Crystal engineering, structure–function relationships, and the future of metal–organic frameworks

Allendorf, Mark D.; Stavila, Vitalie

doi:10.1039/C4CE01693A

Crystal engineering, structure–function relationships, and the future of metal–organic frameworks

Journal Article · Wed Oct 15 00:00:00 EDT 2014 · CrystEngComm

DOI:https://doi.org/10.1039/C4CE01693A· OSTI ID:1184502

Allendorf, Mark D. ^[1]; Stavila, Vitalie ^[1]

Sandia National Laboratories (SNL-CA), Livermore, CA (United States)

Metal-Organic Frameworks (MOFs) are a rapidly expanding class of hybrid organic-inorganic materials that can be rationally designed and assembled through crystal engineering. The explosion of interest in this subclass of coordination polymers results from their outstanding properties and myriad possible applications that include traditional uses of microporous materials, such as gas storage, separations, and catalysis, to new realms in biomedicine, electronic devices, and and information storage. The objective of this Highlight article is to provide the reader with a sense of where the field stands after roughly fifteen years of research. Remarkable progress has been made, but the barriers to practical and commercial advances are also illuminated. We discuss the basic elements of MOF assembly and present a conceptual hierarchy of structural elements that assists in understanding how unique properties in these materials can be achieved. Structure-function relationships are then discussed; several are now well understood as a result of the focused efforts of many research groups over the past decade. Prospects for practical applications of MOFs in membranes, catalysis, biomedicine, and as active components in electronic and photonic devices are also discussed. Finally, we list key challenges that, in our view, must be addressed for these materials to realize their full potential in the marketplace.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1184502

