Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

One-step synthesis of mesoporous pentasil zeolite with single-unit-cell lamellar structural features

Patent ·
OSTI ID:1226009
A method for making a pentasil zeolite material includes forming an aqueous solution that includes a structure directing agent and a silica precursor; and heating the solution at a sufficient temperature and for sufficient time to form a pentasil zeolite material from the silica precursor, wherein the structure directing agent includes a quaternary phosphonium ion.
Research Organization:
Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001004
Assignee:
Regents of the University of Minnesota (Minneapolis, MN)
Patent Number(s):
9,180,413
Application Number:
13/288,595
OSTI ID:
1226009
Country of Publication:
United States
Language:
English

References (16)

Detailed investigation of the lattice structure of zeolite ZSM-11 by a combination of solid-state NMR and synchrotron x-ray diffraction techniques journal March 1989
Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor journal January 2008
Catalytic Behavior of Brønsted Acid Sites in MWW and MFI Zeolites with Dual Meso- and Microporosity journal December 2010
A New, Yet Familiar, Lamellar Zeolite journal March 2010
Oriented Molecular Sieve Membranes by Heteroepitaxial Growth journal November 2002
Sub-40 nm Zeolite Suspensions via Disassembly of Three-Dimensionally Ordered Mesoporous-Imprinted Silicalite-1 journal January 2011
The monoclinic framework structure of zeolite H-ZSM-5. Comparison with the orthorhombic framework of as-synthesized ZSM-5 journal April 1990
Pores by Pillaring: Not Always a Maze journal May 2008
Structure of the Silica Phase Extracted from Silica/(TPA)OH Solutions Containing Nanoparticles journal September 2003
Pure-Silica-Zeolite MEL Low- k Films from Nanoparticle Suspensions journal May 2005
Zeolite-β grown epitaxially on SSZ-31 nanofibers journal January 1999
Desilication: on the controlled generation of mesoporosity in MFI zeolites journal January 2006
Computed X-ray Powder Diffraction Patterns for Ultrasmall Zeolite Crystals journal April 1996
Pillared MFI Zeolite Nanosheets of a Single-Unit-Cell Thickness journal March 2010
Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity journal August 2006
Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts journal September 2009

Similar Records

Synthesis relationships and physicochemical properties of pentasil
Journal Article · Fri Dec 31 23:00:00 EST 1982 · Chem. Technol. Fuels Oils (Engl. Transl.); (United States) · OSTI ID:5799803

Spontaneous Pillaring of Pentasil Zeolites
Journal Article · Mon Apr 26 20:00:00 EDT 2021 · Advanced Materials · OSTI ID:1780538

One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent
Journal Article · Tue Jul 21 20:00:00 EDT 2015 · Chemical Science · OSTI ID:1344503