Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

Axnanda, Stephanus; Crumlin, Ethan J.; Mao, Baohua; Rani, Sana; Chang, Rui; Karlsson, Patrik G.; Edwards, Mårten O. M.; Lundqvist, Måns; Moberg, Robert; Ross, Phil; Hussain, Zahid; Liu, Zhi

doi:10.1038/srep09788

Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

Journal Article · Thu May 07 00:00:00 EDT 2015 · Scientific Reports

DOI:https://doi.org/10.1038/srep09788· OSTI ID:1187106

Axnanda, Stephanus ^[1]; Crumlin, Ethan J. ^[1]; Mao, Baohua ^[2]; Rani, Sana ^[1]; Chang, Rui ^[2]; Karlsson, Patrik G. ^[3]; Edwards, Mårten O. M. ^[3]; Lundqvist, Måns ^[3]; Moberg, Robert ^[3]; Ross, Phil ^[1]; Hussain, Zahid ^[1]; Liu, Zhi ^[4]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China)
VG Scienta,Uppsala (Sweden)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Shanghai Tech Univ., Shanghai (China)

We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²⁺ and Pt⁴⁺ interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1187106

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 5 Vol. 5; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (62)

A Reactive Oxide Overlayer on Rhodium Nanoparticles during CO Oxidation and Its Size Dependence Studied by In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy Grass, Michael E.; Zhang, Yawen; Butcher, Derek R. Angewandte Chemie International Edition, Vol. 47, Issue 46 https://doi.org/10.1002/anie.200803574	journal	November 2008
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia Angewandte Chemie International Edition, Vol. 52, Issue 19 https://doi.org/10.1002/anie.201210077	journal	April 2013
In Situ Study of the Gas-Phase Electrolysis of Water on Platinum by NAP-XPS Arrigo, Rosa; Hävecker, Michael; Schuster, Manfred E. Angewandte Chemie International Edition, Vol. 52, Issue 44 https://doi.org/10.1002/anie.201304765	journal	September 2013
An ESCA Study on the Electrochemical Double Layer of Emersed Electrodes Kolb, P. M.; Rath, D. L.; Wille, R. Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 87, Issue 12 https://doi.org/10.1002/bbpc.19830871206	journal	December 1983
Quantitative electron spectroscopy of surfaces: A standard data base for electron inelastic mean free paths in solids Seah, M. P.; Dench, W. A. Surface and Interface Analysis, Vol. 1, Issue 1 https://doi.org/10.1002/sia.740010103	journal	February 1979
Electron transport in solids for quantitative surface analysis Werner, Wolfgang S. M. Surface and Interface Analysis, Vol. 31, Issue 3 https://doi.org/10.1002/sia.973	journal	January 2001
X-ray photoelectron spectroscopy and electron microscopy of Pt$z.sbnd;Rh gauzes used for catalytic oxidation of ammonia Contour, J. Journal of Catalysis, Vol. 48, Issue 1-3 https://doi.org/10.1016/0021-9517(77)90093-8	journal	June 1977
Ambient-pressure photoelectron spectroscopy for heterogeneous catalysis and electrochemistry Kaya, Sarp; Ogasawara, Hirohito; Näslund, Lars-Åke Catalysis Today, Vol. 205 https://doi.org/10.1016/j.cattod.2012.08.005	journal	April 2013
Photoelectron spectroscopy under ambient pressure and temperature conditions Frank Ogletree, D.; Bluhm, Hendrik; Hebenstreit, Eleonore D. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 601, Issue 1-2 https://doi.org/10.1016/j.nima.2008.12.155	journal	March 2009
ESCA study of sputtered platinum films Bancroft, G. Michael.; Adams, Ian.; Coatsworth, Leighton L. Analytical Chemistry, Vol. 47, Issue 3 https://doi.org/10.1021/ac60353a050	journal	March 1975
Surface Chemistry of Late Transition Metal Oxides Weaver, Jason F. Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300323w	journal	December 2012
Electronic Effects in the Electric Double Layer Schmickler, Wolfgang Chemical Reviews, Vol. 96, Issue 8 https://doi.org/10.1021/cr940408c	journal	January 1996