Report Number(s):: SAND--2014-19073J; 540693

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 2 Vol. 17; ISSN CRECF4; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Mononuclear and polynuclear complexes ligated by an iminodiacetic acid derivative: synthesis, structure, solution studies and magnetic properties Puentes, Roberto; Torres, Julia; Kremer, Carlos Dalton Transactions, Vol. 45, Issue 12 https://doi.org/10.1039/c5dt05060j	journal	January 2016
Amide functionalized metal–organic frameworks for diastereoselective nitroaldol (Henry) reaction in aqueous medium Paul, Anup; Karmakar, Anirban; Guedes da Silva, M. Fátima C. RSC Advances, Vol. 5, Issue 106 https://doi.org/10.1039/c5ra14637b	journal	January 2015
Tunable luminescence and white light emission of mixed lanthanide–organic frameworks based on polycarboxylate ligands Wu, Jiawei; Zhang, Huabin; Du, Shaowu Journal of Materials Chemistry C, Vol. 4, Issue 16 https://doi.org/10.1039/c5tc04432d	journal	January 2016
Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives D'Alessandro, D. M. Chemical Communications, Vol. 52, Issue 58 https://doi.org/10.1039/c6cc00805d	journal	January 2016
Two pillared metal–organic frameworks comprising a long pillar ligand used as fluorescent sensors for nitrobenzene and heterogeneous catalysts for the Knoevenagel condensation reaction Ghasempour, Hosein; Azhdari Tehrani, Alireza; Morsali, Ali CrystEngComm, Vol. 18, Issue 14 https://doi.org/10.1039/c6ce00108d	journal	January 2016
Fluorescence and photochromic properties of a series of new Zn( ii )/Cd( ii ) coordination compounds with a flexible semi-rigid tetrazole–viologen derivative Xiao, Yu; Wang, Shuai-Hua; Zhao, Ya-Ping CrystEngComm, Vol. 18, Issue 14 https://doi.org/10.1039/c6ce00317f	journal	January 2016
Water coordination and dehydration processes in defective UiO-66 type metal organic frameworks Vandichel, M.; Hajek, J.; Ghysels, A. CrystEngComm, Vol. 18, Issue 37 https://doi.org/10.1039/c6ce01027j	journal	January 2016
Zn( ii )-based metal–organic framework: an exceptionally thermally stable, guest-free low dielectric material Mendiratta, Shruti; Usman, Muhammad; Chang, Chun-Chi Journal of Materials Chemistry C, Vol. 5, Issue 6 https://doi.org/10.1039/c6tc05314a	journal	January 2017
From isolated to 2D coordination polymers based on 6-aminonicotinate and 3d-metal ions: towards field-induced single-ion-magnets Rodríguez-Diéguez, Antonio; Pérez-Yáñez, Sonia; Ruiz-Rubio, Leire CrystEngComm, Vol. 19, Issue 16 https://doi.org/10.1039/c7ce00234c	journal	January 2017
Two lanthanide metal–organic frameworks as sensitive luminescent sensors for the detection of Cr ²⁺ and Cr ₂ O ₇ ²⁻ in aqueous solutions Huang, X. H.; Shi, L.; Ying, S. M. CrystEngComm, Vol. 20, Issue 2 https://doi.org/10.1039/c7ce01781b	journal	January 2018
Sequential dielectric phase transitions induced by the vibrations of water molecules in an organic–inorganic hybrid halide (N-(2-ammoniumethyl)piperazinium) CuCl ₅ ·2H ₂ O Wang, Zhongxia; Lu, Yang; Zafar, Zainab Dalton Transactions, Vol. 46, Issue 31 https://doi.org/10.1039/c7dt01378g	journal	January 2017
Cadmium–1,4-cyclohexanedicarboxylato coordination polymers bearing different di-alkyl-2,2′-bipyridines: syntheses, crystal structures and photoluminescence studies Rosales-Vázquez, Luis D.; Sánchez-Mendieta, Víctor; Dorazco-González, Alejandro Dalton Transactions, Vol. 46, Issue 37 https://doi.org/10.1039/c7dt02376f	journal	January 2017
Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks Godoy, Agustín A.; Gomez, Germán E.; Kaczmarek, Anna M. Journal of Materials Chemistry C, Vol. 5, Issue 47 https://doi.org/10.1039/c7tc04006g	journal	January 2017
Bulky substituent and solvent-induced alternative nodes for layered Cd–isophthalate/acylhydrazone frameworks Roztocki, Kornel; Lupa, Magdalena; Hodorowicz, Maciej CrystEngComm, Vol. 20, Issue 20 https://doi.org/10.1039/c8ce00269j	journal	January 2018
Framework flexibility of ZIF-8 under liquid intrusion: discovering time-dependent mechanical response and structural relaxation Sun, Yueting; Li, Yibing; Tan, Jin-Chong Physical Chemistry Chemical Physics, Vol. 20, Issue 15 https://doi.org/10.1039/c8cp00447a	journal	January 2018
Syntheses, crystal structures, adsorption properties and visible photocatalytic activities of highly stable Pb-based coordination polymers constructed by 2-(2-carboxyphenyl)imidazo(4,5- f )-(1,10)phenanthroline and bridging linkers Li, Zhi-Min; Qiao, Yu; Liu, Chun-Bo Dalton Transactions, Vol. 47, Issue 23 https://doi.org/10.1039/c8dt00997j	journal	January 2018
