, Issue 18 https://doi.org/10.1039/c7ta00816c	journal	January 2017
Three electron channels toward two types of active sites in MoS ₂ @Pt nanosheets for hydrogen evolution Xu, X. Y.; Dong, X. F.; Bao, Z. J. Journal of Materials Chemistry A, Vol. 5, Issue 43 https://doi.org/10.1039/c7ta07241d	journal	January 2017
Highly active two dimensional α-MoO _3−x for the electrocatalytic hydrogen evolution reaction Datta, R. S.; Haque, F.; Mohiuddin, M. Journal of Materials Chemistry A, Vol. 5, Issue 46 https://doi.org/10.1039/c7ta07705j	journal	January 2017
Understanding the high-electrocatalytic performance of two-dimensional MoS ₂ nanosheets and their composite materials Jayabal, Subramaniam; Saranya, Govindarajan; Wu, Jian Journal of Materials Chemistry A, Vol. 5, Issue 47 https://doi.org/10.1039/c7ta08327k	journal	January 2017
Molybdenum sulfide clusters immobilized on defective graphene: a stable catalyst for the hydrogen evolution reaction Ouyang, Yixin; Li, Qiang; Shi, Li Journal of Materials Chemistry A, Vol. 6, Issue 5 https://doi.org/10.1039/c7ta09828f	journal	January 2018
Mutually beneficial Co ₃ O ₄ @MoS ₂ heterostructures as a highly efficient bifunctional catalyst for electrochemical overall water splitting Liu, Jia; Wang, Jinsong; Zhang, Bao Journal of Materials Chemistry A, Vol. 6, Issue 5 https://doi.org/10.1039/c7ta10048e	journal	January 2018
Non-equilibrium fractal growth of MoS ₂ for electrocatalytic hydrogen evolution Park, Taejin; Bae, Changdeuck; Lee, Hyangsook CrystEngComm, Vol. 21, Issue 3 https://doi.org/10.1039/c8ce01952e	journal	January 2019
Repairing single and double atomic vacancies in a C ₃ N monolayer with CO or NO molecules: a first-principles study Ma, Dongwei; Zhang, Jing; Tang, Yanan Physical Chemistry Chemical Physics, Vol. 20, Issue 19 https://doi.org/10.1039/c8cp01653d	journal	January 2018
Electronic-dimensionality reduction of bulk MoS ₂ by hydrogen treatment Cho, Soohyun; Kim, Beom Seo; Kim, Beomyoung Physical Chemistry Chemical Physics, Vol. 20, Issue 35 https://doi.org/10.1039/c8cp02365d	journal	January 2018
Preparation of 2D material dispersions and their applications Cai, Xingke; Luo, Yuting; Liu, Bilu Chemical Society Reviews, Vol. 47, Issue 16 https://doi.org/10.1039/c8cs00254a	journal	January 2018
Rapid flame doping of Co to WS ₂ for efficient hydrogen evolution Shi, Xinjian; Fields, Meredith; Park, Joonsuk Energy & Environmental Science, Vol. 11, Issue 8 https://doi.org/10.1039/c8ee01111g	journal	January 2018
Enhancing the activity of oxygen-evolution and chlorine-evolution electrocatalysts by atomic layer deposition of TiO ₂ Finke, Cody E.; Omelchenko, Stefan T.; Jasper, Justin T. Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/c8ee02351d	journal	January 2019
Pulsed laser deposition of single-layer MoS ₂ on Au(111): from nanosized crystals to large-area films Tumino, Francesco; Casari, Carlo S.; Passoni, Matteo Nanoscale Advances, Vol. 1, Issue 2 https://doi.org/10.1039/c8na00126j	journal	January 2019
Sulfur-doped graphene/transition metal dichalcogenide heterostructured hybrids with electrocatalytic activity toward the hydrogen evolution reaction Kagkoura, Antonia; Pelaez-Fernandez, Mario; Arenal, Raul Nanoscale Advances, Vol. 1, Issue 4 https://doi.org/10.1039/c8na00130h	journal	January 2019
Nanoscale mapping of hydrogen evolution on metallic and semiconducting MoS ₂ nanosheets Sun, Tong; Zhang, Hanyu; Wang, Xiang Nanoscale Horizons, Vol. 4, Issue 3 https://doi.org/10.1039/c8nh00346g	journal	January 2019