Electron spectroscopy of platinum-oxygen surfaces and application to electrochemical studies Kim, K. S.; Winograd, N.; Davis, R. E. Journal of the American Chemical Society, Vol. 93, Issue 23 https://doi.org/10.1021/ja00752a065	journal	November 1971
In Situ Oxidation Study of Pt(110) and Its Interaction with CO Butcher, Derek R.; Grass, Michael E.; Zeng, Zhenhua Journal of the American Chemical Society, Vol. 133, Issue 50 https://doi.org/10.1021/ja207261s	journal	December 2011
Mechanistic Studies of Water Electrolysis and Hydrogen Electro-Oxidation on High Temperature Ceria-Based Solid Oxide Electrochemical Cells Zhang, Chunjuan; Yu, Yi; Grass, Michael E. Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja402604u	journal	July 2013
Different Reactivity of the Various Platinum Oxides and Chemisorbed Oxygen in CO Oxidation on Pt(111) Miller, Daniel; Sanchez Casalongue, Hernan; Bluhm, Hendrik Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja413125q	journal	April 2014
Methanol Oxidation on a Copper Catalyst Investigated Using in Situ X-ray Photoelectron Spectroscopy ^† Bluhm, Hendrik; Hävecker, Michael; Knop-Gericke, Axel The Journal of Physical Chemistry B, Vol. 108, Issue 38 https://doi.org/10.1021/jp040080j	journal	September 2004
In Situ Characterization of Ceria Oxidation States in High-Temperature Electrochemical Cells with Ambient Pressure XPS DeCaluwe, Steven C.; Grass, Michael E.; Zhang, Chunjuan The Journal of Physical Chemistry C, Vol. 114, Issue 46 https://doi.org/10.1021/jp107694z	journal	November 2010
In Situ Characterizations of Nanostructured SnO _x /Pt(111) Surfaces Using Ambient-Pressure XPS (APXPS) and High-Pressure Scanning Tunneling Microscopy (HPSTM) Axnanda, Stephanus; Zhu, Zhongwei; Zhou, Weiping The Journal of Physical Chemistry C, Vol. 118, Issue 4 https://doi.org/10.1021/jp409272j	journal	January 2014
Influence of Hydrocarbon and CO ₂ on the Reversibility of Li–O ₂ Chemistry Using In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Lu, Yi-Chun; Crumlin, Ethan J.; Carney, Thomas J. The Journal of Physical Chemistry C, Vol. 117, Issue 49 https://doi.org/10.1021/jp409453s	journal	December 2013
Formation of Nanometer-Sized Surface Platinum Oxide Clusters on a Stepped Pt(557) Single Crystal Surface Induced by Oxygen: A High-Pressure STM and Ambient-Pressure XPS Study Zhu, Zhongwei; Tao, Franklin (Feng); Zheng, Fan Nano Letters, Vol. 12, Issue 3 https://doi.org/10.1021/nl204242s	journal	February 2012
Measure of Surface Potential at the Aqueous–Oxide Nanoparticle Interface by XPS from a Liquid Microjet Brown, Matthew A.; Beloqui Redondo, Amaia; Sterrer, Martin Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl402957y	journal	October 2013
Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy Zhang, Chunjuan; Grass, Michael E.; McDaniel, Anthony H. Nature Materials, Vol. 9, Issue 11 https://doi.org/10.1038/nmat2851	journal	September 2010
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy Starr, D. E.; Liu, Z.; Hävecker, M. Chemical Society Reviews, Vol. 42, Issue 13 https://doi.org/10.1039/c3cs60057b	journal	January 2013
Ellipsometric Study of Oxygen‐Containing Films on Platinum Anodes Reddy, A. K. N.; Genshaw, M. A.; Bockris, J. O'M. The Journal of Chemical Physics, Vol. 48, Issue 2 https://doi.org/10.1063/1.1668699	journal	January 1968
Kinetics of CO oxidation on high-concentration phases of atomic oxygen on Pt(111) Gerrard, Alex L.; Weaver, Jason F. The Journal of Chemical Physics, Vol. 123, Issue 22 https://doi.org/10.1063/1.2126667	journal	December 2005
New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2 Grass, Michael E.; Karlsson, Patrik G.; Aksoy, Funda Review of Scientific Instruments, Vol. 81, Issue 5 https://doi.org/10.1063/1.3427218	journal	May 2010
In situ x-ray photoelectron spectroscopy for electrochemical reactions in ordinary solvents Masuda, Takuya; Yoshikawa, Hideki; Noguchi, Hidenori Applied Physics Letters, Vol. 103, Issue 11 https://doi.org/10.1063/1.4821180	journal	September 2013
