Evolution and Enabling Capabilities of Spatially Resolved Techniques for the Characterization of Heterogeneously Catalyzed Reactions

Morgan, Kevin; Touitou, Jamal; Choi, Jae-Soon; Coney, Ciarán; Hardacre, Christopher; Pihl, Josh A.; Stere, Cristina E.; Kim, Mi-Young; Stewart, Caomhán; Goguet, Alexandre; Partridge, William P.

doi:10.1021/acscatal.5b02602

Title: Evolution and Enabling Capabilities of Spatially Resolved Techniques for the Characterization of Heterogeneously Catalyzed Reactions

Journal Article · Thu Jan 28 00:00:00 EST 2016 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.5b02602· OSTI ID:1237385

Morgan, Kevin ^[1]; Touitou, Jamal ^[2]; Choi, Jae-Soon ^[3]; Coney, Ciarán ^[4]; Hardacre, Christopher ^[4]; Pihl, Josh A. ^[3]; Stere, Cristina E. ^[4]; Kim, Mi-Young ^[3]; Stewart, Caomhán ^[4]; Goguet, Alexandre ^[4]; Partridge, William P. ^[3]

School of Mechanical and Aerospace Engineering, Queen’s University Belfast, Ashby Building, Stranmillis Road, Belfast BT9 5AH, United Kingdom
Department of Chemical and Materials Engineering, King Abdulaziz University, Jeddah, Saudi Arabia
Fuels, Engines and Emissions Research Center, Oak Ridge National Laboratory, P.O. Box 2008, MS-6472, Oak Ridge, Tennessee 37831-6472, United States
School of Chemistry and Chemical Engineering, Queen’s University Belfast, David Keir Building, Stranmillis Road, Belfast BT9 5AG, United Kingdom

The development and optimization of catalysts and catalytic processes requires knowledge of reaction kinetics and mechanisms. In traditional catalyst kinetic characterization, the gas composition is known at the inlet, and the exit flow is measured to determine changes in concentration. As such, the progression of the chemistry within the catalyst is not known. Technological advances in electromagnetic and physical probes have made visualizing the evolution of the chemistry within catalyst samples a reality, as part of a methodology commonly known as spatial resolution. Herein, we discuss and evaluate the development of spatially resolved techniques, including the evolutions and achievements of this growing area of catalytic research. The impact of such techniques is discussed in terms of the invasiveness of physical probes on catalytic systems, as well as how experimentally obtained spatial profiles can be used in conjunction with kinetic modeling. Moreover, some aims and aspirations for further evolution of spatially resolved techniques are considered.

View Journal Article

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: Vehicle Technologies Office; AC05-00OR22725

OSTI ID:: 1237385

Alternate ID(s):: OSTI ID: 1236596

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Vol. 6 Journal Issue: 2; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 53 works

Citation information provided by
Web of Science

References (156)