Oxygen incorporated WS ₂ nanoclusters with superior electrocatalytic properties for hydrogen evolution reaction Sarma, Prasad V.; Tiwary, Chandra Sekhar; Radhakrishnan, Sruthi Nanoscale, Vol. 10, Issue 20 https://doi.org/10.1039/c8nr00253c	journal	January 2018
Large-scale controlled synthesis of porous two-dimensional nanosheets for the hydrogen evolution reaction through a chemical pathway Cui, Zheng; Chu, Hang; Gao, Shangpeng Nanoscale, Vol. 10, Issue 13 https://doi.org/10.1039/c8nr01182f	journal	January 2018
Intercalation of aromatic amine for the 2H–1T′ phase transition of MoS ₂ by experiments and calculations Kwon, Ik Seon; Kwak, In Hye; Abbas, Hafiz Ghulam Nanoscale, Vol. 10, Issue 24 https://doi.org/10.1039/c8nr02365d	journal	January 2018
A porous nickel cyclotetraphosphate nanosheet as a new acid-stable electrocatalyst for efficient hydrogen evolution Liu, Xiong; Wen, Bo; Guo, Ruiting Nanoscale, Vol. 10, Issue 21 https://doi.org/10.1039/c8nr02436g	journal	January 2018
PbTe quantum dots as electron transfer intermediates for the enhanced hydrogen evolution reaction of amorphous MoS _x /TiO ₂ nanotube arrays Gao, Shiyuan; Wang, Bin; Liu, Xinyu Nanoscale, Vol. 10, Issue 21 https://doi.org/10.1039/c8nr02532k	journal	January 2018
Uniform small-sized MoS ₂ from novel solution-based microwave-assisted method with exceptional reversible lithium storage properties Tian, Xuehui; Gao, Qiuming; Zhang, Hang Nanoscale, Vol. 10, Issue 32 https://doi.org/10.1039/c8nr02833h	journal	January 2018
Nitrogen-rich 1T′-MoS ₂ layered nanostructures using alkyl amines for high catalytic performance toward hydrogen evolution Kwak, In Hye; Kwon, Ik Seon; Abbas, Hafiz Ghulam Nanoscale, Vol. 10, Issue 30 https://doi.org/10.1039/c8nr03661f	journal	January 2018
Highly active single-layer MoS ₂ catalysts synthesized by swift heavy ion irradiation Madauß, Lukas; Zegkinoglou, Ioannis; Vázquez Muiños, Henrique Nanoscale, Vol. 10, Issue 48 https://doi.org/10.1039/c8nr04696d	journal	January 2018
Rational inert-basal-plane activating design of ultrathin 1T′ phase MoS ₂ with a MoO ₃ heterostructure for enhancing hydrogen evolution performances Xue, Xiaoyi; Zhang, Jianan; Saana, Ibrahim Amiinu Nanoscale, Vol. 10, Issue 35 https://doi.org/10.1039/c8nr05270k	journal	January 2018
Influence of the support on stabilizing local defects in strained monolayer oxide films Wang, Shuqiu; Hu, Xiao; Goniakowski, Jacek Nanoscale, Vol. 11, Issue 5 https://doi.org/10.1039/c8nr08606k	journal	January 2019
Enhancing charge transfer with foreign molecules through femtosecond laser induced MoS ₂ defect sites for photoluminescence control and SERS enhancement Zuo, Pei; Jiang, Lan; Li, Xin Nanoscale, Vol. 11, Issue 2 https://doi.org/10.1039/c8nr08785g	journal	January 2019
The atomic origin of nickel-doping-induced catalytic enhancement in MoS ₂ for electrochemical hydrogen production Luo, Ruichun; Luo, Min; Wang, Ziqian Nanoscale, Vol. 11, Issue 15 https://doi.org/10.1039/c8nr10023c	journal	January 2019
Synthesis of dense MoS ₂ nanosheet layers on hollow carbon spheres and their applications in supercapacitors and the electrochemical hydrogen evolution reaction Liu, Weiwei; Zhu, Menghua; Liu, Jinghua Inorganic Chemistry Frontiers, Vol. 5, Issue 9 https://doi.org/10.1039/c8qi00562a	journal	January 2018
