The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries

Bhadra, S; Hertzberg, BJ; Hsieh, AG; Croft, M; Gallaway, JW; Van Tassell, BJ; Chamoun, M; Erdonmez, C; Zhong, Z; Sholklapper, T; Steingart, DA

doi:10.1039/c5ta01576f

The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries

Journal Article · Thu Jan 01 04:00:00 EST 2015 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c5ta01576f· OSTI ID:1211289

Bhadra, S; Hertzberg, BJ; Hsieh, AG; Croft, M; Gallaway, JW; Van Tassell, BJ; Chamoun, M; Erdonmez, C; Zhong, Z; Sholklapper, T; Steingart, DA

The coefficient of restitution of alkaline batteries has been shown to increase as a function of depth of discharge. In this work, using non-destructive mechanical testing, the change in coefficient of restitution is compared to in situ energy-dispersive X-ray diffraction data to determine the cause of the macroscopic change in coefficient of restitution. The increase in coefficient of restitution correlates to the formation of a percolation pathway of ZnO within the anode of the cell, and the coefficient of restitution levels off at a value of 0.66 +/- 0.02 at 50% state of charge when the anode has densified into porous ZnO solid. Of note is the sensitivity of coefficient of restitution to the amount of ZnO formation that rivals the sensitivity of in situ energy-dispersive X-ray diffraction.

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: AR0000400

OSTI ID:: 1211289

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 18 Vol. 3; ISSN 2050-7488

Country of Publication:: United States

Language:: English

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Understanding the Dynamics of Primary Zn-MnO ₂ Alkaline Battery Gassing with Operando Visualization and Pressure Cells Faegh, Ehsan; Omasta, Travis; Hull, Matthew Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0321811jes	journal	January 2018
Understanding the Dynamics of Primary Zn-MnO₂ Alkaline Battery Gassing with Operando Visualization and Pressure Cells Faegh, Ehsan; Omasta, Travis J.; Hull, Matt ECS Meeting Abstracts, Vol. MA2018-01, Issue 1, 57 https://doi.org/10.1149/ma2018-01/1/57	journal	April 2018

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