In situ study of an oxidation reaction on a Pt/C electrode by ambient pressure hard X-ray photoelectron spectroscopy Takagi, Yasumasa; Wang, Heng; Uemura, Yohei Applied Physics Letters, Vol. 105, Issue 13 https://doi.org/10.1063/1.4897007	journal	September 2014
Oxidation of Pt(111) under Near-Ambient Conditions Miller, D. J.; Öberg, H.; Kaya, S. Physical Review Letters, Vol. 107, Issue 19 https://doi.org/10.1103/physrevlett.107.195502	journal	November 2011
Influence of the Local Surface Structure on the 5 p Photoemission of Adsorbed Xenon Küppers, J.; Wandelt, K.; Ertl, G. Physical Review Letters, Vol. 43, Issue 13 https://doi.org/10.1103/physrevlett.43.928	journal	September 1979
Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles Tao, F.; Grass, M. E.; Zhang, Y. Science, Vol. 322, Issue 5903 https://doi.org/10.1126/science.1164170	journal	November 2008
Break-Up of Stepped Platinum Catalyst Surfaces by High CO Coverage Tao, F.; Dag, S.; Wang, L. -W. Science, Vol. 327, Issue 5967 https://doi.org/10.1126/science.1182122	journal	February 2010
Accurate Electron Inelastic Cross Sections and Stopping Powers for Liquid Water over the 0.1-10 keV Range Based on an Improved Dielectric Description of the Bethe Surface Emfietzoglou, D.; Nikjoo, H. Radiation Research, Vol. 167, Issue 1 https://doi.org/10.1667/rr0551.1	journal	January 2007
A Reactive Oxide Overlayer on Rhodium Nanoparticles during CO Oxidation and Its Size Dependence Studied by In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy Grass, Michael E.; Zhang, Yawen; Butcher, Derek R. Angewandte Chemie, Vol. 120, Issue 46 https://doi.org/10.1002/ange.200803574	journal	November 2008
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia Angewandte Chemie, Vol. 125, Issue 19 https://doi.org/10.1002/ange.201210077	journal	April 2013
Simulation of electron spectra for surface analysis (SESSA): a novel software tool for quantitative Auger-electron spectroscopy and X-ray photoelectron spectroscopy Smekal, Werner; Werner, Wolfgang S. M.; Powell, Cedric J. Surface and Interface Analysis, Vol. 37, Issue 11 https://doi.org/10.1002/sia.2097	journal	January 2005
An analytical SEM and XPS study of platinum-rhodium gauzes used in high pressure ammonia burners Fierro, J. L. G.; Palacios, J. M.; Tomas, F. Surface and Interface Analysis, Vol. 13, Issue 1 https://doi.org/10.1002/sia.740130107	journal	October 1988
Effect of pretreatment on a platinized tin oxide catalyst used for low-temperature Co oxidation Drawdy, Jean E.; Hoflund, Gar B.; Gardner, Steven D. Surface and Interface Analysis, Vol. 16, Issue 1-12 https://doi.org/10.1002/sia.740160178	journal	July 1990
Electrochemical Equilibria Pourbaix, Marcel; Staehle, Roger W.; Pourbaix, Marcel Lectures on Electrochemical Corrosion, p 83-183 https://doi.org/10.1007/978-1-4684-1806-4_4	book	January 1973
Photoelectron Spectroscopy Hüfner, Stefan Springer Series in Solid-State Sciences https://doi.org/10.1007/978-3-662-03150-6	book	January 1995
Photoelectron Spectroscopy Hüfner, Stefan Advanced Texts in Physics https://doi.org/10.1007/978-3-662-09280-4	book	January 2003
Observation of systematic electrochemically induced binding energy shift in the XPS spectra of emersed Cs+ double layer species D'Agostino, Alfred T.; Hansen, Wilford N. Surface Science, Vol. 165, Issue 1 https://doi.org/10.1016/0039-6028(86)90674-6	journal	January 1986
Ultra-high vacuum techniques in the study of single-crystal electrode surfaces Soriaga, Manuel P. Progress in Surface Science, Vol. 39, Issue 4 https://doi.org/10.1016/0079-6816(92)90016-B	journal	April 1992
Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103 Yeh, J. J.; Lindau, I. Atomic Data and Nuclear Data Tables, Vol. 32, Issue 1 https://doi.org/10.1016/0092-640X(85)90016-6	journal	January 1985