Electronic Spectroscopy: Ultra Violet-Visible and near IR Spectroscopies Jentoft, Friederike C. Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch3	book	April 2012
Effective Model for Prediction of N2O and NH3 Formation During the Regeneration of NO x Storage Catalyst Kočí, Petr; Bártová, Šárka; Mráček, David Topics in Catalysis, Vol. 56, Issue 1-8 https://doi.org/10.1007/s11244-013-9939-y	journal	March 2013
NH3 pulsing adsorption and SCR reactions over a Cu-CHA SCR catalyst Hou, Xuxian; Schmieg, Steven J.; Li, Wei Catalysis Today, Vol. 197, Issue 1 https://doi.org/10.1016/j.cattod.2012.05.041	journal	December 2012
Nuclear Magnetic Resonance Spectroscopy Gladden, Lynn F.; Lutecki, Michal; McGregor, James Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch8	book	April 2012
A Catalytic Reaction Mechanism for Methane Partial Oxidation at Short Contact Times, Reforming, and Combustion, and for Oxygenate Decomposition and Oxidation on Platinum Mhadeshwar, A. B.; Vlachos, D. G. Industrial & Engineering Chemistry Research, Vol. 46, Issue 16 https://doi.org/10.1021/ie070322c	journal	August 2007
Reaction-Driven Surface Restructuring and Selectivity Control in Allylic Alcohol Catalytic Aerobic Oxidation over Pd Lee, Adam F.; Ellis, Christine V.; Naughton, James N. Journal of the American Chemical Society, Vol. 133, Issue 15 https://doi.org/10.1021/ja200684f	journal	April 2011
Sulfur impact on NOx storage, oxygen storage, and ammonia breakthrough during cyclic lean/rich operation of a commercial lean NOx trap Choi, Jae-Soon; Partridge, William P.; Daw, C. Stuart Applied Catalysis B: Environmental, Vol. 77, Issue 1-2 https://doi.org/10.1016/j.apcatb.2007.07.025	journal	November 2007
Shape-Selective Catalysis: Zeolites Hagen, Jens Industrial Catalysis: A Practical Approach, Second Edition https://doi.org/10.1002/3527607684.ch7	book	October 2005
Catalytic partial oxidation of ethane to ethylene and syngas over Rh and Pt coated monoliths: Spatial profiles of temperature and composition Michael, Brian C.; Nare, David N.; Schmidt, Lanny D. Chemical Engineering Science, Vol. 65, Issue 12 https://doi.org/10.1016/j.ces.2010.03.033	journal	June 2010
Anomalous steady-state and spatio-temporal features of methane oxidation on Pt/Pd/Al2O3 monolith spanning lean and rich conditions Bugosh, Gregory S.; Easterling, Vencon G.; Rusakova, Irene A. Applied Catalysis B: Environmental, Vol. 165 https://doi.org/10.1016/j.apcatb.2014.09.058	journal	April 2015
On the need to use steady-state or operando techniques to investigate reaction mechanisms: An in situ DRIFTS and SSITKA-based study example Tibiletti, Daniele; Goguet, Alexandre; Reid, David Catalysis Today, Vol. 113, Issue 1-2 https://doi.org/10.1016/j.cattod.2005.11.013	journal	March 2006
NH3 formation and utilization in regeneration of Pt/Ba/Al2O3 NOx storage-reduction catalyst with H2 Partridge, William P.; Choi, Jae-Soon Applied Catalysis B: Environmental, Vol. 91, Issue 1-2 https://doi.org/10.1016/j.apcatb.2009.05.017	journal	September 2009
Raman and UV-Raman Spectroscopies Fan, Fengtao; Feng, Zhaochi; Li, Can Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch2	book	April 2012
Chemical Imaging of Spatial Heterogeneities in Catalytic Solids at Different Length and Time Scales Weckhuysen, Bert M. Angewandte Chemie International Edition, Vol. 48, Issue 27 https://doi.org/10.1002/anie.200900339	journal	June 2009
Sulfur and temperature effects on the spatial distribution of reactions inside a lean NOx trap and resulting changes in global performance Choi, Jae-Soon; Partridge, William P.; Pihl, Josh A. Catalysis Today, Vol. 136, Issue 1-2 https://doi.org/10.1016/j.cattod.2008.01.008	journal	July 2008
Atomic Structure of Quantum Gold Nanowires: Quantification of the Lattice Strain Kundu, Paromita; Turner, Stuart; Van Aert, Sandra ACS Nano, Vol. 8, Issue 1 https://doi.org/10.1021/nn4052315	journal	December 2013
Progress towards five dimensional diffraction imaging of functional materials under process conditions Beale, Andrew M.; Jacques, Simon D. M.; Gibson, Emma K. Coordination Chemistry Reviews, Vol. 277-278 https://doi.org/10.1016/j.ccr.2014.05.008	journal	October 2014
Effect of pressure in the autothermal catalytic partial oxidation of CH4 and C3H8: Spatially resolved temperature and composition profiles Donazzi, A.; Livio, D.; Diehm, C. Applied Catalysis A: General, Vol. 469 https://doi.org/10.1016/j.apcata.2013.09.054	journal	January 2014
Evolution, achievements, and perspectives of the TAP technique Perezramirez, J.; Kondratenko, E. Catalysis Today, Vol. 121, Issue 3-4 https://doi.org/10.1016/j.cattod.2007.01.001	journal	March 2007
Methane catalytic partial oxidation on autothermal Rh and Pt foam catalysts: Oxidation and reforming zones, transport effects, and approach to thermodynamic equilibrium Horn, R.; Williams, K.; Degenstein, N. Journal of Catalysis, Vol. 249, Issue 2 https://doi.org/10.1016/j.jcat.2007.05.011	journal	July 2007
Ammonia is a hydrogen carrier in the regeneration of Pt/BaO/Al2O3 NOx traps with H2 Cumaranatunge, L.; Mulla, S.; Yezerets, A. Journal of Catalysis, Vol. 246, Issue 1 https://doi.org/10.1016/j.jcat.2006.11.008	journal	February 2007
Spatially resolving SCR reactions over a Fe/zeolite catalyst Luo, Jin-Yong; Hou, Xuxian; Wijayakoon, Prasanna Applied Catalysis B: Environmental, Vol. 102, Issue 1-2 https://doi.org/10.1016/j.apcatb.2010.11.031	journal	February 2011
Synergy of Homogeneous and Heterogeneous Chemistry Probed by In Situ Spatially Resolved Measurements of Temperature and Composition Donazzi, Alessandro; Livio, Dario; Maestri, Matteo Angewandte Chemie International Edition, Vol. 50, Issue 17 https://doi.org/10.1002/anie.201007346	journal	March 2011
Catalytic partial oxidation of ethanol over Rh/Al2O3: Spatially resolved temperature and concentration profiles Livio, Dario; Diehm, Claudia; Donazzi, Alessandro Applied Catalysis A: General, Vol. 467 https://doi.org/10.1016/j.apcata.2013.07.054	journal	October 2013
