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Title: Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

Abstract

Fluorinated carbonate solvents are pursued as liquid electrolytes for high-voltage Li-ion batteries. We report aggregation of [Li +(FEC) 3] n polymer species from fluoroethylene carbonate containing electrolytes and scrutinized the causes for this behavior.

Authors:
 [1];  [2];  [3];  [3];  [3]
  1. Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1249078
Report Number(s):
SAND-2016-1267J
Journal ID: ISSN 1463-9076; PPCPFQ; 619516
Grant/Contract Number:  
AC04-94AL85000; SC0001160; AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 18; Journal Issue: 16; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Malliakas, Christos D., Leung, Kevin, Pupek, Krzysztof Z., Shkrob, Ilya A., and Abraham, Daniel P. Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries. United States: N. p., 2016. Web. doi:10.1039/c6cp01157h.
Malliakas, Christos D., Leung, Kevin, Pupek, Krzysztof Z., Shkrob, Ilya A., & Abraham, Daniel P. Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries. United States. doi:10.1039/c6cp01157h.
Malliakas, Christos D., Leung, Kevin, Pupek, Krzysztof Z., Shkrob, Ilya A., and Abraham, Daniel P. Thu . "Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries". United States. doi:10.1039/c6cp01157h. https://www.osti.gov/servlets/purl/1249078.
@article{osti_1249078,
title = {Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries},
author = {Malliakas, Christos D. and Leung, Kevin and Pupek, Krzysztof Z. and Shkrob, Ilya A. and Abraham, Daniel P.},
abstractNote = {Fluorinated carbonate solvents are pursued as liquid electrolytes for high-voltage Li-ion batteries. We report aggregation of [Li+(FEC)3]n polymer species from fluoroethylene carbonate containing electrolytes and scrutinized the causes for this behavior.},
doi = {10.1039/c6cp01157h},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 16,
volume = 18,
place = {United States},
year = {Thu Mar 31 00:00:00 EDT 2016},
month = {Thu Mar 31 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
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Citation Metrics:
Cited by: 6 works
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Works referenced in this record:

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004