The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries [Bouncing alkaline batteries: A basic solution]

Bhadra, S.; Hertzberg, B. J.; Croft, M.; Gallaway, J. W.; Van Tassell, B. J.; Chamoun, M.; Erdonmez, C.; Zhong, Z.; Steingart, D. A.

doi:10.1039/C5TA01576F

The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries [Bouncing alkaline batteries: A basic solution]

Journal Article · Fri Mar 13 04:00:00 EDT 2015 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C5TA01576F· OSTI ID:1183288

Bhadra, S. ^[1]; Hertzberg, B. J. ^[1]; Croft, M. ^[2]; Gallaway, J. W. ^[3]; Van Tassell, B. J. ^[4]; Chamoun, M. ^[5]; Erdonmez, C. ^[5]; Zhong, Z. ^[5]; Steingart, D. A. ^[1]

Princeton Univ., NJ (United States)
Rutgers Univ., Piscataway, NJ (United States)
City Univ. of New York Energy Inst., New York, NY (United States)
City College of New York, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

The coefficient of restitution of alkaline batteries had been shown to increase as a function of depth of discharge. In this work, using non-destructive mechanical testing, the change in coefficient of restitution is compared to in situ energy-dispersive x-ray diffraction data to determine the cause of the macroscopic change in coefficient of restitution. The increase in coefficient of restitution correlates to the formation of a percolation pathway of ZnO within the anode of the cell, and that the coefficient of restitution saturates at a value of 0.63 ± .05 at 50% state if charge when the anode has densified into porous ZnO solid. Of note is the sensitivity of coefficient of restitution to the amount of ZnO formation that rivals the sensitivity on in situ energy-dispersive x-ray diffraction spectroscopy.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

OSTI ID:: 1183288

Alternate ID(s):: OSTI ID: 1211289

Report Number(s):: BNL--107767-2015-JA; YN0100000

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 18 Vol. 3; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (26)