Observation of systematic electrochemically induced binding energy shift in the XPS spectra of emersed Cs+ double layer species D'Agostino, Alfred T.; Hansen, Wilford N. Surface Science Letters, Vol. 165, Issue 1 https://doi.org/10.1016/0167-2584(86)91168-0	journal	January 1986
An ESCA study on emersed electrodes Hansen, W. N.; Kolb, D. M.; Rath, D. L. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 110, Issue 1-3 https://doi.org/10.1016/S0022-0728(80)80391-3	journal	July 1980
Surface science studies of model fuel cell electrocatalysts Markovic, N. Surface Science Reports, Vol. 45, Issue 4-6 https://doi.org/10.1016/S0167-5729(01)00022-X	journal	April 2002
In situ investigation of electrochemical devices using ambient pressure photoelectron spectroscopy Crumlin, Ethan J.; Bluhm, Hendrik; Liu, Zhi Journal of Electron Spectroscopy and Related Phenomena, Vol. 190 https://doi.org/10.1016/j.elspec.2013.03.002	journal	October 2013
Ambient pressure photoelectron spectroscopy: A new tool for surface science and nanotechnology Salmeron, M.; Schlogl, R. Surface Science Reports, Vol. 63, Issue 4 https://doi.org/10.1016/j.surfrep.2008.01.001	journal	April 2008
Multielement Activity Mapping and Potential Mapping in Solid Oxide Electrochemical Cells through the use of operando XPS Zhang, Chunjuan; Grass, Michael E.; Yu, Yi ACS Catalysis, Vol. 2, Issue 11 https://doi.org/10.1021/cs3004243	journal	September 2012
Electron spectroscopy for chemical analysis of liquids and solutions Siegbahn, Hans The Journal of Physical Chemistry, Vol. 89, Issue 6 https://doi.org/10.1021/j100252a005	journal	March 1985
In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions Lu, Yi-Chun; Crumlin, Ethan J.; Veith, Gabriel M. Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00715	journal	October 2012
Measuring individual overpotentials in an operating solid-oxide electrochemical cell El Gabaly, Farid; Grass, Michael; McDaniel, Anthony H. Physical Chemistry Chemical Physics, Vol. 12, Issue 38 https://doi.org/10.1039/C003581E	journal	January 2010
Measuring individual overpotentials in an operating solid-oxide electrochemical cell El Gabaly, Farid; Grass, Michael; McDaniel, Anthony H. Physical Chemistry Chemical Physics, Vol. 12, Issue 38 https://doi.org/10.1039/c003581e	journal	January 2010
A differentially pumped electrostatic lens system for photoemission studies in the millibar range Ogletree, D. Frank; Bluhm, Hendrik; Lebedev, Gennadi Review of Scientific Instruments, Vol. 73, Issue 11 https://doi.org/10.1063/1.1512336	journal	November 2002
A few selected applications of surface nonlinear optical spectroscopy. Shen, Y. R. Proceedings of the National Academy of Sciences, Vol. 93, Issue 22 https://doi.org/10.1073/pnas.93.22.12104	journal	October 1996
In situ x-ray photoelectron spectroscopy studies of water on metals and oxides at ambient conditions Yamamoto, S.; Bluhm, H.; Andersson, K. Journal of Physics: Condensed Matter, Vol. 20, Issue 18 https://doi.org/10.1088/0953-8984/20/18/184025	journal	April 2008
Oxidation of Pt(111) under Near-Ambient Conditions Miller, D. J.; Öberg, H.; Kaya, S. Physical Review Letters, Vol. 107, Issue 19 https://doi.org/10.1103/PhysRevLett.107.195502	journal	November 2011
Influence of the Local Surface Structure on the 5 p Photoemission of Adsorbed Xenon Küppers, J.; Wandelt, K.; Ertl, G. Physical Review Letters, Vol. 43, Issue 13 https://doi.org/10.1103/PhysRevLett.43.928	journal	September 1979
UHV Techniques in the Study of Electrode Surfaces Kolb, D. M. Zeitschrift für Physikalische Chemie, Vol. 154, Issue Part_1_2 https://doi.org/10.1524/zpch.1987.154.Part_1_2.179	journal	January 1987
Accurate Electron Inelastic Cross Sections and Stopping Powers for Liquid Water over the 0.1-10 keV Range Based on an Improved Dielectric Description of the Bethe Surface Emfietzoglou, D.; Nikjoo, H. Radiation Research, Vol. 167, Issue 1 https://doi.org/10.1667/RR0551.1	journal	January 2007

