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From fundamentals to applications: a toolbox for robust and multifunctional MOF materials

Journal Article · · Chemical Society Reviews
DOI:https://doi.org/10.1039/c8cs00688a· OSTI ID:1566635
 [1];  [1];  [1];  [1];  [2]
  1. Department of Chemistry; Texas A&M University; College Station; USA
  2. Department of Chemistry; Texas A&M University; College Station; USA; Department of Material Science and Engineering
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In recent years, metal–organic frameworks (MOFs) have been regarded as one of the most important classes of materials. The combination of various metal clusters and ligands, arranged in a vast array of geometries has led to an ever-expanding MOF family. Each year, new and novel MOF structures are discovered. The structural diversity present in MOFs has significantly expanded the application of these new materials. MOFs show great potential for a variety of applications, including but not limited to: gas storage and separation, catalysis, biomedicine delivery, and chemical sensing. This review intends to offer a short summary of some of the most important topics and recent development in MOFs. The scope of this review shall cover the fundamental aspects concerning the design and synthesis of MOFs and range to the practical applications regarding their stability and derivative structures. Emerging trends of MOF development will also be discussed. These trends shall include multicomponent MOFs, defect development in MOFs, and MOF composites. The ever important structure–property–application relationship for MOFs will also be investigated. Overall, this review provides insight into both existing structures and emerging aspects of MOFs.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Texas A & M Univ., College Station, TX (United States); Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Fossil Energy (FE)
DOE Contract Number:
FE0026472; SC0001015
OSTI ID:
1566635
Journal Information:
Chemical Society Reviews, Vol. 47, Issue 23; ISSN 0306-0012
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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A novel MOF/graphene oxide composite GrO@MIL-101 with high adsorption capacity for acetone January 2014
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Confine sulfur in mesoporous metal–organic framework @ reduced graphene oxide for lithium sulfur battery January 2014
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Development of MWCNT@MIL-101 hybrid composite with enhanced adsorption capacity for carbon dioxide May 2012
Enhanced hydrogen sorption in single walled carbon nanotube incorporated MIL-101 composite metal–organic framework July 2011
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Synthesis of CNT@MIL-68(Al) composites with improved adsorption capacity for phenol in aqueous solution September 2015
Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction April 2012
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Design of metal organic framework–enzyme based bioelectrodes as a novel and highly sensitive biosensing platform January 2015
Hemin@metal–organic framework with peroxidase-like activity and its application to glucose detection January 2013
Novel Nano-/Micro-Biocatalyst: Soybean Epoxide Hydrolase Immobilized on UiO-66-NH 2 MOF for Efficient Biosynthesis of Enantiopure ( R )-1, 2-Octanediol in Deep Eutectic Solvents May 2016
Bio-functionalization of metal–organic frameworks by covalent protein conjugation January 2011
Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules June 2015
One-Pot Synthesis of Protein-Embedded Metal–Organic Frameworks with Enhanced Biological Activities September 2014
Computational Techniques at the Organic−Inorganic Interface in Biomineralization November 2008
Immobilization of MP-11 into a Mesoporous Metal–Organic Framework, MP-11@mesoMOF: A New Platform for Enzymatic Catalysis July 2011
Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation January 2015
Coupling two enzymes into a tandem nanoreactor utilizing a hierarchically structured MOF January 2016
Toward Design Rules for Enzyme Immobilization in Hierarchical Mesoporous Metal-Organic Frameworks July 2016

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membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)