Fast Spatially Resolved Exhaust Gas Recirculation (EGR) Distribution Measurements in an Internal Combustion Engine Using Absorption Spectroscopy Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E. Applied Spectroscopy, Vol. 69, Issue 9 https://doi.org/10.1366/14-07796	journal	September 2015
In situ cell for combined XRD and on-line catalysis tests: Studies of Cu-based water gas shift and methanol catalysts Clausen, B. Journal of Catalysis, Vol. 132, Issue 2 https://doi.org/10.1016/0021-9517(91)90168-4	journal	December 1991
Surface temperature profiles in CH4 CPO over honeycomb supported Rh catalyst probed with in situ optical pyrometer Donazzi, Alessandro; Livio, Dario; Beretta, Alessandra Applied Catalysis A: General, Vol. 402, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.05.022	journal	July 2011
New high temperature furnace for structure refinement by powder diffraction in controlled atmospheres using synchrotron radiation Margulies, L.; Kramer, M. J.; McCallum, R. W. Review of Scientific Instruments, Vol. 70, Issue 9 https://doi.org/10.1063/1.1149948	journal	September 1999
Catalytic partial oxidation of methane on platinum investigated by spatial reactor profiles, spatially resolved spectroscopy, and microkinetic modeling Korup, Oliver; Goldsmith, Claude Franklin; Weinberg, Gisela Journal of Catalysis, Vol. 297 https://doi.org/10.1016/j.jcat.2012.08.022	journal	January 2013
Detailed surface reaction mechanism for Pt-catalyzed abatement of automotive exhaust gases Koop, J.; Deutschmann, O. Applied Catalysis B: Environmental, Vol. 91, Issue 1-2 https://doi.org/10.1016/j.apcatb.2009.05.006	journal	September 2009
Space- and Time-Resolved Combined DRIFT and Raman Spectroscopy: Monitoring Dynamic Surface and Bulk Processes during NO _x Storage Reduction Urakawa, Atsushi; Maeda, Nobutaka; Baiker, Alfons Angewandte Chemie International Edition, Vol. 47, Issue 48 https://doi.org/10.1002/anie.200804077	journal	October 2008
Hydrogen production by catalytic partial oxidation of methane over staged Pd/Rh coated monoliths: Spatially resolved concentration and temperature profiles Diehm, Claudia; Deutschmann, Olaf International Journal of Hydrogen Energy, Vol. 39, Issue 31 https://doi.org/10.1016/j.ijhydene.2014.06.094	journal	October 2014
Product gas evolution above planar microstructured model catalysts—A combined scanning mass spectrometry, Monte Carlo, and Computational Fluid Dynamics study Roos, M.; Bansmann, J.; Zhang, D. The Journal of Chemical Physics, Vol. 133, Issue 9 https://doi.org/10.1063/1.3475518	journal	September 2010
Optical frequency domain reflectometry measurements of spatio-temporal temperature inside catalytic reactors: Applied to study wrong-way behavior Nguyen, Hoang; Harold, Michael P.; Luss, Dan Chemical Engineering Journal, Vol. 234 https://doi.org/10.1016/j.cej.2013.08.074	journal	December 2013
Spatially resolved catalysis in microstructured reactors by IR spectroscopy: CO oxidation over mono- and bifunctional Pt catalysts Daniel, C.; Clarté, M-O.; Teh, S. -P. Journal of Catalysis, Vol. 272, Issue 1 https://doi.org/10.1016/j.jcat.2010.03.012	journal	May 2010
Axial variation of the oxidation state of Pt-Rh/Al2O3 during partial methane oxidation in a fixed-bed reactor: An in situ X-ray absorption spectroscopy study Grunwaldt, J. -D.; Baiker, A. Catalysis Letters, Vol. 99, Issue 1-2 https://doi.org/10.1007/s10562-005-0770-3	journal	January 2005
Kinetic Study of Carbon Monoxide and Propylene Oxidation on Platinum Catalysts Voltz, Sterling E.; Morgan, Charles R.; Liederman, David Industrial & Engineering Chemistry Product Research and Development, Vol. 12, Issue 4 https://doi.org/10.1021/i360048a006	journal	December 1973
In situ magnetic resonance visualisation of the spatial variation of catalytic conversion within a fixed-bed reactor Yuen, E. H. L.; Sederman, A. J.; Gladden, L. F. Applied Catalysis A: General, Vol. 232, Issue 1-2 https://doi.org/10.1016/S0926-860X(02)00064-9	journal	June 2002
Mechanism of H2 and CO formation in the catalytic partial oxidation of CH4 on Rh probed by steady-state spatial profiles and spatially resolved transients Horn, R.; Williams, K. A.; Degenstein, N. J. Chemical Engineering Science, Vol. 62, Issue 5 https://doi.org/10.1016/j.ces.2006.11.030	journal	March 2007
Review of Vehicular Emissions Trends Johnson, Timothy V. SAE International Journal of Engines, Vol. 8, Issue 3 https://doi.org/10.4271/2015-01-0993	journal	January 2015
Numerical simulation of a structured catalytic methane reformer by DUO: The new computational interface for OpenFOAM® and DETCHEM™ Hettel, Matthias; Diehm, Claudia; Bonart, Henning Catalysis Today, Vol. 258 https://doi.org/10.1016/j.cattod.2015.02.011	journal	December 2015
Metal Redispersion Strategies for Recycling of Supported Metal Catalysts: A Perspective Morgan, Kevin; Goguet, Alexandre; Hardacre, Christopher ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00535	journal	May 2015
Correlation between catalytic activity and catalytic surface area of a Pt/Al2O3 DOC: An experimental and microkinetic modeling study Chan, Denise; Tischer, Steffen; Heck, Jasmin Applied Catalysis B: Environmental, Vol. 156-157 https://doi.org/10.1016/j.apcatb.2014.03.009	journal	September 2014
Mass Spectrometry Alves, Sandra; Tabet, Jean-Claude Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch20	book	April 2012
Modeling spatially resolved profiles of methane partial oxidation on a Rh foam catalyst with detailed chemistry Dallenogare, D.; Degenstein, N.; Horn, R. Journal of Catalysis, Vol. 258, Issue 1 https://doi.org/10.1016/j.jcat.2008.06.006	journal	August 2008
Combined high-pressure cell–ultrahigh vacuum system for fast testing of model metal alloy catalysts using scanning mass spectrometry Johansson, M.; Hoffmann Jørgensen, J.; Chorkendorff, I. Review of Scientific Instruments, Vol. 75, Issue 6 https://doi.org/10.1063/1.1753677	journal	June 2004