Ultralong needle-like N-doped Co(OH)F on carbon fiber paper with abundant oxygen vacancies as an efficient oxygen evolution reaction catalyst Lv, Jiaqi; Yang, Xiaoxuan; Zang, Hong-Ying Materials Chemistry Frontiers, Vol. 2, Issue 11 https://doi.org/10.1039/c8qm00405f	journal	January 2018
Exfoliation, point defects and hydrogen storage properties of monolayer TiS ₃ : an ab initio study Arsentev, M. Yu.; Petrov, A. V.; Missyul, A. B. RSC Advances, Vol. 8, Issue 46 https://doi.org/10.1039/c8ra04417a	journal	January 2018
Carbon nanotube-induced phase and stability engineering: a strained cobalt-doped WSe ₂ /MWNT heterostructure for enhanced hydrogen evolution reaction Zhang, Guoyuan; Zheng, Xiaoli; Xu, Qun Journal of Materials Chemistry A, Vol. 6, Issue 11 https://doi.org/10.1039/c8ta00163d	journal	January 2018
A metallic MoS ₂ nanosheet array on graphene-protected Ni foam as a highly efficient electrocatalytic hydrogen evolution cathode Zhu, Peng; Chen, Yu; Zhou, Yu Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/c8ta02835d	journal	January 2018
Synergistic modulation in MX ₂ (where M = Mo or W or V, and X = S or Se) for an enhanced hydrogen evolution reaction Wang, Ran; Han, Jiecai; Zhang, Xinghong Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta05912h	journal	January 2018
Molybdenum carbide nanoparticle decorated hierarchical tubular carbon superstructures with vertical nanosheet arrays for efficient hydrogen evolution Xu, Zhixiao; Zhang, Guangfeng; Lu, Chenbao Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/c8ta06278a	journal	January 2018
Recent advances in nanostructured metal nitrides for water splitting Han, Ning; Liu, Pengyun; Jiang, Jing Journal of Materials Chemistry A, Vol. 6, Issue 41 https://doi.org/10.1039/c8ta06529b	journal	January 2018
Strongly enhanced visible light photoelectrocatalytic hydrogen evolution reaction in an n-doped MoS ₂ /TiO ₂ (B) heterojunction by selective decoration of platinum nanoparticles at the MoS ₂ edge sites Paul, Kamal Kumar; Sreekanth, N.; Biroju, Ravi K. Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta06783j	journal	January 2018
Electrochemical activity of 1T′ structured rhenium selenide nanosheets via electronic structural modulation from selenium-vacancy generation Sun, Yuan; Meng, Jie; Ju, Huanxin Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta06889e	journal	January 2018
Tuning the catalytic activity of heterogeneous two-dimensional transition metal dichalcogenides for hydrogen evolution Noh, Seung Hyo; Hwang, Jeemin; Kang, Joonhee Journal of Materials Chemistry A, Vol. 6, Issue 41 https://doi.org/10.1039/c8ta07141a	journal	January 2018
Transition metal modification and carbon vacancy promoted Cr ₂ CO ₂ (MXenes): a new opportunity for a highly active catalyst for the hydrogen evolution reaction Cheng, Yu-Wen; Dai, Jian-Hong; Zhang, Yu-Min Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/c8ta07749e	journal	January 2018
Arising synergetic and antagonistic effects in the design of Ni- and Ru-based water splitting electrocatalysts Marques Mota, Filipe; Choi, Chi Hun; Boppella, Ramireddy Journal of Materials Chemistry A, Vol. 7, Issue 2 https://doi.org/10.1039/c8ta08535h	journal	January 2019
Two-dimensional materials as catalysts for solar fuels: hydrogen evolution reaction and CO ₂ reduction Hasani, Amirhossein; Tekalgne, Mahider; Le, Quyet Van Journal of Materials Chemistry A, Vol. 7, Issue 2 https://doi.org/10.1039/c8ta09496a	journal	January 2019