Cited By (44)

Nanocarbon-Edge-Anchored High-Density Pt Atoms for 3-nitrostyrene Hydrogenation: Strong Metal-Carbon Interaction Lou, Yang; Wu, Honglu; Liu, Jingyue iScience, Vol. 13 https://doi.org/10.1016/j.isci.2019.02.016	journal	March 2019
The Oxidation of Platinum under Wet Conditions Observed by Electrochemical X-ray Photoelectron Spectroscopy Mom, Rik; Frevel, Lorenz; Velasco-Vélez, Juan-Jesús Journal of the American Chemical Society, Vol. 141, Issue 16 https://doi.org/10.1021/jacs.8b12284	journal	March 2019
Unravelling the electrochemical double layer by direct probing of the solid/liquid interface Favaro, Marco; Jeong, Beomgyun; Ross, Philip N. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12695	journal	August 2016
Probing a battery electrolyte drop with ambient pressure photoelectron spectroscopy Maibach, Julia; Källquist, Ida; Andersson, Margit Karlsruhe https://doi.org/10.5445/ir/1000096844	text	January 2019
Electronic Structure Characterization of Soft Semiconductors Liu, Xianjie; Fahlman, Mats Advanced Materials Interfaces https://doi.org/10.1002/admi.201900439	journal	June 2019
NiFe-Based (Oxy)hydroxide Catalysts for Oxygen Evolution Reaction in Non-Acidic Electrolytes Dionigi, Fabio; Strasser, Peter Advanced Energy Materials, Vol. 6, Issue 23 https://doi.org/10.1002/aenm.201600621	journal	July 2016
Electrode Architecture in Galvanic and Electrolytic Energy Cells Jeong, Beomgyun; Ocon, Joey D.; Lee, Jaeyoung Angewandte Chemie International Edition, Vol. 55, Issue 16 https://doi.org/10.1002/anie.201507780	journal	March 2016
Ambient Pressure Photoelectron Spectroscopy: Opportunities in Catalysis from Solids to Liquids and Introducing Time Resolution Roy, Kanak; Artiglia, Luca; van Bokhoven, Jeroen A. ChemCatChem, Vol. 10, Issue 4 https://doi.org/10.1002/cctc.201701522	journal	January 2018
In‐Situ/Operando X‐ray Characterization of Metal Hydrides Liu, Yi‐Sheng; Jeong, Sohee; White, James L. ChemPhysChem, Vol. 20, Issue 10 https://doi.org/10.1002/cphc.201801185	journal	March 2019
External RBS analysis setup at University of Göttingen: RBS analysis for liquid samples Saito, M.; Holm, K.; Bregolin, F. L. Surface and Interface Analysis, Vol. 50, Issue 11 https://doi.org/10.1002/sia.6396	journal	February 2018
Single-Atom Electrocatalysts for Water Splitting Guimaraes, Robson R.; Gonçalves, Josue M.; Björneholm, Olle Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 67-111 https://doi.org/10.1007/978-3-030-27161-9_3	book	January 2020
In Situ Electrochemical Cells to Study the Oxygen Evolution Reaction by Near Ambient Pressure X-ray Photoelectron Spectroscopy Streibel, Verena; Hävecker, Michael; Yi, Youngmi Topics in Catalysis, Vol. 61, Issue 20 https://doi.org/10.1007/s11244-018-1061-8	journal	October 2018
Stabilizing the Meniscus for Operando Characterization of Platinum During the Electrolyte-Consuming Alkaline Oxygen Evolution Reaction Stoerzinger, Kelsey A.; Favaro, Marco; Ross, Philip N. Topics in Catalysis, Vol. 61, Issue 20 https://doi.org/10.1007/s11244-018-1063-6	journal	October 2018
Various spectroelectrochemical cells for in situ observation of electrochemical processes at solid–liquid interfaces Masuda, Takuya Topics in Catalysis, Vol. 61, Issue 20 https://doi.org/10.1007/s11244-018-1067-2	journal	October 2018
Speciation and Electronic Structure of La1−xSrxCoO3−δ During Oxygen Electrolysis Stoerzinger, Kelsey A.; Renshaw Wang, Xiao; Hwang, Jonathan Topics in Catalysis, Vol. 61, Issue 20 https://doi.org/10.1007/s11244-018-1070-7	journal	October 2018
An APXPS endstation for gas–solid and liquid–solid interface studies at SSRF Cai, Jun; Dong, Qiao; Han, Yong Nuclear Science and Techniques, Vol. 30, Issue 5 https://doi.org/10.1007/s41365-019-0608-0	journal	April 2019