Three–Dimensional Water Vapor Visualization in Porous Packing by Near-Infrared Diffuse Transmittance Tomography Nic An tSaoir, Méabh; Abreu Fernandes, Daniel Luis; Sá, Jacinto Industrial & Engineering Chemistry Research, Vol. 51, Issue 26 https://doi.org/10.1021/ie202023t	journal	December 2011
Spatial Resolution of Species and Temperature Profiles in Catalytic Reactors: In Situ Sampling Techniques and CFD Modeling Diehm, Claudia; Karadeniz, Hüsyein; Karakaya, Canan Modeling and Simulation of Heterogeneous Catalytic Processes https://doi.org/10.1016/B978-0-12-800422-7.00002-9	book	January 2014
Investigation of a fixed-bed pilot plant reactor by dynamic experimentation. Part 1. Apparatus and experimental results Baiker, Alfons; Bergougnan, Michel The Canadian Journal of Chemical Engineering, Vol. 63, Issue 1 https://doi.org/10.1002/cjce.5450630122	journal	February 1985
New insights on N2O formation pathways during lean/rich cycling of a commercial lean NOx trap catalyst Bártová, Šárka; Kočí, Petr; Mráček, David Catalysis Today, Vol. 231 https://doi.org/10.1016/j.cattod.2013.11.050	journal	August 2014
Transmission Electron Microscopy Thomas, John Meurig; Ducati, Caterina Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch16	book	April 2012
Dose limited reliability of quantitative annular dark field scanning transmission electron microscopy for nano-particle atom-counting De Backer, A.; Martinez, G. T.; MacArthur, K. E. Ultramicroscopy, Vol. 151 https://doi.org/10.1016/j.ultramic.2014.11.028	journal	April 2015
X-Ray Diffraction and Small Angle X-Ray Scattering Behrens, Malte; Schlogl, Robert Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch15	book	April 2012
Integrating intrinsic and global kinetics as a dual kinetic model for automotive catalysis Stewart, Jonathan; Douglas, Roy; Goguet, Alexandre Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, Vol. 228, Issue 3 https://doi.org/10.1177/0954407013508379	journal	November 2013
Local ammonia storage and ammonia inhibition in a monolithic copper-beta zeolite SCR catalyst Auvray, Xavier; Partridge, William P.; Choi, Jae-Soon Applied Catalysis B: Environmental, Vol. 126 https://doi.org/10.1016/j.apcatb.2012.07.019	journal	September 2012
Spatially-Resolved Calorimetry: Using IR Thermography to Measure Temperature and Trapped NOX Distributions on a NOX Adsorber Catalyst Aftab, Khurram; Mandur, Jasdeep; Budman, Hector Catalysis Letters, Vol. 125, Issue 3-4 https://doi.org/10.1007/s10562-008-9578-2	journal	July 2008
Applying spatially resolved concentration and temperature measurements in a catalytic plate reactor for the kinetic study of CO methanation Kopyscinski, Jan; Schildhauer, Tilman J.; Vogel, Frédéric Journal of Catalysis, Vol. 271, Issue 2 https://doi.org/10.1016/j.jcat.2010.02.008	journal	May 2010
Spatially resolved temperature and gas species concentration changes during C3H6 oxidation over a Pt/Al2O3 catalyst following sulfur exposure Russell, April; Henry, Cary; Currier, Neal W. Applied Catalysis A: General, Vol. 397, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.03.012	journal	April 2011
An in situ spatially resolved method to probe gas phase reactions through a fixed bed catalyst Touitou, Jamal; Morgan, Kevin; Burch, Robbie Catalysis Science & Technology, Vol. 2, Issue 9 https://doi.org/10.1039/c2cy20141k	journal	January 2012
Closing the operando gap: The application of high energy photons for studying catalytic solids at work O’Brien, Matthew G.; Beale, Andrew M.; Jacques, Simon D. M. Applied Catalysis A: General, Vol. 391, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.06.027	journal	January 2011
Spatially-Resolved Temperature and Gas Species Changes in a Lean-Burn Engine Emissions Control Catalyst Russell, April; Epling, William S.; Hess, Howard Industrial & Engineering Chemistry Research, Vol. 49, Issue 21 https://doi.org/10.1021/ie1005299	journal	November 2010
The development of a model capable of predicting diesel lean NO_x catalyst performance under transient conditions Ansell, G. P.; Bennett, P. S.; Cox, J. P. Applied Catalysis B: Environmental, Vol. 10, Issue 1-3, p. 183-201 https://doi.org/10.1016/0926-3373(96)00030-6	journal	September 1996
Spatial Resolution of Reactant Species Consumption in Diesel Oxidation Catalysts Irani, Karishma; Epling, William S.; Blint, Richard Topics in Catalysis, Vol. 52, Issue 13-20 https://doi.org/10.1007/s11244-009-9349-3	journal	July 2009
X-ray absorption spectroscopy under reaction conditions: suitability of different reaction cells for combined catalyst characterization and time-resolved studies Grunwaldt, J. -D.; Caravati, M.; Hannemann, S. Physical Chemistry Chemical Physics, Vol. 6, Issue 11 https://doi.org/10.1039/b403071k	journal	January 2004
Detailed validation of an automotive catalysis model using spatially resolved measurements within the catalyst substrate Stewart, Jonathan; Douglas, Roy; Goguet, Alexandre The Canadian Journal of Chemical Engineering, Vol. 92, Issue 9 https://doi.org/10.1002/cjce.21993	journal	June 2014
Dynamics of N2 and N2O peaks during and after the regeneration of lean NO trap Mráček, David; Kočí, Petr; Marek, Miloš Applied Catalysis B: Environmental, Vol. 166-167 https://doi.org/10.1016/j.apcatb.2014.12.002	journal	May 2015
Catalytic partial oxidation of methane on rhodium and platinum: Spatial profiles at elevated pressure Bitsch-Larsen, A.; Horn, R.; Schmidt, L. D. Applied Catalysis A: General, Vol. 348, Issue 2 https://doi.org/10.1016/j.apcata.2008.06.036	journal	October 2008
Chemical and geometric effects of Ce and washcoat addition on catalytic partial oxidation of CH4 on Rh probed by spatially resolved measurements Donazzi, Alessandro; Michael, Brian C.; Schmidt, Lanny D. Journal of Catalysis, Vol. 260, Issue 2 https://doi.org/10.1016/j.jcat.2008.09.028	journal	December 2008
Resolving kinetics and dynamics of a catalytic reaction inside a fixed bed reactor by combined kinetic and spectroscopic profiling Geske, Michael; Korup, Oliver; Horn, Raimund Catal. Sci. Technol., Vol. 3, Issue 1 https://doi.org/10.1039/C2CY20489D	journal	January 2013