Intercalated complexes of 1T′-MoS ₂ nanosheets with alkylated phenylenediamines as excellent catalysts for electrochemical hydrogen evolution Kwak, In Hye; Kwon, Ik Seon; Abbas, Hafiz Ghulam Journal of Materials Chemistry A, Vol. 7, Issue 5 https://doi.org/10.1039/c8ta11085a	journal	January 2019
Atomic (single, double, and triple atoms) catalysis: frontiers, opportunities, and challenges Chen, Z. W.; Chen, L. X.; Yang, C. C. Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta11416a	journal	January 2019
A computational study on Pt and Ru dimers supported on graphene for the hydrogen evolution reaction: new insight into the alkaline mechanism Liu, Xin; Jiao, Yan; Zheng, Yao Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta11626a	journal	January 2019
Proposal of a stable B ₃ S nanosheet as an efficient hydrogen evolution catalyst Wu, Hong; Li, Xingxing; Zhang, Ruiqi Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta11797g	journal	January 2019
Facile microwave assisted synthesis of vastly edge exposed 1T/2H-MoS ₂ with enhanced activity for hydrogen evolution catalysis Lee, Young Bum; Kim, Seong K.; Ji, Seulgi Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta12080c	journal	January 2019
Anionic defect engineering of transition metal oxides for oxygen reduction and evolution reactions Zhu, Yunmin; Liu, Xi; Jin, Shiguang Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/c8ta12477a	journal	January 2019
Optimizing the surface state of cobalt-iron bimetallic phosphide via regulating phosphorus vacancies Li, Shuang; Geng, Zhibin; Wang, Xiyang Chemical Communications, Vol. 56, Issue 17 https://doi.org/10.1039/c9cc09741d	journal	January 2020
Vacancy-engineered catalysts for water electrolysis Choi, Songa; Park, Yeji; Yang, Heesu CrystEngComm, Vol. 22, Issue 9 https://doi.org/10.1039/c9ce01883b	journal	January 2020
Enhancing the electrocatalytic activity of 2H-WS ₂ for hydrogen evolution via defect engineering Wu, Longfei; van Hoof, Arno J. F.; Dzade, Nelson Y. Physical Chemistry Chemical Physics, Vol. 21, Issue 11 https://doi.org/10.1039/c9cp00722a	journal	January 2019
Hydrogen interaction with a sulfur-vacancy-induced occupied defect state in the electronic band structure of MoS ₂ Han, Sang Wook; Cha, Gi-Beom; Kim, Kyoo Physical Chemistry Chemical Physics, Vol. 21, Issue 28 https://doi.org/10.1039/c9cp01030k	journal	January 2019
Understanding electro-catalysis by using density functional theory Chen, Z. W.; Chen, L. X.; Wen, Z. Physical Chemistry Chemical Physics, Vol. 21, Issue 43 https://doi.org/10.1039/c9cp04430b	journal	January 2019
Probing the active sites of newly predicted stable Janus scandium dichalcogenides for photocatalytic water-splitting Yang, Xiaoyong; Banerjee, Amitava; Ahuja, Rajeev Catalysis Science & Technology, Vol. 9, Issue 18 https://doi.org/10.1039/c9cy01014a	journal	January 2019
Surface intercalated spherical MoS _2x Se _2(1−x) nanocatalysts for highly efficient and durable hydrogen evolution reactions Lin, Bo; Lin, Zhiping; Chen, Shougang Dalton Transactions, Vol. 48, Issue 23 https://doi.org/10.1039/c9dt01218d	journal	January 2019
Unique interfacial thermodynamics of few-layer 2D MoS ₂ for (photo)electrochemical catalysis Carroll, Gerard Michael; Zhang, Hanyu; Dunklin, Jeremy R. Energy & Environmental Science, Vol. 12, Issue 5 https://doi.org/10.1039/c9ee00513g	journal	January 2019
Metal boride better than Pt: HCP Pd ₂ B as a superactive hydrogen evolution reaction catalyst Chen, Lin; Zhang, Ling-Ran; Yao, Ling-Yan Energy & Environmental Science, Vol. 12, Issue 10 https://doi.org/10.1039/c9ee01564g	journal	January 2019