Probing a battery electrolyte drop with ambient pressure photoelectron spectroscopy Maibach, Julia; Källquist, Ida; Andersson, Margit Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10803-y	journal	July 2019
Multiphase carbon mineralization for the reactive separation of CO2 and directed synthesis of H2 Gadikota, Greeshma Nature Reviews Chemistry, Vol. 4, Issue 2 https://doi.org/10.1038/s41570-019-0158-3	journal	January 2020
Direct observation of the energetics at a semiconductor/liquid junction by operando X-ray photoelectron spectroscopy Lichterman, Michael F.; Hu, Shu; Richter, Matthias H. Energy & Environmental Science, Vol. 8, Issue 8 https://doi.org/10.1039/c5ee01014d	journal	January 2015
Interfacial band-edge energetics for solar fuels production Smith, Wilson A.; Sharp, Ian D.; Strandwitz, Nicholas C. Energy & Environmental Science, Vol. 8, Issue 10 https://doi.org/10.1039/c5ee01822f	journal	January 2015
Aqueous solution/metal interfaces investigated in operando by photoelectron spectroscopy Karslıoğlu, O.; Nemšák, S.; Zegkinoglou, I. Faraday Discussions, Vol. 180 https://doi.org/10.1039/c5fd00003c	journal	January 2015
Frontiers of water oxidation: the quest for true catalysts Li, J.; Güttinger, R.; Moré, R. Chemical Society Reviews, Vol. 46, Issue 20 https://doi.org/10.1039/c7cs00306d	journal	January 2017
Molecular species forming at the α-Fe ₂ O ₃ nanoparticle–aqueous solution interface Ali, Hebatallah; Seidel, Robert; Pohl, Marvin N. Chemical Science, Vol. 9, Issue 19 https://doi.org/10.1039/c7sc05156e	journal	January 2018
Self-organization of porous anodic alumina films studied in situ by grazing-incidence transmission small-angle X-ray scattering Evertsson, Jonas; Vinogradov, Nikolay A.; Harlow, Gary S. RSC Advances, Vol. 8, Issue 34 https://doi.org/10.1039/c8ra02913j	journal	January 2018
Electronic structure of aqueous-phase anatase titanium dioxide nanoparticles probed by liquid jet photoelectron spectroscopy Ali, Hebatallah; Seidel, Robert; Bergmann, Arno Journal of Materials Chemistry A, Vol. 7, Issue 12 https://doi.org/10.1039/c8ta09414d	journal	January 2019
2D oxides on metal materials: concepts, status, and perspectives Barcaro, Giovanni; Fortunelli, Alessandro Physical Chemistry Chemical Physics, Vol. 21, Issue 22 https://doi.org/10.1039/c9cp00972h	journal	January 2019
The effect of grain size on the hydration of BaZr _0.9 Y _0.1 O _3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy Jarry, Angelique; Jackson, Gregory S.; Crumlin, Ethan J. Physical Chemistry Chemical Physics, Vol. 22, Issue 1 https://doi.org/10.1039/c9cp04335g	journal	January 2020
Atmospheric pressure X-ray photoelectron spectroscopy apparatus: Bridging the pressure gap Velasco-Vélez, J. J.; Pfeifer, V.; Hävecker, M. Review of Scientific Instruments, Vol. 87, Issue 5 https://doi.org/10.1063/1.4951724	journal	May 2016
Advances in liquid phase soft-x-ray photoemission spectroscopy: A new experimental setup at BESSY II Seidel, Robert; Pohl, Marvin N.; Ali, Hebatallah Review of Scientific Instruments, Vol. 88, Issue 7 https://doi.org/10.1063/1.4990797	journal	July 2017
Revealing the formation dynamics of the electric double layer by means of in - situ Rutherford backscattering spectrometry Khojasteh, Nasrin B.; Apelt, Sabine; Bergmann, Ute Review of Scientific Instruments, Vol. 90, Issue 8 https://doi.org/10.1063/1.5100216	journal	August 2019
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars Amann, Peter; Degerman, David; Lee, Ming-Tao Review of Scientific Instruments, Vol. 90, Issue 10 https://doi.org/10.1063/1.5109321	journal	October 2019