The effect of reaction conditions on the stability of Au/CeZrO4 catalysts in the low-temperature water–gas shift reaction Daly, H.; Goguet, A.; Hardacre, C. Journal of Catalysis, Vol. 273, Issue 2 https://doi.org/10.1016/j.jcat.2010.05.021	journal	July 2010
A SCR Model Calibration Approach with Spatially Resolved Measurements and NH3 Storage Distributions Song, Xiaobo; Parker, Gordon G.; Johnson, John H. Emission Control Science and Technology, Vol. 1, Issue 1 https://doi.org/10.1007/s40825-014-0003-6	journal	November 2014
Techniques Coupling for Catalyst Characterisation Beale, Andrew M.; O'Brien, Matthew G.; Weckhuysen, Bert M. Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch23	book	January 2012
Transient Techniques: Temporal Analysis of Products and Steady State Isotopic Transient Kinetic Analysis Efstathiou, Angelos M.; Gleaves, John T.; Yablonsky, Gregory S. Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch22	book	April 2012
Chromatographic Methods Bertoncini, Fabrice; Thiebaut, Didier; Courtiade, Marion Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity https://doi.org/10.1002/9783527645329.ch21	book	January 2012
Syngas by catalytic partial oxidation of methane on rhodium: Mechanistic conclusions from spatially resolved measurements and numerical simulations Horn, R.; Williams, K.; Degenstein, N. Journal of Catalysis, Vol. 242, Issue 1 https://doi.org/10.1016/j.jcat.2006.05.008	journal	August 2006
Evaluation of an in situ spatial resolution instrument for fixed beds through the assessment of the invasiveness of probes and a comparison with a micro-kinetic model Touitou, Jamal; Aiouache, Farid; Burch, Robbie Journal of Catalysis, Vol. 319 https://doi.org/10.1016/j.jcat.2014.09.006	journal	November 2014
Kinetic modeling of NH3-SCR over a supported Cu zeolite catalyst using axial species distribution measurements Auvray, Xavier; Partridge, William; Choi, Jae-Soon Applied Catalysis B: Environmental, Vol. 163 https://doi.org/10.1016/j.apcatb.2014.08.003	journal	February 2015
Simultaneous measurement of X-ray small angle scattering, absorption and reactivity: A continuous flow catalysis reactor Lee, Sungsik; Lee, Byeongdu; Seifert, Soenke Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1 https://doi.org/10.1016/j.nima.2010.12.172	journal	September 2011
Spatially resolving LNT desulfation: re-adsorption induced by oxygen storage materials Luo, Jin-Yong; AL-Harbi, Meshari; Pang, Marcus Applied Catalysis B: Environmental, Vol. 106, Issue 3-4 https://doi.org/10.1016/j.apcatb.2011.06.033	journal	August 2011
–152.5 dB sensitivity high dynamic-range optical frequency-domain reflectometry Mussi, G.; Gisin, N.; Passy, R. Electronics Letters, Vol. 32, Issue 10 https://doi.org/10.1049/el:19960600	journal	January 1996
Microimaging of Transient Concentration Profiles of Reactant and Product Molecules during Catalytic Conversion in Nanoporous Materials Titze, Tobias; Chmelik, Christian; Kullmann, Jens Angewandte Chemie International Edition, Vol. 54, Issue 17 https://doi.org/10.1002/anie.201409482	journal	February 2015
The development of a two-dimensional transient catalyst model for direct injection two-stroke applications McCullough, G.; Douglas, R.; Cunningham, G. Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, Vol. 215, Issue 8 https://doi.org/10.1243/0954407011528482	journal	August 2001
Critical evaluation of in situ probe techniques for catalytic honeycomb monoliths Hettel, Matthias; Diehm, Claudia; Torkashvand, Bentholhoda Catalysis Today, Vol. 216 https://doi.org/10.1016/j.cattod.2013.05.005	journal	November 2013
An artificial structure modeler for 3D CFD simulations of catalytic foams Wehinger, Gregor D.; Heitmann, Helge; Kraume, Matthias Chemical Engineering Journal, Vol. 284 https://doi.org/10.1016/j.cej.2015.09.014	journal	January 2016
Intra-channel evolution of carbon monoxide and its implication on the regeneration of a monolithic Pt/K/Al2O3 NOx storage-reduction catalyst Choi, Jae-Soon; Partridge, William P.; Epling, William S. Catalysis Today, Vol. 114, Issue 1 https://doi.org/10.1016/j.cattod.2006.02.011	journal	April 2006
Design and application of a high-temperature microfurnace for an in situ X-ray diffraction study of phase transformation Eu, W. S.; Cheung, W. H.; Valix, M. Journal of Synchrotron Radiation, Vol. 16, Issue 6 https://doi.org/10.1107/S090904950903115X	journal	September 2009
Combining in situ characterization methods in one set-up: looking with more eyes into the intricate chemistry of the synthesis and working of heterogeneous catalysts Bentrup, Ursula Chemical Society Reviews, Vol. 39, Issue 12 https://doi.org/10.1039/b919711g	journal	January 2010
Optically accessible channel reactor for the kinetic investigation of hydrocarbon reforming reactions Bosco, Marcello; Vogel, Frédéric Catalysis Today, Vol. 116, Issue 3 https://doi.org/10.1016/j.cattod.2006.05.064	journal	August 2006
Modeling spatially resolved data of methane catalytic partial oxidation on Rh foam catalyst at different inlet compositions and flowrates Nogare, D. Dalle; Degenstein, N. J.; Horn, R. Journal of Catalysis, Vol. 277, Issue 2 https://doi.org/10.1016/j.jcat.2010.10.020	journal	January 2011
In Situ X-ray Diffraction and Solid-State NMR Study of the Fluorination of γ-Al ₂ O ₃ with HCF ₂ Cl Chupas, Peter J.; Ciraolo, Michael F.; Hanson, Jonathan C. Journal of the American Chemical Society, Vol. 123, Issue 8 https://doi.org/10.1021/ja0032374	journal	February 2001
Simple method for the modelling of the behaviour of a non-isothermal, non-adiabatic fixed-bed catalytic reactor Baiker, Alfons; Epple, Daniel Applied Catalysis, Vol. 22, Issue 1 https://doi.org/10.1016/S0166-9834(00)82594-4	journal	January 1986
Scanning mass spectrometer for quantitative reaction studies on catalytically active microstructures Roos, M.; Kielbassa, S.; Schirling, C. Review of Scientific Instruments, Vol. 78, Issue 8 https://doi.org/10.1063/1.2777167	journal	August 2007
