Selective functionalization of the mesopores of SBA-15

Webb, Jonathan D.; Seki, Tomohiro; Goldston, Jennifer F.; Pruski, Marek; Crudden, Cathleen M.

doi:10.1016/j.micromeso.2014.10.032

Selective functionalization of the mesopores of SBA-15

Journal Article · Thu Oct 23 00:00:00 EDT 2014 · Microporous and Mesoporous Materials

DOI:https://doi.org/10.1016/j.micromeso.2014.10.032· OSTI ID:1227147

Webb, Jonathan D. ^[1]; Seki, Tomohiro ^[1]; Goldston, Jennifer F. ^[2]; Pruski, Marek ^[2]; Crudden, Cathleen M. ^[1]

Queen's Univ., Kingston, ON (Canada)
Iowa State Univ., Ames, IA (United States)

In this study, a method has been developed that permits the highly selective functionalization of the interior and exterior surfaces of the ubiquitous mesoporous material, SBA-15. The key step is reloading the as-synthesized material with structure-directing agent, Pluronic^® P123, prior to selective functionalization of the external surface with a silylating agent. This new approach represents a significant improvement over literature procedures. Results from physisorption analyses as well as solid-state NMR permit a detailed, quantitative assessment of functionalized SBA-15. This work also provides insight into the stability of the silyl layer during extraction procedures – an issue often neglected in other studies but of significant importance as decomposition of this layer could result in the introduction of new silanols and reduce the effectiveness of any selective grafting procedure.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1227147

Alternate ID(s):: OSTI ID: 1251429

Report Number(s):: IS-J--8587; PII: S138718111400612X

Journal Information:: Microporous and Mesoporous Materials, Journal Name: Microporous and Mesoporous Materials Journal Issue: C Vol. 203; ISSN 1387-1811

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
SBA-15
mesoporous silica
selective grafting
silylation
solid state NMR
surface functionalization

Selective functionalization of the mesopores of SBA-15

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References (55)

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