Energy absorption during compression and impact of dry elastic-plastic spherical granules Antonyuk, Sergiy; Heinrich, Stefan; Tomas, Jürgen Granular Matter, Vol. 12, Issue 1 https://doi.org/10.1007/s10035-009-0161-3	journal	January 2010
Investigation of impact of solid particles against hardmetal and cermet targets Hussainova, Irma; Kübarsepp, Jakob; Shcheglov, Igor Tribology International, Vol. 32, Issue 6 https://doi.org/10.1016/S0301-679X(99)00073-0	journal	June 1999
Evaluation of acoustic emission as a suitable tool for aging characterization of LiAl/LiMnO2 cell Kircheva, N.; Genies, S.; Chabrol, C. Electrochimica Acta, Vol. 88 https://doi.org/10.1016/j.electacta.2012.10.121	journal	January 2013
Effect of cycling rate, particle size and transport properties on lithium-ion cathode performance Du, Wenbo; Gupta, Amit; Zhang, Xiangchun International Journal of Heat and Mass Transfer, Vol. 53, Issue 17-18 https://doi.org/10.1016/j.ijheatmasstransfer.2010.04.017	journal	August 2010
The effect of compression on natural graphite anode performance and matrix conductivity Striebel, K. A.; Sierra, A.; Shim, J. Journal of Power Sources, Vol. 134, Issue 2 https://doi.org/10.1016/j.jpowsour.2004.03.052	journal	August 2004
Effects of cationic CTAB and anionic SDBS surfactants on the performance of Zn–MnO2 alkaline batteries Ghavami, Robab Khayat; Rafiei, Zahra; Tabatabaei, S. Mojtaba Journal of Power Sources, Vol. 164, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.10.084	journal	February 2007
Porous cathode optimization for lithium cells: Ionic and electronic conductivity, capacity, and selection of materials Chen, Y. -H.; Wang, C. -W.; Zhang, X. Journal of Power Sources, Vol. 195, Issue 9 https://doi.org/10.1016/j.jpowsour.2009.11.044	journal	May 2010
The role of mechanically induced separator creep in lithium-ion battery capacity fade Peabody, Christina; Arnold, Craig B. Journal of Power Sources, Vol. 196, Issue 19, p. 8147-8153 https://doi.org/10.1016/j.jpowsour.2011.05.023	journal	October 2011
A study of lithium ion intercalation induced fracture of silicon particles used as anode material in Li-ion battery Kalnaus, S.; Rhodes, K.; Daniel, C. Journal of Power Sources, Vol. 196, Issue 19, p. 8116-8124 https://doi.org/10.1016/j.jpowsour.2011.05.049	journal	October 2011
In situ investigation of the volume change and pulverization of hydride materials for Ni-MH batteries by concomitant generated force and acoustic emission measurements Etiemble, A.; Idrissi, H.; Meille, S. Journal of Power Sources, Vol. 205 https://doi.org/10.1016/j.jpowsour.2012.01.066	journal	May 2012
In situ atomic force microscopy studies on lithium (de)intercalation-induced morphology changes in LixCoO2 micro-machined thin film electrodes Park, Jonghyun; Kalnaus, Sergiy; Han, Sangwoo Journal of Power Sources, Vol. 222 https://doi.org/10.1016/j.jpowsour.2012.09.017	journal	January 2013
Ion transport restriction in mechanically strained separator membranes Cannarella, John; Arnold, Craig B. Journal of Power Sources, Vol. 226 https://doi.org/10.1016/j.jpowsour.2012.10.093	journal	March 2013
Numerical study of grain boundary effect on Li+ effective diffusivity and intercalation-induced stresses in Li-ion battery active materials Han, Sangwoo; Park, Jonghyun; Lu, Wei Journal of Power Sources, Vol. 240 https://doi.org/10.1016/j.jpowsour.2013.03.135	journal	October 2013
Stress evolution and capacity fade in constrained lithium-ion pouch cells Cannarella, John; Arnold, Craig B. Journal of Power Sources, Vol. 245 https://doi.org/10.1016/j.jpowsour.2013.06.165	journal	January 2014
Compressional Behavior of Bulk and Nanorod LiMn ₂ O ₄ under Nonhydrostatic Stress Lin, Yu; Yang, Yuan; Ma, Hongwei The Journal of Physical Chemistry C, Vol. 115, Issue 20 https://doi.org/10.1021/jp112289h	journal	May 2011
Real-time materials evolution visualized within intact cycling alkaline batteries Gallaway, Joshua W.; Erdonmez, Can K.; Zhong, Zhong J. Mater. Chem. A, Vol. 2, Issue 8 https://doi.org/10.1039/C3TA15169G	journal	January 2014
In situ investigation of the discharge of alkaline Zn–MnO2 batteries with synchrotron x-ray and neutron tomographies Manke, I.; Banhart, J.; Haibel, A. Applied Physics Letters, Vol. 90, Issue 21 https://doi.org/10.1063/1.2742283	journal	May 2007
Novel cell design for combined in situ acoustic emission and x-ray diffraction study during electrochemical cycling of batteries Rhodes, Kevin; Kirkham, Melanie; Meisner, Roberta Review of Scientific Instruments, Vol. 82, Issue 7 https://doi.org/10.1063/1.3607961	journal	July 2011
Elastic properties of zinc: A compilation and a review Ledbetter, H. M. Journal of Physical and Chemical Reference Data, Vol. 6, Issue 4 https://doi.org/10.1063/1.555564	journal	October 1977
Listening to the coefficient of restitution - revisited Stensgaard, I.; Lægsgaard, E. American Journal of Physics, Vol. 69, Issue 3 https://doi.org/10.1119/1.1326077	journal	March 2001
Visualization and Quantification of Electrochemical and Mechanical Degradation in Li Ion Batteries Ebner, M.; Marone, F.; Stampanoni, M. Science, Vol. 342, Issue 6159 https://doi.org/10.1126/science.1241882	journal	October 2013
Morphology and Spatial Distribution of ZnO Formed in Discharged Alkaline Zn/MnO[sub 2] AA Cells Horn, Quinn C.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 150, Issue 5 https://doi.org/10.1149/1.1566014	journal	January 2003
In Situ Microtomographic Monitoring of Discharging Processes in Alkaline Cells Haibel, A.; Manke, I.; Melzer, A. Journal of The Electrochemical Society, Vol. 157, Issue 4 https://doi.org/10.1149/1.3294566	journal	January 2010
Effects of Sonication on EIS Results for Zinc Alkaline Batteries Dornbusch, D. A.; Hilton, R.; Gordon, M. J. ECS Electrochemistry Letters, Vol. 2, Issue 9 https://doi.org/10.1149/2.006309eel	journal	January 2013
Coupling Phenomena between Zinc Surface Morphological Variations and Ionic Mass Transfer Rate in Alkaline Solution Arise, I.; Kawai, S.; Fukunaka, Y. Journal of The Electrochemical Society, Vol. 160, Issue 2 https://doi.org/10.1149/2.083302jes	journal	December 2012
Compression behavior of manganite Suzuki, Akio Journal of Mineralogical and Petrological Sciences, Vol. 108, Issue 5 https://doi.org/10.2465/jmps.130621b	journal	January 2013

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Understanding the Dynamics of Primary Zn-MnO ₂ Alkaline Battery Gassing with Operando Visualization and Pressure Cells Faegh, Ehsan; Omasta, Travis; Hull, Matthew Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0321811jes	journal	January 2018
Understanding the Dynamics of Primary Zn-MnO₂ Alkaline Battery Gassing with Operando Visualization and Pressure Cells Faegh, Ehsan; Omasta, Travis J.; Hull, Matt ECS Meeting Abstracts, Vol. MA2018-01, Issue 1, 57 https://doi.org/10.1149/ma2018-01/1/57	journal	April 2018

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