First-principles and experimental investigation of carbon-coated MoS ₂ hollow nanosphere heterogeneous structures with enhanced hydrogen evolution performance Ren, Jie; Wang, Zhenguo; Feng, Yu New Journal of Chemistry, Vol. 43, Issue 44 https://doi.org/10.1039/c9nj04607k	journal	January 2019
Transition metal doping activated basal-plane catalytic activity of two-dimensional 1T’-ReS ₂ for hydrogen evolution reaction: a first-principles calculation study Pan, Jing; Wang, Rui; Xu, Xiaoyong Nanoscale, Vol. 11, Issue 21 https://doi.org/10.1039/c9nr00997c	journal	January 2019
N-Doped amorphous MoS _x for the hydrogen evolution reaction Ding, Ruimin; Wang, Mengchao; Wang, Xianfen Nanoscale, Vol. 11, Issue 23 https://doi.org/10.1039/c9nr02717c	journal	January 2019
Spontaneous full photocatalytic water splitting on 2D MoSe ₂ /SnSe ₂ and WSe ₂ /SnSe ₂ vdW heterostructures Fan, Yingcai; Wang, Junru; Zhao, Mingwen Nanoscale, Vol. 11, Issue 31 https://doi.org/10.1039/c9nr03469b	journal	January 2019
Boosting the electrocatalytic activity of amorphous molybdenum sulfide nanoflakes via nickel sulfide decoration Zheng, Zheng; Su, Tong; Shi, Jianping Nanoscale, Vol. 11, Issue 47 https://doi.org/10.1039/c9nr05916d	journal	January 2019
Strain and defect engineered monolayer Ni-MoS ₂ for pH-universal hydrogen evolution catalysis Liang, Dan; Zhang, Yong-Wei; Lu, Pengfei Nanoscale, Vol. 11, Issue 39 https://doi.org/10.1039/c9nr06541e	journal	January 2019
Recent progress of TMD nanomaterials: phase transitions and applications Huang, H. H.; Fan, Xiaofeng; Singh, David J. Nanoscale, Vol. 12, Issue 3 https://doi.org/10.1039/c9nr08313h	journal	January 2020
Active site manipulation in MoS ₂ cluster electrocatalysts by transition metal doping Humphrey, Jo J. L.; Kronberg, Rasmus; Cai, Rongsheng Nanoscale, Vol. 12, Issue 7 https://doi.org/10.1039/c9nr10702a	journal	January 2020
Toward heterostructured transition metal hybrids with highly promoted electrochemical hydrogen evolution Gao, Guanhui; Xie, Xiaobin; Kang, Shendong RSC Advances, Vol. 9, Issue 35 https://doi.org/10.1039/c9ra02673h	journal	January 2019
NO reduction over an Al-embedded MoS ₂ monolayer: a first-principles study Esrafili, Mehdi D.; Heydari, Safa RSC Advances, Vol. 9, Issue 67 https://doi.org/10.1039/c9ra05759e	journal	January 2019
Layer dependence of the photoelectrochemical performance of a WSe ₂ photocathode characterized using in situ microscale measurements Zhang, Yu; Xiao, Jingwei; Xie, Xi RSC Advances, Vol. 9, Issue 53 https://doi.org/10.1039/c9ra06297a	journal	January 2019
Hierarchical NiCo ₂ O ₄ /NiFe/Pt heterostructures supported on nickel foam as bifunctional electrocatalysts for efficient oxygen/hydrogen production Huang, Qingyou; Cao, Yang; Wang, Xiaohong RSC Advances, Vol. 9, Issue 60 https://doi.org/10.1039/c9ra07012e	journal	January 2019
Defect-mediated selective hydrogenation of nitroarenes on nanostructured WS ₂ Sun, Yifan; Darling, Albert J.; Li, Yawei Chemical Science, Vol. 10, Issue 44 https://doi.org/10.1039/c9sc03337h	journal	January 2019
An advanced and highly efficient Ce assisted NiFe-LDH electrocatalyst for overall water splitting Jadhav, Harsharaj S.; Roy, Animesh; Desalegan, Bezawit Z. Sustainable Energy & Fuels, Vol. 4, Issue 1 https://doi.org/10.1039/c9se00700h	journal	January 2020
