Nickel Complexes of a Binucleating Ligand Derived from an SCS Pincer

Peterson, Sonja M.; Helm, Monte L.; Appel, Aaron M.

doi:10.1039/c4dt02718c

Nickel Complexes of a Binucleating Ligand Derived from an SCS Pincer

Journal Article · Tue Jan 13 23:00:00 EST 2015 · Dalton Transactions, 44(2):747-752

DOI:https://doi.org/10.1039/c4dt02718c· OSTI ID:1184947

Peterson, Sonja M.; Helm, Monte L.; Appel, Aaron M.

A binucleating ligand has been prepared that contains an SCS pincer and three oxygen donor ligands in a partial crown ether loop. To enable metalation with Ni0, a bromoarene precursor was used and resulted in the formation of a nickel-bromide complex in the SCS pincer. Reaction of the nickel complex with a lithium salt yielded a heterobimetallic complex with bromide bridging the two metal centers. The solid-state structures were determined for this heterobimetallic complex and the nickel-bromide precursor, and the two complexes were characterized electrochemically to determine the influence of coordinating the second metal. This research was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. MLH was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Energy Frontier Research Centers (EFRC); Center for Molecular Electrocatalysis (CME)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1184947

Report Number(s):: PNNL-SA-104617; KC0302010

Journal Information:: Dalton Transactions, 44(2):747-752, Journal Name: Dalton Transactions, 44(2):747-752

Country of Publication:: United States

Language:: English

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