The corrosivity and passivity of sputtered Mg-Ti alloys

Song, Guang -Ling; Unocic, Kinga A.; Meyer, III, Harry M.; Cakmak, Ercan; Brady, Michael P.; Gannon, Paul E.; Himmer, Phil; Andrews, Quinn

doi:10.1016/j.corsci.2015.11.028

The corrosivity and passivity of sputtered Mg-Ti alloys

Journal Article · Mon Nov 30 04:00:00 EST 2015 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2015.11.028· OSTI ID:1237147

Song, Guang -Ling ^[1]; Unocic, Kinga A. ^[2]; Meyer, III, Harry M. ^[2]; Cakmak, Ercan ^[2]; Brady, Michael P. ^[2]; Gannon, Paul E. ^[3]; Himmer, Phil ^[3]; Andrews, Quinn ^[3]

Xiamen Univ., Xiamen (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Montana State Univ., Bozeman, MT (United States)

Our study explored the possibility of forming a “stainless” Mg–Ti alloy. The electrochemical behavior of magnetron-sputtered Mg–Ti alloys was measured in a NaCl solution, and the surface films on the alloys were examined by XPS, SEM and TEM. Increased corrosion resistance was observed with increased Ti content in the sputtered Mg–Ti alloys, but passive-like behavior was not reached until the Ti level (atomic %) was higher than the Mg level. Moreover, the surface film that formed on sputtered Mg–Ti based alloys in NaCl solution was thick, discontinuous and non-protective, whereas a thin, continuous and protective Mg and Ti oxide film was formed on a sputtered Ti–Mg based alloy.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1237147

Alternate ID(s):: OSTI ID: 22568327
OSTI ID: 1254777

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Journal Issue: 3 Vol. 104; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (52)