Template effect of innocent and coordinating anions on the formation of interpenetrated 2D and 3D networks: methyl orange and iodine sorption studies Baig, Fayaz; Rangan, Krishnan; Eappen, Shibu M. CrystEngComm, Vol. 22, Issue 4 https://doi.org/10.1039/c9ce00998a	journal	January 2020
Solvent-assisted ligand exchange (SALE) for the enhancement of epoxide ring-opening reaction catalysis based on three amide-functionalized metal–organic frameworks Gharib, Maniya; Esrafili, Leili; Morsali, Ali Dalton Transactions, Vol. 48, Issue 24 https://doi.org/10.1039/c9dt00941h	journal	January 2019
Cyclometalation of lanthanum( iii ) based MOF for catalytic hydrogenation of carbon dioxide to formate Tshuma, Piwai; Makhubela, Banothile C. E.; Öhrström, Lars RSC Advances, Vol. 10, Issue 6 https://doi.org/10.1039/c9ra09938g	journal	January 2020
Solvent-dependent supramolecular self-assembly of boron cage pillared metal–organic frameworks for selective gas separation Zhang, Yuanbin; Wang, Lingyao; Hu, Jianbo CrystEngComm, Vol. 22, Issue 15 https://doi.org/10.1039/d0ce00142b	journal	January 2020
Highly efficient and durable aqueous electrocatalytic reduction of CO ₂ to HCOOH with a novel bismuth–MOF: experimental and DFT studies Zhang, Xurui; Zhang, Yanxing; Li, Qingqing Journal of Materials Chemistry A, Vol. 8, Issue 19 https://doi.org/10.1039/d0ta00384k	journal	January 2020
Influence of thermally induced structural transformations on the magnetic and luminescence properties of tartrate-based chiral lanthanide organic-frameworks Huizi-Rayo, Uxua; Zabala-Lekuona, Andoni; Terenzi, Alessio Journal of Materials Chemistry C, Vol. 8, Issue 24 https://doi.org/10.1039/d0tc00736f	journal	January 2020
Homo- and heterometallic complexes constructed from hexafluoroacetylacetonato and Schiff-base complexes as building-blocks Mocanu, Mihaela I.; Shova, Sergiu; Lloret, Francesc Journal of Coordination Chemistry, Vol. 71, Issue 5 https://doi.org/10.1080/00958972.2018.1434877	journal	February 2018
Three Ln ^III coordination compounds based on 1,1′,1″-(benzene-1,3,5-triyltris(methylene))tris(4-carboxypyridinium)tribromide: Synthesis, structures, and properties Zhou, Jie; Qiao, Yong-Feng; Yan, Tong Journal of Coordination Chemistry, Vol. 71, Issue 7 https://doi.org/10.1080/00958972.2018.1454591	journal	March 2018
The right isotherms for the right reasons? Validation of generic force fields for prediction of methane adsorption in metal-organic frameworks Lennox, Matthew J.; Bound, Michelle; Henley, Alice Molecular Simulation, Vol. 43, Issue 10-11 https://doi.org/10.1080/08927022.2017.1301665	journal	March 2017
Recent advances and opportunities in the treatment of hydrocarbons and oils: Metal-organic frameworks-based approaches Kumar, Vanish; Vellingiri, Kowsalya; Kukkar, Deepak Critical Reviews in Environmental Science and Technology, Vol. 49, Issue 7 https://doi.org/10.1080/10643389.2018.1554402	journal	January 2019
Syntheses, structure and spectral studies of a new highly luminescent Cd(II)-5-sulfoisophthalate coordination polymer Semerci, Fatih Inorganic and Nano-Metal Chemistry, Vol. 48, Issue 3 https://doi.org/10.1080/24701556.2018.1503675	journal	March 2018
Fe(III) porphyrin metal–organic framework as an artificial enzyme mimics and its application in biosensing of glucose and H2O2 Dehghanpour, Saeed; Aghayan, Morvarid; Mahmoudi, Ali figshare https://doi.org/10.6084/m9.figshare.13726708	text	January 2021
Fe(III) porphyrin metal–organic framework as an artificial enzyme mimics and its application in biosensing of glucose and H2O2 Dehghanpour, Saeed; Aghayan, Morvarid; Mahmoudi, Ali figshare https://doi.org/10.6084/m9.figshare.13726708.v1	text	January 2021
The right isotherms for the right reasons? Validation of generic force fields for prediction of methane adsorption in metal-organic frameworks Lennox, Matthew J.; Bound, Michelle; Henley, Alice Taylor & Francis https://doi.org/10.6084/m9.figshare.4753837	text	January 2017
Homo- and heterometallic complexes constructed from hexafluoroacetylacetonato and Schiff-base complexes as building-blocks Mocanu, Mihaela I.; Shova, Sergiu; Lloret, Francesc Taylor & Francis https://doi.org/10.6084/m9.figshare.5840577.v1	text	January 2018

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