Stringing MOF-derived nanocages: a strategy for the enhanced oxygen evolution reaction Xu, Huajie; Yang, Yiwei; Yang, Xiaoxi Journal of Materials Chemistry A, Vol. 7, Issue 14 https://doi.org/10.1039/c9ta00624a	journal	January 2019
A facile and controllable, deep eutectic solvent aided strategy for the synthesis of graphene encapsulated metal phosphides for enhanced electrocatalytic overall water splitting Mou, Hongyu; Wang, Jinfang; Yu, Dongkun Journal of Materials Chemistry A, Vol. 7, Issue 22 https://doi.org/10.1039/c9ta02304f	journal	January 2019
Building a lateral/vertical 1T-2H MoS ₂ /Au heterostructure for enhanced photoelectrocatalysis and surface enhanced Raman scattering Zheng, Xiaoli; Guo, Zhihua; Zhang, Guoyuan Journal of Materials Chemistry A, Vol. 7, Issue 34 https://doi.org/10.1039/c9ta06091j	journal	January 2019
A Co–Mo ₂ N composite on a nitrogen-doped carbon matrix with hydrogen evolution activity comparable to that of Pt/C in alkaline media Lang, Xuewei; Qadeer, Muhammad Abdul; Shen, Guoqiang Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta07749a	journal	January 2019
Activating MoS ₂ basal planes for hydrogen evolution through direct CVD morphology control Dong, Lianqing; Guo, Shaoqiang; Wang, Yuyan Journal of Materials Chemistry A, Vol. 7, Issue 48 https://doi.org/10.1039/c9ta08738a	journal	January 2019
Activated basal planes of WS ₂ by intrinsic defects as catalysts for the electrocatalytic nitrogen reduction reaction Yao, Xue; Chen, Zhiwen; Wang, Yaru Journal of Materials Chemistry A, Vol. 7, Issue 45 https://doi.org/10.1039/c9ta10050d	journal	January 2019
Temperature-regulated reversible transformation of spinel-to-oxyhydroxide active species for electrocatalytic water oxidation Zhou, Tingli; Wang, Changhong; Shi, Yanmei Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta12200a	journal	January 2020
Engineering two-dimensional metal oxides via surface functionalization for biological applications Ren, Baiyu; Wang, Yichao; Ou, Jian Zhen Journal of Materials Chemistry B, Vol. 8, Issue 6 https://doi.org/10.1039/c9tb02423a	journal	January 2020
Defect-engineered MoS ₂ with extended photoluminescence lifetime for high-performance hydrogen evolution Kang, Sangmin; Koo, Ja-Jung; Seo, Hongmin Journal of Materials Chemistry C, Vol. 7, Issue 33 https://doi.org/10.1039/c9tc02256b	journal	January 2019
Strain engineering in functional 2-dimensional materials Sun, Yufei; Liu, Kai Journal of Applied Physics, Vol. 125, Issue 8 https://doi.org/10.1063/1.5053795	journal	February 2019
Hydrogen interaction with selectively desulfurized MoS ₂ surface using Ne ⁺ sputtering Han, Sang Wook; Cha, Gi-Beom; Kang, Manil Journal of Applied Physics, Vol. 125, Issue 8 https://doi.org/10.1063/1.5079281	journal	February 2019
The development of 2D materials for electrochemical energy applications: A mechanistic approach Hynek, David J.; Pondick, Joshua V.; Cha, Judy J. APL Materials, Vol. 7, Issue 3 https://doi.org/10.1063/1.5085187	journal	March 2019
Wafer-recyclable, environment-friendly transfer printing for large-scale thin-film nanoelectronics Wie, Dae Seung; Zhang, Yue; Kim, Min Ku Proceedings of the National Academy of Sciences, Vol. 115, Issue 31 https://doi.org/10.1073/pnas.1806640115	journal	July 2018
Achieving half-metallicity in zigzag MoS ₂ nanoribbon with a sulfur vacancy by edge passivation Zhou, X. Y.; Wang, R.; Meng, L. J. Journal of Physics D: Applied Physics, Vol. 51, Issue 26 https://doi.org/10.1088/1361-6463/aac7df	journal	June 2018