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission Hävecker, Michael; Düngen, Pascal; Buller, Saskia Catalysis, Structure & Reactivity, Vol. 3, Issue 1-2 https://doi.org/10.1080/2055074x.2017.1287535	journal	March 2017
Ambient pressure photoelectron spectroscopy: Practical considerations and experimental frontiers Trotochaud, Lena; Head, Ashley R.; Karslıoğlu, Osman Journal of Physics: Condensed Matter, Vol. 29, Issue 5 https://doi.org/10.1088/1361-648x/29/5/053002	journal	December 2016
The offset droplet: a new methodology for studying the solid/water interface using x-ray photoelectron spectroscopy Booth, S. G.; Tripathi, A. M.; Strashnov, I. Journal of Physics: Condensed Matter, Vol. 29, Issue 45 https://doi.org/10.1088/1361-648x/aa8b92	journal	October 2017
Beyond Koopmans’ theorem: electron binding energies in disordered materials Muchová, Eva; Slavíček, Petr Journal of Physics: Condensed Matter, Vol. 31, Issue 4 https://doi.org/10.1088/1361-648x/aaf130	journal	December 2018
In-depth study of the chemical/electronic structures of two-dimensional molybdenum disulfide materials with sub-micrometer-resolution scanning photoelectron microscopy Yun, Dong-Jin; Lee, Hyangsook; Baik, Jaeyoon 2D Materials, Vol. 7, Issue 2 https://doi.org/10.1088/2053-1583/ab5d96	journal	January 2020
Water-mediated photo-induced reduction of platinum films Fraxedas, Jordi; Zhang, Kuan; Sepúlveda, Borja Journal of Synchrotron Radiation, Vol. 26, Issue 4 https://doi.org/10.1107/s1600577519004685	journal	June 2019
Water-mediated photo-induced reduction of platinum films Fraxedas, Jordi; Zhang, Kuan; Sepúlveda, Borja International Union of Crystallography (IUCr) https://doi.org/10.1107/s1600577519004685/il5027sup1.pdf	text	January 2019
Perovskites in catalysis and electrocatalysis Hwang, Jonathan; Rao, Reshma R.; Giordano, Livia Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7092	journal	November 2017
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars Amann, Peter; Degerman, David; Lee, Ming-Tao Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-04318	text	January 2019
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars Amann, Peter; Degerman, David; Lee, Ming-Tao Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-04325	text	January 2019
Interface Science Using Ambient Pressure Hard X-ray Photoelectron Spectroscopy Favaro, Marco; Abdi, Fatwa; Crumlin, Ethan Surfaces, Vol. 2, Issue 1 https://doi.org/10.3390/surfaces2010008	journal	January 2019
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission Hävecker, Michael; Düngen, Pascal; Buller, Saskia Taylor & Francis https://doi.org/10.6084/m9.figshare.4721023	text	January 2017
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission Hävecker, Michael; Düngen, Pascal; Buller, Saskia Taylor & Francis https://doi.org/10.6084/m9.figshare.4721023.v1	text	January 2017

Similar Records

Stabilizing the Meniscus for Operando Characterization of Platinum During the Electrolyte-Consuming Alkaline Oxygen Evolution Reaction

Journal Article · Mon Oct 22 20:00:00 EDT 2018 · Topics in Catalysis · OSTI ID:1580347

(Invited) Investigation of the Si/TiO₂/Electrolyte Interface Using Operando Tender X-ray Photoelectron Spectroscopy

Journal Article · Sun Apr 12 20:00:00 EDT 2015 · ECS Transactions (Online) · OSTI ID:1634113

A new endstation at the Swiss Light Source for ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy measurements of liquid solutions

Journal Article · Mon Jul 15 00:00:00 EDT 2013 · Review of Scientific Instruments · OSTI ID:22220559

Related Subjects

25 ENERGY STORAGE
batteries
electrocatalysis
surface spectroscopy

Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

Citation Formats

References (62)

Cited By (44)

Similar Records

Related Subjects