Optical and mechanical properties of nanocrystalline ZrC thin films grown by pulsed laser deposition.

Craciun, D.; Socol, G.; Lambers, E.; McCumiskey, E. J.; Taylor, C. R.; Martin, C.; Argibay, Nicolas; Craciun, V.; Tanner, D. B.

doi:10.1016/j.apsusc.2015.01.076

Optical and mechanical properties of nanocrystalline ZrC thin films grown by pulsed laser deposition.

Journal Article · Fri Jan 16 23:00:00 EST 2015 · Applied Surface Science

DOI:https://doi.org/10.1016/j.apsusc.2015.01.076· OSTI ID:1236229

Craciun, D. ^[1]; Socol, G. ^[1]; Lambers, E. ^[2]; McCumiskey, E. J. ^[2]; Taylor, C. R. ^[2]; Martin, C. ^[3]; Argibay, Nicolas ^[4]; Craciun, V. ^[1]; Tanner, D. B. ^[2]

National Institute for Laser, Plasma, and Radiation Physics, Magurele (Romania)
Univ. of Florida, Gainesville, FL (United States)
Ramapo College of New Jersey, Mahwah, NJ (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Thin ZrC films (<500 nm) were grown on (100) Si substrates at a substrate temperature of 500 °C by the pulsed laser deposition (PLD) technique using a KrF excimer laser under different CH₄ pressures. Glancing incidence X-ray diffraction showed that films were nanocrystalline, while X-ray reflectivity studies found out films were very dense and exhibited a smooth surface morphology. Optical spectroscopy data shows that the films have high reflectivity (>90%) in the infrared region, characteristic of metallic behavior. Nanoindentation results indicated that films deposited under lower CH₄ pressures exhibited slightly higher nanohardness and Young modulus values than films deposited under higher pressures. As a result, tribological characterization revealed that these films exhibited relatively high wear resistance and steady-state friction coefficients on the order of μ = 0.4.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: unfunded

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1236229

Alternate ID(s):: OSTI ID: 22573182
OSTI ID: 1247552

Report Number(s):: SAND--2015-0364J; 562238

Journal Information:: Applied Surface Science, Journal Name: Applied Surface Science Journal Issue: C Vol. 352; ISSN 0169-4332

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (17)

Wear resistance of ZrC/TiN and ZrC/ZrN thin multilayers grown by pulsed laser deposition Craciun, D.; Socol, G.; Dorcioman, G. Applied Physics A, Vol. 110, Issue 3 https://doi.org/10.1007/s00339-012-7224-8	journal	September 2012
Residual stress measurement in textured thin film by grazing-incidence X-ray diffraction Ma, C. -H.; Huang, J. -H.; Chen, Haydn Thin Solid Films, Vol. 418, Issue 2 https://doi.org/10.1016/S0040-6090(02)00680-6	journal	October 2002
Chemical composition of ZrC thin films grown by pulsed laser deposition Craciun, D.; Socol, G.; Stefan, N. Applied Surface Science, Vol. 255, Issue 10 https://doi.org/10.1016/j.apsusc.2008.08.097	journal	March 2009
Wear tests of ZrC and ZrN thin films grown by pulsed laser deposition Dorcioman, G.; Socol, G.; Craciun, D. Applied Surface Science, Vol. 306 https://doi.org/10.1016/j.apsusc.2013.12.048	journal	July 2014
Phase composition, microstructure and mechanical properties of ZrC coatings produced by chemical vapor deposition Long, Ying; Javed, Athar; Chen, Jie Ceramics International, Vol. 40, Issue 1 https://doi.org/10.1016/j.ceramint.2013.06.059	journal	January 2014
Very hard ZrC thin films grown by pulsed laser deposition Craciun, V.; McCumiskey, E. J.; Hanna, M. Journal of the European Ceramic Society, Vol. 33, Issue 12 https://doi.org/10.1016/j.jeurceramsoc.2013.01.001	journal	October 2013
Properties of zirconium carbide for nuclear fuel applications Katoh, Yutai; Vasudevamurthy, Gokul; Nozawa, Takashi Journal of Nuclear Materials, Vol. 441, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2013.05.037	journal	October 2013
High-repetition rate pulsed laser deposition of ZrC thin films Craciun, D.; Socol, G.; Stefan, N. Surface and Coatings Technology, Vol. 203, Issue 8 https://doi.org/10.1016/j.surfcoat.2008.09.039	journal	January 2009
Thin and hard ZrC/TiN multilayers grown by pulsed laser deposition Craciun, D.; Bourne, G.; Zhang, J. Surface and Coatings Technology, Vol. 205, Issue 23-24 https://doi.org/10.1016/j.surfcoat.2011.06.017	journal	September 2011
Deposition and characterization of reactive magnetron sputtered zirconium carbide films Meng, Q. N.; Wen, M.; Mao, F. Surface and Coatings Technology, Vol. 232 https://doi.org/10.1016/j.surfcoat.2013.06.116	journal	October 2013
Wear resistant electrically conductive Au–ZnO nanocomposite coatings synthesized by e-beam evaporation Argibay, N.; Prasad, S. V.; Goeke, R. S. Wear, Vol. 302, Issue 1-2 https://doi.org/10.1016/j.wear.2013.01.049	journal	April 2013
Structure and composition of zirconium carbide thin-film grown by ion beam sputtering for optical applications Singh, Amol; Modi, Mohammed H.; Dhawan, Rajnish SOLID STATE PHYSICS: Proceedings of the 58th DAE Solid State Physics Symposium 2013, AIP Conference Proceedings https://doi.org/10.1063/1.4872785	conference	January 2014
Rietveld refinements performed on mesoporous ceria layers at grazing incidence Simeone, David; Baldinozzi, Gianguido; Gosset, Dominique Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811042294	journal	November 2011
Preparation and Characterization of Zirconium Carbide Coating on Coated Fuel Particles Liu, Chao; Liu, Bing; Shao, Youlin Journal of the American Ceramic Society, Vol. 90, Issue 11 https://doi.org/10.1111/j.1551-2916.2007.01965.x	journal	November 2007
Titanium nitride as a plasmonic material for visible and near-infrared wavelengths Naik, Gururaj V.; Schroeder, Jeremy L.; Ni, Xingjie Optical Materials Express, Vol. 2, Issue 4 https://doi.org/10.1364/OME.2.000478	journal	January 2012
An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments Oliver, W. C.; Pharr, G. M. Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583 https://doi.org/10.1557/JMR.1992.1564	journal	June 1992
Three-dimensional visualization of nanoscale structure and deformation McCumiskey, Edward J.; Rudawski, Nicholas G.; Sawyer, W. Gregory Journal of Materials Research, Vol. 28, Issue 18 https://doi.org/10.1557/jmr.2013.245	journal	September 2013

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77 NANOSCIENCE AND NANOTECHNOLOGY
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Optical and mechanical properties of nanocrystalline ZrC thin films grown by pulsed laser deposition.

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