Electronic structure and the hydrogen evolution reaction in layered ReS ₂ regulated by alkali-metal atom intercalation Zhou, Gan; Xiong, Tao; Shan, Yun Journal of Physics D: Applied Physics, Vol. 52, Issue 16 https://doi.org/10.1088/1361-6463/aaff47	journal	February 2019
Lateral heterostructures and one-dimensional interfaces in 2D transition metal dichalcogenides Ávalos-Ovando, O.; Mastrogiuseppe, D.; Ulloa, S. E. Journal of Physics: Condensed Matter, Vol. 31, Issue 21 https://doi.org/10.1088/1361-648X/ab0970	journal	March 2019
Forces and electronic transport in a contact formed by a graphene tip and a defective MoS ₂ monolayer: a theoretical study di Felice, D.; Dappe, Y. J.; González, C. Nanotechnology, Vol. 29, Issue 22 https://doi.org/10.1088/1361-6528/aab5fc	journal	April 2018
Synergetic photocatalytic effect between 1 T@2H-MoS ₂ and plasmon resonance induced by Ag quantum dots Liu, Haiyang; Wu, Rong; Tian, Lie Nanotechnology, Vol. 29, Issue 28 https://doi.org/10.1088/1361-6528/aabf56	journal	May 2018
Mo ₂ C/graphene heterostructures: low temperature chemical vapor deposition on liquid bimetallic Sn–Cu and hydrogen evolution reaction electrocatalytic properties Chaitoglou, Stefanos; Giannakopoulou, Tatiana; Speliotis, Thanassis Nanotechnology, Vol. 30, Issue 12 https://doi.org/10.1088/1361-6528/aaf9e8	journal	January 2019
Size-dependent optical properties of MoS ₂ nanoparticles and their photo-catalytic applications Bhattacharya, Didhiti; Mukherjee, Subhrajit; Mitra, Rajib Kumar Nanotechnology, Vol. 31, Issue 14 https://doi.org/10.1088/1361-6528/ab61ce	journal	January 2020
Mechanical instability driven self-assembly and architecturing of 2D materials Wang, Michael Cai; Leem, Juyoung; Kang, Pilgyu 2D Materials, Vol. 4, Issue 2 https://doi.org/10.1088/2053-1583/aa62e8	journal	March 2017
Single-layer 1 T ′-MoS ₂ under electron irradiation from ab initio molecular dynamics Pizzochero, Michele; Yazyev, Oleg V. 2D Materials, Vol. 5, Issue 2 https://doi.org/10.1088/2053-1583/aab279	journal	March 2018
Strain-Enhanced p Doping in Monolayer MoS 2 Choi, Minseok Physical Review Applied, Vol. 9, Issue 2 https://doi.org/10.1103/physrevapplied.9.024009	journal	February 2018
Large Spin-Orbit Splitting of Deep In-Gap Defect States of Engineered Sulfur Vacancies in Monolayer WS 2 Schuler, Bruno; Qiu, Diana Y.; Refaely-Abramson, Sivan Physical Review Letters, Vol. 123, Issue 7 https://doi.org/10.1103/physrevlett.123.076801	journal	August 2019
Substrate screening effects on the quasiparticle band gap and defect charge transition levels in MoS 2 Naik, Mit H.; Jain, Manish Physical Review Materials, Vol. 2, Issue 8 https://doi.org/10.1103/physrevmaterials.2.084002	journal	August 2018
Key role of antibonding electron transfer in bonding on solid surfaces Yu, Liping; Yan, Qimin; Ruzsinszky, Adrienn Physical Review Materials, Vol. 3, Issue 9 https://doi.org/10.1103/physrevmaterials.3.092801	journal	September 2019
Combining theory and experiment in electrocatalysis: Insights into materials design Seh, Zhi Wei; Kibsgaard, Jakob; Dickens, Colin F. Science, Vol. 355, Issue 6321 https://doi.org/10.1126/science.aad4998	journal	January 2017
Direct and continuous strain control of catalysts with tunable battery electrode materials Wang, Haotian; Xu, Shicheng; Tsai, Charlie Science, Vol. 354, Issue 6315 https://doi.org/10.1126/science.aaf7680	journal	November 2016
