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Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices

Journal Article · · Journal of Vacuum Science and Technology B
DOI:https://doi.org/10.1116/1.4922627· OSTI ID:1224764
 [1];  [2]
  1. Alabama A&M Univ., Normal, AL (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)

Thin films of hafnium dioxide (HfO2) are widely used as the gate oxide in fabricating integrated circuits because of their high dielectric constants. In this paper, the authors report the growth of thin films of HfO2 using e-beam evaporation, and the fabrication of complementary metal-oxide semiconductor (CMOS) integrated circuits using this HfO2 thin film as the gate oxide. The authors analyzed the thin films using high-resolution transmission electron microscopy and electron diffraction, thereby demonstrating that the e-beam-evaporation-grown HfO2 film has a polycrystalline structure and forms an excellent interface with silicon. Accordingly, we fabricated 31-stage CMOS ring oscillator to test the quality of the HfO2 thin film as the gate oxide, and obtained excellent rail-to-rail oscillation waveforms from it, denoting that the HfO2 thin film functioned very well as the gate oxide.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI ID:
1224764
Report Number(s):
BNL--108477-2015-JA; KC0403020
Journal Information:
Journal of Vacuum Science and Technology B, Journal Name: Journal of Vacuum Science and Technology B Journal Issue: 4 Vol. 33; ISSN 2166-2746; ISSN JVTBD9
Publisher:
American Vacuum Society/AIPCopyright Statement
Country of Publication:
United States
Language:
English

References (15)

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High-K materials and metal gates for CMOS applications journal February 2015
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Integrated Circuits Based on Bilayer MoS2 Transistors journal January 2012
Effects of crystallization on the electrical properties of ultrathin HfO2 dielectrics grown by atomic layer deposition journal January 2003
Crystal structure and band gap determination of HfO2 thin films journal March 2007
Textured crystallization of ultrathin hafnium oxide films on silicon substrate journal April 2007
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High dielectric constant gate oxides for metal oxide Si transistors journal December 2005
Cramming More Components Onto Integrated Circuits journal January 1998
Atomic layer deposition of hafnium oxide and hafnium silicate thin films using liquid precursors and ozone
  • Senzaki, Yoshihide; Park, Seung; Chatham, Hood
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 22, Issue 4 https://doi.org/10.1116/1.1761186
journal July 2004
Thin-Film Transistor Fabricated in Single-Crystalline Transparent Oxide Semiconductor journal May 2003
Beyond the conventional transistor journal March 2002
ALD of Hafnium Oxide Thin Films from Tetrakis(ethylmethylamino)hafnium and Ozone journal January 2005

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