Comment on “The Critical evaluation of in situ probe techniques for catalytic honeycomb monoliths” by Hettel et al. Goguet, Alexandre; Partridge, William P.; Aiouche, Farid Catalysis Today, Vol. 236 https://doi.org/10.1016/j.cattod.2014.02.034	journal	November 2014
Answer to the Comment from Goguet et al. to the paper “The Critical evaluation of in situ probe techniques for catalytic honeycomb monoliths” by Hettel et al. [1] Hettel, Matthias; Diehm, Claudia; Deutschmann, Olaf Catalysis Today, Vol. 236 https://doi.org/10.1016/j.cattod.2014.02.033	journal	November 2014
Heterogeneities of individual catalyst particles in space and time as monitored by spectroscopy Buurmans, Inge L. C.; Weckhuysen, Bert M. Nature Chemistry, Vol. 4, Issue 11 https://doi.org/10.1038/nchem.1478	journal	October 2012
Comparative analysis of ex-situ and operando X-ray diffraction experiments for lithium insertion materials Brant, William R.; Li, Dan; Gu, Qinfen Journal of Power Sources, Vol. 302 https://doi.org/10.1016/j.jpowsour.2015.10.015	journal	January 2016
Spatially resolved in situ measurements of transient species breakthrough during cyclic, low-temperature regeneration of a monolithic Pt/K/Al2O3 NOx storage-reduction catalyst Choi, Jae-Soon; Partridge, William P.; Daw, C. Stuart Applied Catalysis A: General, Vol. 293 https://doi.org/10.1016/j.apcata.2005.06.025	journal	September 2005
Kinetic modeling of NOx storage and reduction using spatially resolved MS measurements Shwan, Soran; Partridge, William; Choi, Jae-Soon Applied Catalysis B: Environmental, Vol. 147 https://doi.org/10.1016/j.apcatb.2013.10.023	journal	April 2014
Fluidic effects on kinetic parameter estimation in lab-scale catalysis testing – A critical evaluation based on computational fluid dynamics Wehinger, Gregor D.; Eppinger, Thomas; Kraume, Matthias Chemical Engineering Science, Vol. 111 https://doi.org/10.1016/j.ces.2014.02.025	journal	May 2014
Thermodynamic Consistency in Microkinetic Development of Surface Reaction Mechanisms Mhadeshwar, A. B.; Wang, H.; Vlachos, D. G. The Journal of Physical Chemistry B, Vol. 107, Issue 46 https://doi.org/10.1021/jp034954y	journal	November 2003
A Mathematical Approach to the Balancing of Mass Transfer and Reaction Kinetics in Dual Kinetic Model for Automotive Catalysis Stewart, Jonathan; Douglas, Roy; Goguet, Alexandre SAE 2014 International Powertrain, Fuels & Lubricants Meeting, SAE Technical Paper Series https://doi.org/10.4271/2014-01-2821	conference	October 2014
Complex structural dynamics of nanocatalysts revealed in Operando conditions by correlated imaging and spectroscopy probes Li, Y.; Zakharov, D.; Zhao, S. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8583	journal	June 2015
Magnetic Resonance Imaging of Catalysts and Catalytic Processes Gladden, L. F.; Mantle, M. D.; Sederman, A. J. Advances in Catalysis https://doi.org/10.1016/S0360-0564(06)50001-X	book	January 2006
On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reactionElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b4/b403438d/ Tibiletti, Daniele; Goguet, Alexandre; Meunier, Frederic C. Chemical Communications, Issue 14 https://doi.org/10.1039/b403438d	journal	January 2004
Partial catalytic oxidation of methane to synthesis gas over rhodium: in situ Raman experiments and detailed simulations Appel, Christoph; Mantzaras, John; Schaeren, Rolf Proceedings of the Combustion Institute, Vol. 30, Issue 2 https://doi.org/10.1016/j.proci.2004.08.055	journal	January 2005
An in situ sample environment reaction cell for spatially resolved x-ray absorption spectroscopy studies of powders and small structured reactors Zhang, Chu; Gustafson, Johan; Merte, Lindsay R. Review of Scientific Instruments, Vol. 86, Issue 3 https://doi.org/10.1063/1.4915321	journal	March 2015
Thermographic Phosphors for High Temperature Measurements: Principles, Current State of the Art and Recent Applications Khalid, Ashiq; Kontis, Konstantinos Sensors, Vol. 8, Issue 9 https://doi.org/10.3390/s8095673	journal	September 2008
Carbon formation in catalytic partial oxidation of methane on platinum: Model studies on a polycrystalline Pt foil Korup, Oliver; Schlögl, Robert; Horn, Raimund Catalysis Today, Vol. 181, Issue 1 https://doi.org/10.1016/j.cattod.2011.04.051	journal	February 2012
Detailed numerical simulations of catalytic fixed-bed reactors: Heterogeneous dry reforming of methane Wehinger, Gregor D.; Eppinger, Thomas; Kraume, Matthias Chemical Engineering Science, Vol. 122 https://doi.org/10.1016/j.ces.2014.09.007	journal	January 2015
Spatially resolving concentration and temperature gradients during the oxidation of propylene on Pt/Al2O3 Shakir, Osama; Yezerets, Aleksey; Currier, Neal W. Applied Catalysis A: General, Vol. 365, Issue 2 https://doi.org/10.1016/j.apcata.2009.06.033	journal	August 2009
New operation strategy for driving the selectivity of NO reduction to N2, NH3 or N2O during lean/rich cycling of a lean NO trap catalyst Mráček, David; Kočí, Petr; Choi, Jae-Soon Applied Catalysis B: Environmental, Vol. 182 https://doi.org/10.1016/j.apcatb.2015.09.002	journal	March 2016
Mechanism of the Oxidation−Reduction of the MoVSbNbO Catalyst: In Operando X-ray Absorption Spectroscopy and Electrical Conductivity Measurements Safonova, Olga V.; Deniau, Benoit; Millet, Jean-Marc M. The Journal of Physical Chemistry B, Vol. 110, Issue 47 https://doi.org/10.1021/jp064347l	journal	November 2006
Modeling the high-temperature catalytic partial oxidation of methane over platinum gauze: Detailed gas-phase and surface chemistries coupled with 3D flow field simulations Quiceno, Raúl; Pérez-Ramírez, Javier; Warnatz, Jürgen Applied Catalysis A: General, Vol. 303, Issue 2 https://doi.org/10.1016/j.apcata.2006.01.041	journal	April 2006
Reactor for in situ measurements of spatially resolved kinetic data in heterogeneous catalysis Horn, R.; Korup, O.; Geske, M. Review of Scientific Instruments, Vol. 81, Issue 6 https://doi.org/10.1063/1.3428727	journal	June 2010