Synthesis of Z-scheme Mn-CdS/MoS ₂ /TiO ₂ ternary photocatalysts for high-efficiency sunlight-driven photocatalysis Feng, Hui; Zhou, Wenhua; Zhang, Xiangyang Advanced Composites Letters, Vol. 28 https://doi.org/10.1177/2633366x19895020	journal	January 2019
Two-Dimensional Material Molybdenum Disulfides as Electrocatalysts for Hydrogen Evolution Yang, Lei; Liu, Ping; Li, Jing Catalysts, Vol. 7, Issue 10 https://doi.org/10.3390/catal7100285	journal	September 2017
Atmospheric Air Plasma Treated SnS Films: An Efficient Electrocatalyst for HER Huang, Po-Chia; Brahma, Sanjaya; Liu, Po-Yen Catalysts, Vol. 8, Issue 10 https://doi.org/10.3390/catal8100462	journal	October 2018
Earth-Abundant Electrocatalysts in Proton Exchange Membrane Electrolyzers Sun, Xinwei; Xu, Kaiqi; Fleischer, Christian Catalysts, Vol. 8, Issue 12 https://doi.org/10.3390/catal8120657	journal	December 2018
Self-Assembled Monolayers of Molybdenum Sulfide Clusters on Au Electrode as Hydrogen Evolution Catalyst for Solar Water Splitting Spring, Stephanie; Shinde, Pravin S.; Fontenot, Patricia R. Inorganics, Vol. 7, Issue 6 https://doi.org/10.3390/inorganics7060079	journal	June 2019
Comparative Study of the Structure, Composition, and Electrocatalytic Performance of Hydrogen Evolution in MoSx~2+δ/Mo and MoSx~3+δ Films Obtained by Pulsed Laser Deposition Fominski, V.; Demin, M.; Fominski, D. Nanomaterials, Vol. 10, Issue 2 https://doi.org/10.3390/nano10020201	journal	January 2020
A Highly Sensitive Nonenzymatic Glucose Biosensor Based on the Regulatory Effect of Glucose on Electrochemical Behaviors of Colloidal Silver Nanoparticles on MoS2 Anderson, Kash; Poulter, Benjamin; Dudgeon, John Sensors, Vol. 17, Issue 8 https://doi.org/10.3390/s17081807	journal	August 2017
A General Method for the Synthesis of Hybrid Nanostructures Using MoSe ₂ Nanosheet-Assembled Nanospheres as Templates Han, Shikui; Zhou, Kai; Yu, Yifu Research, Vol. 2019 https://doi.org/10.34133/2019/6439734	journal	November 2019
Sensing behavior of flower-shaped MoS 2 nanoflakes: case study with methanol and xylene Barzegar, Maryam; Berahman, Masoud; Iraji zad, Azam Beilstein Journal of Nanotechnology, Vol. 9 https://doi.org/10.3762/bjnano.9.57	journal	January 2018
Post Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization Hirsch, Andreas; Hauke, Frank arXiv https://doi.org/10.48550/arxiv.1903.06460	text	January 2019
General approach for preparing sandwich-structured metal sulfide@reduced graphene oxide as highly reversible Li-ion battery anode Huang, Jiarui; Liu, Dongxu; Gu, Cuiping Taylor & Francis https://doi.org/10.6084/m9.figshare.5992918	text	January 2018
General approach for preparing sandwich-structured metal sulfide@reduced graphene oxide as highly reversible Li-ion battery anode Huang, Jiarui; Liu, Dongxu; Gu, Cuiping Taylor & Francis https://doi.org/10.6084/m9.figshare.5992918.v1	text	January 2018

Similar Records

Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution

Journal Article · Thu Apr 20 20:00:00 EDT 2017 · Nature Communications · OSTI ID:1360913

Enhancing Catalytic Activity of MoS2 Basal Plane S-Vacancy by Co Cluster Addition

Journal Article · Sun Oct 07 20:00:00 EDT 2018 · ACS Energy Letters · OSTI ID:1656475

Rational design of stable sulfur vacancies in molybdenum disulfide for hydrogen evolution

Journal Article · Fri Jan 31 19:00:00 EST 2020 · Journal of Catalysis · OSTI ID:1580683

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemical engineering
electrocatalysis
two-dimensional materials