Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

High efficiency organic photovoltaic cells employing hybridized mixed-planar heterojunctions

Patent ·
OSTI ID:1210224
A device is provided, having a first electrode, a second electrode, and a photoactive region disposed between the first electrode and the second electrode. The photoactive region includes a first photoactive organic layer that is a mixture of an organic acceptor material and an organic donor material, wherein the first photoactive organic layer has a thickness not greater than 0.8 characteristic charge transport lengths; a second photoactive organic layer in direct contact with the first organic layer, wherein the second photoactive organic layer is an unmixed layer of the organic acceptor material of the first photoactive organic layer, and the second photoactive organic layer has a thickness not less than about 0.1 optical absorption lengths; and a third photoactive organic layer disposed between the first electrode and the second electrode and in direct contact with the first photoactive organic layer. The third photoactive organic layer is an unmixed layer of the organic donor layer of the first photoactive organic layer and has a thickness not less than about 0.1 optical absorption lengths.
Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC36-99GO10337
Assignee:
The Trustees of Princeton University (Princeton, NJ)
Patent Number(s):
9,112,164
Application Number:
14/068,430
OSTI ID:
1210224
Country of Publication:
United States
Language:
English

References (39)

Organic small molecule solar cells with a homogeneously mixed copper phthalocyanine: C60 active layer journal May 2004
4.2% efficient organic photovoltaic cells with low series resistances journal April 2004
Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions journal December 1995
Modeling of thin film solar cells: Uniform field approximation journal December 1983
Effects of Postproduction Treatment on Plastic Solar Cells journal January 2003
The effect of fullerene doping on photoelectric conversion using titanyl phthalocyanine and a perylene pigment journal February 2000
Two‐layer organic photovoltaic cell journal January 1986
Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells journal July 2001
Study of localized and extended excitons in 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) II. Photocurrent response at low electric fields journal October 1996
Photoluminescence quenching at a p o l y t h i o p h e n e / C 60 heterojunction journal May 2000
Three‐layered organic solar cell with a photoactive interlayer of codeposited pigments journal March 1991
Photoluminescence quenching of Alq3 by metal deposition: A surface analytical investigation
  • Choong, V.-E.; Park, Y.; Gao, Y.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 16, Issue 3, p. 1838-1841 https://doi.org/10.1116/1.581115
journal May 1998
Exciton diffusion and optical interference in organic donor–acceptor photovoltaic cells journal October 2001
Variable range hopping as possible origin of a universal relation between conductivity and mobility in disordered organic semiconductors journal December 2002
Monochromatic versus solar efficiencies of organic solar cells journal February 2000
Long-Range Singlet Energy Transfer in Perylene Bis(phenethylimide) Films journal July 1997
Exciton diffusion and dissociation in a poly(p‐phenylenevinylene)/C60 heterojunction photovoltaic cell journal May 1996
Photovoltaic yield from exciton dissociation in organic dye layers journal January 1999
p‐i‐n like behavior in three‐layered organic solar cells having a co‐deposited interlayer of pigments journal October 1992
Weak intrinsic charge transfer complexes: A new route for developing wide spectrum organic photovoltaic cells journal January 2002
Relationship between electroluminescence and current transport in organic heterojunction light‐emitting devices journal May 1996
Exciton Migration and Cathode Quenching in Organic Light Emitting Diodes journal May 2000
Efficient photodiodes from interpenetrating polymer networks journal August 1995
Amorphous silicon alloy photovoltaic research—present and future journal January 2000
Ultrathin Organic Films Grown by Organic Molecular Beam Deposition and Related Techniques journal October 1997
2.5% efficient organic plastic solar cells journal February 2001
Low-band-gap, sublimable rhenium(I) diimine complex for efficient bulk heterojunction photovoltaic devices journal April 2004
Synthesis and aggregation behavior of hosts containing phthalocyanine and crown ether subunits journal July 1987
Carrier transport in multilayer organic photodetectors: II. Effects of anode preparation journal February 2004
Modeling photocurrent action spectra of photovoltaic devices based on organic thin films journal July 1999
Molecular level control of donor/acceptor heterostructuresin organic photovoltaic devices journal July 2004
High efficiency organic solar cells based on single or multiple PIN structures journal March 2004
Organic p-i-n solar cells journal June 2004
Influence of codeposition on the performance of CuPc–C60 heterojunction photovoltaic devices journal February 2004
Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films journal September 2003
High photovoltage multiple-heterojunction organic solar cells incorporating interfacial metallic nanoclusters journal March 2002
Small molecular weight organic thin-film photodetectors and solar cells journal April 2003
Bulk-heterojunction photovoltaic devices based on donor–acceptor organic small molecule blends journal August 2003
Highly efficient p–i–n type organic photovoltaic devices journal March 2004

Similar Records

High efficiency organic photovoltaic cells employing hybridized mixed-planar heterojunctions
Patent · Mon Nov 18 23:00:00 EST 2013 · OSTI ID:1108716

Hybrid planar-mixed heterojunction for organic photovoltaics
Patent · Tue Sep 14 00:00:00 EDT 2021 · OSTI ID:1840450

Organic photovoltaic cells utilizing ultrathin sensitizing layer
Patent · Tue May 24 00:00:00 EDT 2011 · OSTI ID:1019536

Related Subjects