Concepts of Modern Catalysis and Kinetics Chorkendorff, I.; Niemantsverdriet, J. W. https://doi.org/10.1002/3527602658	book	October 2003
Modeling the simultaneous oxidation of CO and H2 on Pt – Promoting effect of H2 on the CO-light-off Hauptmann, W.; Votsmeier, M.; Vogel, H. Applied Catalysis A: General, Vol. 397, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.02.031	journal	April 2011
Spatial and temporal profiles in millisecond partial oxidation processes Horn, Raimund; Degenstein, Nick J.; Williams, Kenneth A. Catalysis Letters, Vol. 110, Issue 3-4 https://doi.org/10.1007/s10562-006-0117-8	journal	September 2006
Spatiotemporal distribution of NOx storage and impact on NH3 and N2O selectivities during lean/rich cycling of a Ba-based lean NOx trap catalyst Choi, Jae-Soon; Partridge, William P.; Pihl, Josh A. Catalysis Today, Vol. 184, Issue 1 https://doi.org/10.1016/j.cattod.2011.11.007	journal	April 2012
High resolution optical frequency domain reflectometry for characterization of components and assemblies Soller, Brian J.; Gifford, Dawn K.; Wolfe, Matthew S. Optics Express, Vol. 13, Issue 2 https://doi.org/10.1364/OPEX.13.000666	journal	January 2005
Time-Resolved Measurements of Emission Transients By Mass Spectrometry Partridge, William P.; Storey, John M. E.; Lewis, Samuel A. International Fuels & Lubricants Meeting & Exposition, SAE Technical Paper Series https://doi.org/10.4271/2000-01-2952	conference	October 2000
Fiber grating sensors Kersey, A. D.; Davis, M. A.; Patrick, H. J. Journal of Lightwave Technology, Vol. 15, Issue 8 https://doi.org/10.1109/50.618377	journal	January 1997
What drives spontaneous oscillations during CO oxidation using O2 over supported Rh/Al2O3 catalysts? Figueroa, Santiago J. A.; Newton, Mark A. Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.006	journal	April 2014
First Direct Study of the Ammonolysis Reaction in the Most Common Alkaline and Alkaline Earth Metal Hydrides by in Situ SR-PXD Pistidda, C.; Santoru, A.; Garroni, S. The Journal of Physical Chemistry C, Vol. 119, Issue 2 https://doi.org/10.1021/jp510720x	journal	January 2015
Evidence for the Active Phase of Heterogeneous Catalysts through In Situ Reaction Product Imaging and Multiscale Modeling Matera, S.; Blomberg, S.; Hoffmann, M. J. ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b00858	journal	June 2015
Monitoring catalysts at work in their final form: spectroscopic investigations on a monolithic catalyst Rasmussen, Søren B.; Bañares, Miguel A.; Bazin, Philippe Phys. Chem. Chem. Phys., Vol. 14, Issue 7 https://doi.org/10.1039/C1CP22629K	journal	January 2012
Operando spatially and time-resolved X-ray absorption spectroscopy and infrared thermography during oscillatory CO oxidation Gänzler, Andreas M.; Casapu, Maria; Boubnov, Alexey Journal of Catalysis, Vol. 328 https://doi.org/10.1016/j.jcat.2015.01.002	journal	August 2015
Resolving EGR Distribution and Mixing Partridge, William P.; Lewis, Samuel A.; Ruth, Michael J. SAE Powertrain & Fluid Systems Conference & Exhibition, SAE Technical Paper Series https://doi.org/10.4271/2002-01-2882	conference	October 2002
Three-Way Catalytic Converter Modeling and Applications Koltsakis, G. C.; Kandylas, I. P.; Stamatelos, A. M. Chemical Engineering Communications, Vol. 164, Issue 1 https://doi.org/10.1080/00986449808912363	journal	January 1998
Limitations of Global Kinetic Parameters for Automotive Application Stewart, Jonathan; Douglas, Roy; Goguet, Alexandre SAE 2012 International Powertrains, Fuels & Lubricants Meeting, SAE Technical Paper Series https://doi.org/10.4271/2012-01-1638	conference	September 2012
In Situ MRI Study of 1-octene Isomerisation and Hydrogenation within a Trickle-bed Reactor Sederman, Andrew J.; Mantle, Michael D.; Dunckley, Christopher P. Catalysis Letters, Vol. 103, Issue 1-2 https://doi.org/10.1007/s10562-005-7522-2	journal	September 2005
Comparison among structured and packed-bed reactors for the catalytic partial oxidation of CH4 at short contact times Maestri, Matteo; Beretta, Alessandra; Groppi, Gianpiero Catalysis Today, Vol. 105, Issue 3-4 https://doi.org/10.1016/j.cattod.2005.06.045	journal	August 2005
Trends of NO-, NO2-, and NH3-emissions from gasoline-fueled Euro-3- to Euro-4-passenger cars Heeb, Norbert V.; Saxer, Christian J.; Forss, Anna-Maria Atmospheric Environment, Vol. 42, Issue 10 https://doi.org/10.1016/j.atmosenv.2007.12.008	journal	March 2008
Two-Dimensional Spatial Resolution of Concentration Profiles in Catalytic Reactors by Planar Laser-Induced Fluorescence: NO Reduction over Diesel Oxidation Catalysts Zellner, Alexander; Suntz, Rainer; Deutschmann, Olaf Angewandte Chemie International Edition, Vol. 54, Issue 9 https://doi.org/10.1002/anie.201410324	journal	January 2015
Remote thermometry with thermographic phosphors: Instrumentation and applications Allison, S. W.; Gillies, G. T. Review of Scientific Instruments, Vol. 68, Issue 7 https://doi.org/10.1063/1.1148174	journal	July 1997
Intra-fuel cell stack measurements of transient concentration distributions Partridge, W. P.; Toops, T. J.; Green, J. B. Journal of Power Sources, Vol. 160, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.01.016	journal	September 2006
Active phase evolution in single Ni/Al ₂ O ₃ methanation catalyst bodies studied in real time using combined μ-XRD-CT and μ-absorption-CT O'Brien, Matthew G.; Jacques, Simon D. M.; Di Michiel, Marco Chem. Sci., Vol. 3, Issue 2 https://doi.org/10.1039/C1SC00637A	journal	January 2012
SpaciMS: spatial and temporal operando resolution of reactions within catalytic monoliths Sá, Jacinto; Fernandes, Daniel Luis Abreu; Aiouache, Farid The Analyst, Vol. 135, Issue 9 https://doi.org/10.1039/c0an00303d	journal	January 2010
In situ13C DEPT-MRI as a tool to spatially resolve chemical conversion and selectivity of a heterogeneous catalytic reaction occurring in a fixed-bed reactor Akpa, Belinda S.; Mantle, Michael D.; Sederman, Andrew J. Chemical Communications, Issue 21 https://doi.org/10.1039/b501698c	journal	January 2005