Recent Progress in Corrosion and Protection of Magnesium Alloys Song, G. Advanced Engineering Materials, Vol. 7, Issue 7 https://doi.org/10.1002/adem.200500013	journal	July 2005
Review of Recent Developments in the Field of Magnesium Corrosion: Recent Developments in Mg Corrosion Atrens, Andrej; Song, Guang-Ling; Liu, Ming Advanced Engineering Materials, Vol. 17, Issue 4 https://doi.org/10.1002/adem.201400434	journal	January 2015
Growth and structure of a combinatorial array of mixed-phase magnesium–aluminum thin-film alloys Olk, C. H.; Haddad, D. B. Applied Physics A, Vol. 88, Issue 2 https://doi.org/10.1007/s00339-007-4015-8	journal	May 2007
Preface for the special issue on light metals as biomaterials Song, Guang-Ling; Zeng, Rong-Chang Frontiers of Materials Science, Vol. 8, Issue 3 https://doi.org/10.1007/s11706-014-0260-x	journal	September 2014
The stability of the transpassive film on 304 stainless steel with post-treatment Song, Guang-Ling; Cao, Chu-Nan; Lin, Hai-Chao Corrosion Science, Vol. 36, Issue 1 https://doi.org/10.1016/0010-938X(94)90117-1	journal	January 1994
The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions Baril, Geneviève; Pébère, Nadine Corrosion Science, Vol. 43, Issue 3 https://doi.org/10.1016/S0010-938X(00)00095-0	journal	March 2001
Corrosion behavior of melt-spun Mg65Ni20Nd15 and Mg65Cu25Y10 metallic glasses Yao, H. B.; Li, Y.; Wee, A. T. S. Electrochimica Acta, Vol. 48, Issue 18 https://doi.org/10.1016/S0013-4686(03)00310-4	journal	August 2003
Magnesium: nutrition and metabolism Vormann, J. Molecular Aspects of Medicine, Vol. 24, Issue 1-3 https://doi.org/10.1016/S0098-2997(02)00089-4	journal	February 2003
Characterisation of corrosion products in Cr implanted Mg surfaces Vilarigues, M.; Alves, L. C.; Nogueira, I. D. Surface and Coatings Technology, Vol. 158-159 https://doi.org/10.1016/S0257-8972(02)00193-7	journal	September 2002
Protective coatings on magnesium and its alloys — a critical review Gray, J. E.; Luan, B. Journal of Alloys and Compounds, Vol. 336, Issue 1-2 https://doi.org/10.1016/S0925-8388(01)01899-0	journal	April 2002
In vitro corrosion and biocompatibility of binary magnesium alloys Gu, Xuenan; Zheng, Yufeng; Cheng, Yan Biomaterials, Vol. 30, Issue 4, p. 484-498 https://doi.org/10.1016/j.biomaterials.2008.10.021	journal	February 2009
Transpassivation of Fe–Cr–Ni stainless steels Song, Guangling Corrosion Science, Vol. 47, Issue 8 https://doi.org/10.1016/j.corsci.2004.09.007	journal	August 2005
Corrosion behavior of rapidly solidified Mg–Zn–rare earth element alloys in NaCl solution Yamasaki, Michiaki; Hayashi, Naoyuki; Izumi, Shogo Corrosion Science, Vol. 49, Issue 1 https://doi.org/10.1016/j.corsci.2006.05.017	journal	January 2007
Corrosion behaviour of magnesium/aluminium alloys in 3.5wt.% NaCl Pardo, A.; Merino, M. C.; Coy, A. E. Corrosion Science, Vol. 50, Issue 3 https://doi.org/10.1016/j.corsci.2007.11.005	journal	March 2008
Corrosion resistance of WE43 and AZ91D magnesium alloys with phosphate PEO coatings Arrabal, R.; Matykina, E.; Viejo, F. Corrosion Science, Vol. 50, Issue 6 https://doi.org/10.1016/j.corsci.2008.03.002	journal	June 2008
Corrosion behaviour of Mg–Cu and Mg–Mo composites in 3.5% NaCl Budruk Abhijeet, S.; Balasubramaniam, R.; Gupta, M. Corrosion Science, Vol. 50, Issue 9 https://doi.org/10.1016/j.corsci.2008.06.043	journal	September 2008
Relation between corrosion behavior and microstructure of Mg–Zn–Y alloys prepared by rapid solidification at various cooling rates Izumi, Shogo; Yamasaki, Michiaki; Kawamura, Yoshihito Corrosion Science, Vol. 51, Issue 2 https://doi.org/10.1016/j.corsci.2008.11.003	journal	February 2009
The role of Ca microalloying on the microstructure and corrosion behavior of Mg–6Zn–Mn–(0.5–2)Si alloys Lisitsyn, V.; Ben-Hamu, G.; Eliezer, D. Corrosion Science, Vol. 51, Issue 4 https://doi.org/10.1016/j.corsci.2009.01.009	journal	April 2009
Effect of heat treatment on corrosion behaviour of magnesium alloy AZ91D in simulated body fluid Zhou, Wei; Shen, Tian; Aung, Naing Naing Corrosion Science, Vol. 52, Issue 3 https://doi.org/10.1016/j.corsci.2009.11.030	journal	March 2010
Corrosion behaviour of sputter-deposited Mg–Zr alloys in a borate buffer solution El-Moneim, A. A.; Akiyama, E.; Ismail, K. M. Corrosion Science, Vol. 53, Issue 9 https://doi.org/10.1016/j.corsci.2011.05.043	journal	September 2011
Corrosion of heat treated magnesium alloy ZE41 Neil, W. C.; Forsyth, M.; Howlett, P. C. Corrosion Science, Vol. 53, Issue 10 https://doi.org/10.1016/j.corsci.2011.06.005	journal	October 2011
Effect of microstructure evolution on corrosion of different crystal surfaces of AZ31 Mg alloy in a chloride containing solution Song, Guang-Ling; Xu, Zhenqing Corrosion Science, Vol. 54 https://doi.org/10.1016/j.corsci.2011.09.005	journal	January 2012
Corrosion behavior of fine-grained AZ31B magnesium alloy Liao, Jinsun; Hotta, Makoto; Yamamoto, Naotsugu Corrosion Science, Vol. 61 https://doi.org/10.1016/j.corsci.2012.04.039	journal	August 2012
Electrochemical corrosion properties of CeO2-containing coatings on AZ31 magnesium alloys prepared by plasma electrolytic oxidation Lim, Tae Seop; Ryu, Hyun Sam; Hong, Seong-Hyeon Corrosion Science, Vol. 62 https://doi.org/10.1016/j.corsci.2012.04.043	journal	September 2012
The effect of surface pretreatment on the corrosion performance of Electroless E-coating coated AZ31 Song, Guang-Ling; Liu, Minghong Corrosion Science, Vol. 62 https://doi.org/10.1016/j.corsci.2012.04.045	journal	September 2012
Crystal orientation and electrochemical corrosion of polycrystalline Mg Song, Guang-Ling; Xu, Zhenqing Corrosion Science, Vol. 63 https://doi.org/10.1016/j.corsci.2012.05.019	journal	October 2012
Influence of cerium additions on the corrosion behaviour of high pressure die cast AM50 alloy Mert, Faruk; Blawert, Carsten; Kainer, Karl Ulrich Corrosion Science, Vol. 65, p. 145-151 https://doi.org/10.1016/j.corsci.2012.08.011	journal	December 2012
