Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols

Weiss, Charles J.; Wiedner, Eric S.; Roberts, John A.; Appel, Aaron M.

doi:10.1039/C5CC01107H

Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols

Journal Article · Sat Apr 11 00:00:00 EDT 2015 · Chemical Communications, 51(28):6172-6174

DOI:https://doi.org/10.1039/C5CC01107H· OSTI ID:1182935

Weiss, Charles J.; Wiedner, Eric S.; Roberts, John A.; Appel, Aaron M.

Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells. The research by CJW, ESW, and AMA was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The research by JASR was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Energy Frontier Research Centers (EFRC); Center for Molecular Electrocatalysis (CME)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1182935

Report Number(s):: PNNL-SA-107999; KC0302010; KC0307010

Journal Information:: Chemical Communications, 51(28):6172-6174, Journal Name: Chemical Communications, 51(28):6172-6174

Country of Publication:: United States

Language:: English

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References (24)

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