Laser induced fluorescence of formaldehyde and Raman measurements of major species during partial catalytic oxidation of methane with large H2O and CO2 dilution at pressures up to 10bar Schneider, Adrian; Mantzaras, John; Bombach, Rolf Proceedings of the Combustion Institute, Vol. 31, Issue 2 https://doi.org/10.1016/j.proci.2006.08.076	journal	January 2007
Assessing Reductant Chemistry During In-Cylinder Regeneration of Diesel Lean NOx Traps West, Brian; Huff, Shean; Parks, James 2004 Powertrain & Fluid Systems Conference & Exhibition, SAE Technical Paper Series https://doi.org/10.4271/2004-01-3023	conference	October 2004
An in situ spatially resolved analytical technique to simultaneously probe gas phase reactions and temperature within the packed bed of a plug flow reactor Touitou, Jamal; Burch, Robbie; Hardacre, Christopher The Analyst, Vol. 138, Issue 10 https://doi.org/10.1039/c3an00250k	journal	January 2013
Tracing the conversion of aurichalcite to a copper catalyst by combined X-ray absorption and diffraction Couves, John W.; Thomas, John Meurig; Waller, David Nature, Vol. 354, Issue 6353 https://doi.org/10.1038/354465a0	journal	December 1991
Spatiotemporal behavior of Pt/Rh/CeO2/BaO catalyst during lean–rich cycling Nguyen, Hoang; Harold, Michael P.; Luss, Dan Chemical Engineering Journal, Vol. 262 https://doi.org/10.1016/j.cej.2014.09.103	journal	February 2015
2D-Mapping of the Catalyst Structure Inside a Catalytic Microreactor at Work: Partial Oxidation of Methane over Rh/Al ₂ O ₃ Grunwaldt, Jan-Dierk; Hannemann, Stefan; Schroer, Christian G. The Journal of Physical Chemistry B, Vol. 110, Issue 17 https://doi.org/10.1021/jp060371n	journal	May 2006
Optimal Design of A CPO-Reformer of Light Hydrocarbons with Honeycomb Catalyst: Effect of Frontal Heat Dispersions on the Temperature Profiles Livio, Dario; Donazzi, Alessandro; Beretta, Alessandra Topics in Catalysis, Vol. 54, Issue 13-15 https://doi.org/10.1007/s11244-011-9710-1	journal	July 2011
Conclusion: Challenges to Computational Catalysis van Santen, Rutger A.; Sautet, Philippe Computational Methods in Catalysis and Materials Science: An Introduction for Scientists and Engineers https://doi.org/10.1002/9783527625482.ch20	book	January 2009
Optimal design of a CH4 CPO-reformer with honeycomb catalyst: Combined effect of catalyst load and channel size on the surface temperature profile Beretta, Alessandra; Donazzi, Alessandro; Livio, Dario Catalysis Today, Vol. 171, Issue 1 https://doi.org/10.1016/j.cattod.2011.03.081	journal	August 2011
Measurement and analysis of spatial reactor profiles in high temperature catalysis research Korup, Oliver; Mavlyankariev, Sardor; Geske, Michael Chemical Engineering and Processing: Process Intensification, Vol. 50, Issue 10 https://doi.org/10.1016/j.cep.2011.05.024	journal	October 2011
Microkinetic modeling of spatially resolved autothermal CH4 catalytic partial oxidation experiments over Rh-coated foams Donazzi, A.; Maestri, M.; Michael, B. C. Journal of Catalysis, Vol. 275, Issue 2 https://doi.org/10.1016/j.jcat.2010.08.007	journal	October 2010
Optimization of Kinetic Parameters for an Aftertreatment Catalyst Pedlow, Andrew; McCullough, Geoffrey; Goguet, Alexandre SAE 2014 International Powertrain, Fuels & Lubricants Meeting, SAE Technical Paper Series https://doi.org/10.4271/2014-01-2814	conference	October 2014
Visualization of water vapour flow in a packed bed adsorber by near-infrared diffused transmittance tomography Nic An tSaoir, Méabh; Fernandes, Daniel Luis Abreu; Sá, Jacinto Chemical Engineering Science, Vol. 66, Issue 24 https://doi.org/10.1016/j.ces.2011.08.049	journal	December 2011
Nitrogen Selectivity in Lean NOx Trap Catalysis with Diesel Engine In-Cylinder Regeneration Parks, Jim; Huff, Shean; Pihl, Josh Powertrain & Fluid Systems Conference & Exhibition, SAE Technical Paper Series https://doi.org/10.4271/2005-01-3876	conference	October 2005
Steady-state and transient analysis of a CH₄-catalytic partial oxidation reformer Tavazzi, Ivan; Maestri, Matteo; Beretta, Alessandra AIChE Journal, Vol. 52, Issue 9, p. 3234-3245 https://doi.org/10.1002/aic.10938	journal	September 2006
Watching the Methanol-to-Olefin Process with Time- and Space-Resolved High-Energy Operando X-ray Diffraction Wragg, David S.; O'Brien, Matthew G.; Bleken, Francesca L. Angewandte Chemie International Edition, Vol. 51, Issue 32 https://doi.org/10.1002/anie.201203462	journal	July 2012
Space-Resolved Profiling Relevant in Heterogeneous Catalysis Urakawa, Atsushi; Baiker, Alfons Topics in Catalysis, Vol. 52, Issue 10 https://doi.org/10.1007/s11244-009-9312-3	journal	June 2009
Numerical Simulation of NO/NO2/NH3 Reactions on SCR-Catalytic Converters:Model Development and Applications Chatterjee, Daniel; Burkhardt, Thomas; Weibel, Michel SAE 2006 World Congress & Exhibition, SAE Technical Paper Series https://doi.org/10.4271/2006-01-0468	conference	April 2006

Similar Records

SpaciMS: spatial and temporal operando resolution of reactions within catalytic monoliths

Journal Article · Fri Jan 01 00:00:00 EST 2010 · Analyst, The · OSTI ID:1237385

Sa, Jacinto; Fernandes, Daniel; Aiouache, Farid; +6 more

Interfaces in Heterogeneous Catalysts: Advancing Mechanistic Understanding through Atomic-Scale Measurements

Journal Article · Thu Feb 16 00:00:00 EST 2017 · Accounts of Chemical Research · OSTI ID:1237385

Gao, Wenpei; Hood, Zachary D.; Chi, Miaofang

Space and time-resolved probing of heterogeneous catalysis reactions using lab-on-a-chip

Journal Article · Thu Feb 04 00:00:00 EST 2016 · Nanoscale · OSTI ID:1237385

Navin, Chelliah V.; Krishna, Katla Sai; Theegala, Chandra S.; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
spatial resolution
catalyst characterization
monoliths
packed beds
electromagnetic probes
physical probes

Title: Evolution and Enabling Capabilities of Spatially Resolved Techniques for the Characterization of Heterogeneously Catalyzed Reactions

Citation Formats

References (156)

Similar Records

Related Subjects