Effect of impurity Fe on corrosion behavior of AM50 and AM60 magnesium alloys Matsubara, Hiroshi; Ichige, Yasuhiro; Fujita, Kazuaki Corrosion Science, Vol. 66 https://doi.org/10.1016/j.corsci.2012.09.021	journal	January 2013
Corrosion behaviour of Mg–Zn–Y–Mischmetal alloys in phosphate buffer saline solution Pérez, P.; Onofre, E.; Cabeza, S. Corrosion Science, Vol. 69 https://doi.org/10.1016/j.corsci.2012.12.007	journal	April 2013
Corrosion performance and mechanical properties of sputter-deposited MgY and MgGd alloys Schlüter, Kristina; Shi, Zhiming; Zamponi, Christiane Corrosion Science, Vol. 78 https://doi.org/10.1016/j.corsci.2013.08.027	journal	January 2014
The influence of zirconium additions on the corrosion of magnesium Gandel, D. S.; Easton, M. A.; Gibson, M. A. Corrosion Science, Vol. 81 https://doi.org/10.1016/j.corsci.2013.11.051	journal	April 2014
The possibility of forming a sacrificial anode coating for Mg Song, Guang-Ling; Dudney, Nancy J.; Li, Juchuan Corrosion Science, Vol. 87 https://doi.org/10.1016/j.corsci.2014.07.007	journal	October 2014
The anodic surface film and hydrogen evolution on Mg Song, Guang-Ling; Unocic, Kinga A. Corrosion Science, Vol. 98 https://doi.org/10.1016/j.corsci.2015.05.047	journal	September 2015
Crystallographic orientation and electrochemical activity of AZ31 Mg alloy Song, Guang-Ling; Mishra, Raja; Xu, ZhenQing Electrochemistry Communications, Vol. 12, Issue 8 https://doi.org/10.1016/j.elecom.2010.05.011	journal	August 2010
Effect of bicarbonate on biodegradation behaviour of pure magnesium in a simulated body fluid Li, Zaichun; Song, Guang-Ling; Song, Shizhe Electrochimica Acta, Vol. 115 https://doi.org/10.1016/j.electacta.2013.10.131	journal	January 2014
Effects of pretreatment and process temperature of a conversion coating produced by an aprotic ammonium-phosphate ionic liquid on magnesium corrosion protection Elsentriecy, Hassan H.; Luo, Huimin; Meyer, Harry M. Electrochimica Acta, Vol. 123 https://doi.org/10.1016/j.electacta.2013.12.167	journal	March 2014
Characterisation of corrosion products formed on PVD in situ mechanically worked Mg–Ti alloys Mitchell, T.; Diplas, S.; Tsakiropoulos, P. Journal of Alloys and Compounds, Vol. 392, Issue 1-2 https://doi.org/10.1016/j.jallcom.2004.08.086	journal	April 2005
The effect of thermal treatment on the corrosion properties of vapor deposited magnesium alloyed with yttrium, aluminum, titanium, and misch metal Wolfe, Ryan C.; Shaw, Barbara A. Journal of Alloys and Compounds, Vol. 437, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.07.111	journal	June 2007
Structure and electrochemical behaviour of metastable Mg50Ti50 alloy prepared by ball milling Rousselot, S.; Bichat, M. -P.; Guay, D. Journal of Power Sources, Vol. 175, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.09.022	journal	January 2008
The topography of magnetron sputter-deposited Mg–Ti alloy thin films Song, Guang-Ling; Haddad, Daad Materials Chemistry and Physics, Vol. 125, Issue 3 https://doi.org/10.1016/j.matchemphys.2010.10.018	journal	February 2011
Corrosion resistance of nanocrystalline Mg–Cr alloys deposited by magnetron sputtering Samulevičienė, Meilutė; Miečinskas, Povilas; Leinartas, Konstantinas Materials Chemistry and Physics, Vol. 126, Issue 3 https://doi.org/10.1016/j.matchemphys.2010.12.017	journal	April 2011
Recent progress in corrosion protection of magnesium alloys by organic coatings Hu, Rong-Gang; Zhang, Su; Bu, Jun-Fu Progress in Organic Coatings, Vol. 73, Issue 2-3 https://doi.org/10.1016/j.porgcoat.2011.10.011	journal	February 2012
Formation by ion plating of Ti-coating on pure Mg for biomedical applications Zhang, Erlin; Xu, Liping; Yang, Ke Scripta Materialia, Vol. 53, Issue 5 https://doi.org/10.1016/j.scriptamat.2005.05.009	journal	September 2005
Improved corrosion resistance of AZ91D magnesium alloy by an aluminium-alloyed coating Zhu, Liqun; Song, Guangling Surface and Coatings Technology, Vol. 200, Issue 8 https://doi.org/10.1016/j.surfcoat.2004.11.042	journal	January 2006
Corrosion resistance of Al ion implanted AZ31 magnesium alloy at elevated temperature Zhu, X. M.; Yang, H. G.; Lei, M. K. Surface and Coatings Technology, Vol. 201, Issue 15 https://doi.org/10.1016/j.surfcoat.2006.09.060	journal	April 2007
Corrosion resistance of titanium ion implanted AZ91 magnesium alloy Liu, Chenglong; Xin, Yunchang; Tian, Xiubo Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 25, Issue 2 https://doi.org/10.1116/1.2699371	journal	March 2007
Electroless Plating of Aluminum from a Room-Temperature Ionic Liquid Electrolyte Koura, Nobuyuki; Nagase, Hiroshi; Sato, Atsushi Journal of The Electrochemical Society, Vol. 155, Issue 2 https://doi.org/10.1149/1.2817880	journal	January 2008
Transmission Electron Microscopy Study of Aqueous Film Formation and Evolution on Magnesium Alloys Unocic, K. A.; Elsentriecy, H. H.; Brady, Michael P. Journal of The Electrochemical Society, Vol. 161, Issue 6 https://doi.org/10.1149/2.024406jes	journal	January 2014
Corrosion behaviour of some vapour deposited magnesium alloys Baldwin, K. R.; Bray, D. J.; Howard, G. D. Materials Science and Technology, Vol. 12, Issue 11 https://doi.org/10.1179/mst.1996.12.11.929	journal	November 1996
Mg-Ti: A Possible Biodegradable, Biocompatible, Mechanically Matched Material for Temporary Implants Hoffmann, Ilona; Cheng, Yang-Tse; Puleo, David A. MRS Proceedings, Vol. 1301 https://doi.org/10.1557/opl.2011.566	journal	January 2011
Corrosion Properties of Supersaturated Magnesium Alloy Systems Blawert, Carsten; Heitmann, V.; Dietzel, Wolfgang Materials Science Forum, Vol. 539-543 https://doi.org/10.4028/www.scientific.net/MSF.539-543.1679	journal	March 2007
Corrosion and Electrochemical Evaluation of Coated Magnesium Alloys Song, S.; Song, G. -L.; Shen, W. CORROSION, Vol. 68, Issue 1 https://doi.org/10.5006/1.3674295	journal	January 2012

Cited By (2)

Influence of chemical heterogeneity and microstructure on the corrosion resistance of biodegradable WE43 magnesium alloys Mraied, Hesham; Wang, Wenbo; Cai, Wenjun Journal of Materials Chemistry B, Vol. 7, Issue 41 https://doi.org/10.1039/c9tb00388f	journal	January 2019
Magnesium Alloy Effects on Plasma Electrolytic Oxidation Electro-Ceramic and Electro-Coat Formation and Corrosion Resistance Brady, Michael P.; Leonard, Donovan N.; McNally, Elizabeth A. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0531914jes	journal	January 2019

Similar Records

Ti-Nb thin films deposited by magnetron sputtering on stainless steel

Journal Article · Tue Mar 15 00:00:00 EDT 2016 · Journal of Vacuum Science and Technology. A, Vacuum, Surfaces and Films · OSTI ID:22489805

Electrochemistry and passivity of a Ti-15Mo-3Nb-3Al beta-titanium alloy in ambient temperature aqueous chloride solutions

Journal Article · Fri Oct 01 00:00:00 EDT 1993 · Journal of the Electrochemical Society; (United States) · OSTI ID:5784195

Corrosion behavior of Ti-Al-N/Ti-Al duplex coating on AZ31 magnesium alloy in NaCl aqueous solution

Journal Article · Sat Aug 15 00:00:00 EDT 2009 · Materials Characterization · OSTI ID:22066109

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
A. Mg alloy
B. SEM
B. TEM
B. XPS
C. Passivity

The corrosivity and passivity of sputtered Mg-Ti alloys

Citation Formats

References (52)

Cited By (2)

Similar Records

Related Subjects